Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions
The sonocatalytic pesticide destruction is one of the efficient methodologies to eradicate the effluents generated via agricultural industries. Herein, the novel NaA-type zeolite/ZnFe 2 O 4 /SnO 2 as a magnetically retrievable nanocomposite catalyst was successfully synthesized and applied for the s...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2024-12, Vol.35 (35), p.2216, Article 2216 |
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| creator | Sadeghi, Meysam Zarshenas, Pourya |
| description | The sonocatalytic pesticide destruction is one of the efficient methodologies to eradicate the effluents generated via agricultural industries. Herein, the novel NaA-type zeolite/ZnFe
2
O
4
/SnO
2
as a magnetically retrievable nanocomposite catalyst was successfully synthesized and applied for the sonodestruction of the chlorpyrifos (CP), malathion (MT), methyl parathion (MPT), methyl paraoxon (MPO), fenitrothion (FNT), and diazinon (DZ) as hazardous organophosphorous pesticides (OPPs) from water solutions. The NaA/ZnFe
2
O
4
/SnO
2
nanocomposite was precisely identified via the FESEM, AFM, EDAX, EDAX elemental dot mappings, FTIR, XRD, VSM, BET, UV–Vis DRS, XPS, and ICP-AES methods. To investigate the sonocatalytic performance of the NaA/ZnFe
2
O
4
/SnO
2
, the main key factors, like irradiation time, initial pesticide concentration, sonocatalyst amount, H
2
O
2
concentration, and ultrasound (US) power intensity were surveyed. The maximum sonocatalytic yields of 100%, 100%, 98.32%, 96.87%, 95.91%, and 95% were gained for CP, MT, MPO, MPT, FNT, and DZ on the NaA/ZnFe
2
O
4
/SnO
2
in the presence of the US/H
2
O
2
system, respectively. The sonocatalytic destruction process of CPS was assessed through the first-order kinetic model. On the basis of the obtained results, the half-life time (
t
1/2
) and reaction rate constant (
k
app
) of the CPS destruction via the NaA/ZnFe
2
O
4
/SnO
2
/US/H
2
O
2
system were calculated to be 3.96 min and 0.1748 min
−1
, respectively. The hydroxyl radicals (
•
OHs) were distinguished as the crucial reactive oxidative species on the destruction of CP under US irradiation. As well, the reproducibility and stability of the as-synthesized NaA/ZnFe
2
O
4
/SnO
2
sonocatalyst were investigated in four sequential runs, and a loss of less than 6% was obtained in the sonodestruction yield. |
| doi_str_mv | 10.1007/s10854-024-13992-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3141254536</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3141254536</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-1c98eb045aa755413476c14aaa7157358e3b9bf75c7f7a23609bac1b4182a22e3</originalsourceid><addsrcrecordid>eNp9kc1KAzEURoMoWKsv4Crgemx-OzPLUtQKxS5UEDchEzPtlGnumGTU-iK-rqkV3LkIIeSc-3H5EDqn5JISko8CJYUUGWEio7wsWSYP0IDKnGeiYE-HaEBKmWdCMnaMTkJYE0LGghcD9DVrlqt2i21dN6axLuIADl5siL43sQGHocYRPhqDwS-1g24FIR0PfcBdwpKVaNyHxi2xgzfb4js9wZ8W2iba0bO7tmwhRvduwbBLvoFNByF9YaOjbrch4trDBr_raH0Kb_tdajhFR7Vugz37vYfo8frqYTrL5oub2-lknhlGSMyoKQtbESG1zqUUlIt8bKjQ6bnbXhaWV2VV59Lkda4ZH5Oy0oZWghZMM2b5EF3s53YeXvu0j1pD712KVJwKyqSQfJwotqeMhxC8rVXnm432W0WJ2hWg9gWoVID6KUDJJPG9FBLsltb_jf7H-gYXkYx9</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3141254536</pqid></control><display><type>article</type><title>Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions</title><source>SpringerLink Journals - AutoHoldings</source><creator>Sadeghi, Meysam ; Zarshenas, Pourya</creator><creatorcontrib>Sadeghi, Meysam ; Zarshenas, Pourya</creatorcontrib><description>The sonocatalytic pesticide destruction is one of the efficient methodologies to eradicate the effluents generated via agricultural industries. Herein, the novel NaA-type zeolite/ZnFe
2
O
4
/SnO
2
as a magnetically retrievable nanocomposite catalyst was successfully synthesized and applied for the sonodestruction of the chlorpyrifos (CP), malathion (MT), methyl parathion (MPT), methyl paraoxon (MPO), fenitrothion (FNT), and diazinon (DZ) as hazardous organophosphorous pesticides (OPPs) from water solutions. The NaA/ZnFe
2
O
4
/SnO
2
nanocomposite was precisely identified via the FESEM, AFM, EDAX, EDAX elemental dot mappings, FTIR, XRD, VSM, BET, UV–Vis DRS, XPS, and ICP-AES methods. To investigate the sonocatalytic performance of the NaA/ZnFe
2
O
4
/SnO
2
, the main key factors, like irradiation time, initial pesticide concentration, sonocatalyst amount, H
2
O
2
