Instability of colloidal lead halide perovskite nanocrystals: Causes, improvement, and evaluation

The instability of colloidal lead halide perovskite nanocrystals (NCs) presents a significant challenge for their application in optoelectronic devices. This review examines the primary causes of instability in these NCs and the proposed mechanisms of degradation. It also introduces the recently dev...

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Veröffentlicht in:Nano research 2024-09, Vol.17 (12), p.10607-10619
Hauptverfasser: Tran, Thi Kim Tran, Nyiera, Hawi N., Zhao, Jing
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container_title Nano research
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creator Tran, Thi Kim Tran
Nyiera, Hawi N.
Zhao, Jing
description The instability of colloidal lead halide perovskite nanocrystals (NCs) presents a significant challenge for their application in optoelectronic devices. This review examines the primary causes of instability in these NCs and the proposed mechanisms of degradation. It also introduces the recently developed synthesis and surface passivation methods to address the instability issue of colloidal perovskite NCs. Specifically, we focus on the various types of ligands and precursors introduced during NC synthesis or post-treatment and how they impact the structural and optical properties of the perovskite NCs. This review also proposes a systematic approach to evaluating stability enhancement strategies by establishing key parameters and ranking them based on working and processing conditions. Finally, we discuss the issues that need to be addressed in future research to achieve practical application of lead halide perovskite NCs in advanced optoelectronic systems.
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subjects Atomic/Molecular Structure and Spectra
Biomedicine
Biotechnology
Chemistry and Materials Science
Colloiding
Condensed Matter Physics
Crystal structure
Crystals
Energy
Instability
Lead compounds
Ligands
Materials Science
Metal halides
Nanocrystals
Nanotechnology
Optical properties
Optoelectronic devices
Perovskites
Point defects
Review Article
Structural stability
Surface stability
Synthesis
title Instability of colloidal lead halide perovskite nanocrystals: Causes, improvement, and evaluation
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