Exchange of CO2 with CO as Reactant Switches Selectivity in Photoreduction on Co−ZrO2 from C1–3 Paraffin to Small Olefins

Photocatalytic reduction of CO2 into C2,3 hydrocarbons completes a C‐neutral cycle. The reaction pathways of photocatalytic generation of C2,3 paraffin and C2H4 from CO2 are mostly unclear. Herein, a Co0−ZrO2 photocatalyst converted CO2 into C1–3 paraffin, while selectively converting CO into C2H4 a...

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Veröffentlicht in:	Angewandte Chemie 2024-12, Vol.136 (51), p.n/a
Hauptverfasser:	Loumissi, Tarik, Ishii, Rento, Hara, Keisuke, Oyumi, Tomoki, Abe, Ikki, Li, Chongxu, Zhang, Hongwei, Hirayama, Rumiko, Niki, Kaori, Itoi, Takaomi, Izumi, Yasuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes Carbon dioxide Carbon monoxide Cobalt Ethene Nanoparticles Paraffin Paraffins Photocatalysis Photocatalyst Photoreduction Reducing agents Zirconium dioxide
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