concentration, and ultrasound (US) power intensity were surveyed. The maximum sonocatalytic yields of 100%, 100%, 98.32%, 96.87%, 95.91%, and 95% were gained for CP, MT, MPO, MPT, FNT, and DZ on the NaA/ZnFe
2
O
4
/SnO
2
in the presence of the US/H
2
O
2
system, respectively. The sonocatalytic destruction process of CPS was assessed through the first-order kinetic model. On the basis of the obtained results, the half-life time (
t
1/2
) and reaction rate constant (
k
app
) of the CPS destruction via the NaA/ZnFe
2
O
4
/SnO
2
/US/H
2
O
2
system were calculated to be 3.96 min and 0.1748 min
−1
, respectively. The hydroxyl radicals (
•
OHs) were distinguished as the crucial reactive oxidative species on the destruction of CP under US irradiation. As well, the reproducibility and stability of the as-synthesized NaA/ZnFe
2
O
4
/SnO
2
sonocatalyst were investigated in four sequential runs, and a loss of less than 6% was obtained in the sonodestruction yield.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-024-13992-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysts ; Characterization and Evaluation of Materials ; Chemical synthesis ; Chemistry and Materials Science ; Chlorpyrifos ; Hydrogen peroxide ; Hydroxyl radicals ; Irradiation ; Materials Science ; Methyl parathion ; Nanocomposites ; Optical and Electronic Materials ; Pesticides ; Tin dioxide ; X ray photoelectron spectroscopy ; Zeolites ; Zinc ferrites</subject><ispartof>Journal of materials science. Materials in electronics, 2024-12, Vol.35 (35), p.2216, Article 2216</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. Dec 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-1c98eb045aa755413476c14aaa7157358e3b9bf75c7f7a23609bac1b4182a22e3</cites><orcidid>0000-0003-2528-5607</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-024-13992-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-024-13992-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Sadeghi, Meysam</creatorcontrib><creatorcontrib>Zarshenas, Pourya</creatorcontrib><title>Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>The sonocatalytic pesticide destruction is one of the efficient methodologies to eradicate the effluents generated via agricultural industries. Herein, the novel NaA-type zeolite/ZnFe
2
O
4
/SnO
2
as a magnetically retrievable nanocomposite catalyst was successfully synthesized and applied for the sonodestruction of the chlorpyrifos (CP), malathion (MT), methyl parathion (MPT), methyl paraoxon (MPO), fenitrothion (FNT), and diazinon (DZ) as hazardous organophosphorous pesticides (OPPs) from water solutions. The NaA/ZnFe
2
O
4
/SnO
2
nanocomposite was precisely identified via the FESEM, AFM, EDAX, EDAX elemental dot mappings, FTIR, XRD, VSM, BET, UV–Vis DRS, XPS, and ICP-AES methods. To investigate the sonocatalytic performance of the NaA/ZnFe
2
O
4
/SnO
2
, the main key factors, like irradiation time, initial pesticide concentration, sonocatalyst amount, H
2
O
2
concentration, and ultrasound (US) power intensity were surveyed. The maximum sonocatalytic yields of 100%, 100%, 98.32%, 96.87%, 95.91%, and 95% were gained for CP, MT, MPO, MPT, FNT, and DZ on the NaA/ZnFe
2
O
4
/SnO
2
in the presence of the US/H
2
O
2
system, respectively. The sonocatalytic destruction process of CPS was assessed through the first-order kinetic model. On the basis of the obtained results, the half-life time (
t
1/2
) and reaction rate constant (
k
app
) of the CPS destruction via the NaA/ZnFe
2
O
4
/SnO
2
/US/H
2
O
2
system were calculated to be 3.96 min and 0.1748 min
−1
, respectively. The hydroxyl radicals (
•
OHs) were distinguished as the crucial reactive oxidative species on the destruction of CP under US irradiation. As well, the reproducibility and stability of the as-synthesized NaA/ZnFe
2
O
4
/SnO
2
sonocatalyst were investigated in four sequential runs, and a loss of less than 6% was obtained in the sonodestruction yield.</description><subject>Catalysts</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Chlorpyrifos</subject><subject>Hydrogen peroxide</subject><subject>Hydroxyl radicals</subject><subject>Irradiation</subject><subject>Materials Science</subject><subject>Methyl parathion</subject><subject>Nanocomposites</subject><subject>Optical and Electronic Materials</subject><subject>Pesticides</subject><subject>Tin dioxide</subject><subject>X ray photoelectron spectroscopy</subject><subject>Zeolites</subject><subject>Zinc