Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

Activating atmospheric dinitrogen (N 2 ), a molecule with a remarkably strong triple bond, remains a major challenge in chemistry. This theoretical study explores the potential of superbase phosphines, specifically those decorated with imidazolin-2-imine ((ImN) 3 P) and imidazolin-2-methylidene ((Im...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2024-12, Vol.53 (48), p.19235-19245
Hauptverfasser:	Krishnapriya, Vilakkathala U, Suresh, Cherumuttathu H
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy Chemical bonds Density functional theory Endothermic reactions Energy requirements Hydrazines Hydrogen bonding Nitrogenation Phosphines
Online-Zugang:	Volltext
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