ferrites</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kc1KAzEURoMoWKsv4Crgemx-OzPLUtQKxS5UEDchEzPtlGnumGTU-iK-rqkV3LkIIeSc-3H5EDqn5JISko8CJYUUGWEio7wsWSYP0IDKnGeiYE-HaEBKmWdCMnaMTkJYE0LGghcD9DVrlqt2i21dN6axLuIADl5siL43sQGHocYRPhqDwS-1g24FIR0PfcBdwpKVaNyHxi2xgzfb4js9wZ8W2iba0bO7tmwhRvduwbBLvoFNByF9YaOjbrch4trDBr_raH0Kb_tdajhFR7Vugz37vYfo8frqYTrL5oub2-lknhlGSMyoKQtbESG1zqUUlIt8bKjQ6bnbXhaWV2VV59Lkda4ZH5Oy0oZWghZMM2b5EF3s53YeXvu0j1pD712KVJwKyqSQfJwotqeMhxC8rVXnm432W0WJ2hWg9gWoVID6KUDJJPG9FBLsltb_jf7H-gYXkYx9</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Sadeghi, Meysam</creator><creator>Zarshenas, Pourya</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-2528-5607</orcidid></search><sort><creationdate>20241201</creationdate><title>Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions</title><author>Sadeghi, Meysam ; Zarshenas, Pourya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-1c98eb045aa755413476c14aaa7157358e3b9bf75c7f7a23609bac1b4182a22e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Catalysts</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Chlorpyrifos</topic><topic>Hydrogen peroxide</topic><topic>Hydroxyl radicals</topic><topic>Irradiation</topic><topic>Materials Science</topic><topic>Methyl parathion</topic><topic>Nanocomposites</topic><topic>Optical and Electronic Materials</topic><topic>Pesticides</topic><topic>Tin dioxide</topic><topic>X ray photoelectron spectroscopy</topic><topic>Zeolites</topic><topic>Zinc ferrites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sadeghi, Meysam</creatorcontrib><creatorcontrib>Zarshenas, Pourya</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sadeghi, Meysam</au><au>Zarshenas, Pourya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2024-12-01</date><risdate>2024</risdate><volume>35</volume><issue>35</issue><spage>2216</spage><pages>2216-</pages><artnum>2216</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>The sonocatalytic pesticide destruction is one of the efficient methodologies to eradicate the effluents generated via agricultural industries. Herein, the novel NaA-type zeolite/ZnFe
2
O
4
/SnO
2
as a magnetically retrievable nanocomposite catalyst was successfully synthesized and applied for the sonodestruction of the chlorpyrifos (CP), malathion (MT), methyl parathion (MPT), methyl paraoxon (MPO), fenitrothion (FNT), and diazinon (DZ) as hazardous organophosphorous pesticides (OPPs) from water solutions. The NaA/ZnFe
2
O
4
/SnO
2
nanocomposite was precisely identified via the FESEM, AFM, EDAX, EDAX elemental dot mappings, FTIR, XRD, VSM, BET, UV–Vis DRS, XPS, and ICP-AES methods. To investigate the sonocatalytic performance of the NaA/ZnFe
2
O
4
/SnO
2
, the main key factors, like irradiation time, initial pesticide concentration, sonocatalyst amount, H
2
O
2
concentration, and ultrasound (US) power intensity were surveyed. The maximum sonocatalytic yields of 100%, 100%, 98.32%, 96.87%, 95.91%, and 95% were gained for CP, MT, MPO, MPT, FNT, and DZ on the NaA/ZnFe
2
O
4
/SnO
2
in the presence of the US/H
2
O
2
system, respectively. The sonocatalytic destruction process of CPS was assessed through the first-order kinetic model. On the basis of the obtained results, the half-life time (
t
1/2
) and reaction rate constant (
k
app
) of the CPS destruction via the NaA/ZnFe
2
O
4
/SnO
2
/US/H
2
O
2
system were calculated to be 3.96 min and 0.1748 min
−1
, respectively. The hydroxyl radicals (
•
OHs) were distinguished as the crucial reactive oxidative species on the destruction of CP under US irradiation. As well, the reproducibility and stability of the as-synthesized NaA/ZnFe
2
O
4
/SnO
2
sonocatalyst were investigated in four sequential runs, and a loss of less than 6% was obtained in the sonodestruction yield.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-024-13992-5</doi><orcidid>https://orcid.org/0000-0003-2528-5607</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of materials science. Materials in electronics, 2024-12, Vol.35 (35), p.2216, Article 2216 |
| issn | 0957-4522 1573-482X |
| language | eng |
| recordid | cdi_proquest_journals_3141254536 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Catalysts Characterization and Evaluation of Materials Chemical synthesis Chemistry and Materials Science Chlorpyrifos Hydrogen peroxide Hydroxyl radicals Irradiation Materials Science Methyl parathion Nanocomposites Optical and Electronic Materials Pesticides Tin dioxide X ray photoelectron spectroscopy Zeolites Zinc ferrites |
| title | Highly efficient sonodestruction of toxic organophosphorous pesticides using novel NaA zeolite/ZnFe2O4/SnO2 nanocomposite catalyst from water solutions |
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