Synthesis and Reactivity of the Amino‐Functionalized β‐Diketiminate Ligand Stabilized Germylene and Stannylene
Amino‐functionalized β‐diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β‐diketiminate stabilized tert‐butoxygermylene 3 and tert‐butoxystannylene 4, respectively. On the other hand, th...
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| Veröffentlicht in: | European journal of inorganic chemistry 2024-11, Vol.27 (33), p.n/a |
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| creator | Sun, Tianyi Kong, Cheng Wu, Linlin Wang, Hao |
| description | Amino‐functionalized β‐diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β‐diketiminate stabilized tert‐butoxygermylene 3 and tert‐butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis‐stannylene 5 containing a four‐membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X‐ray analysis.
Amino‐functionalized β‐diketiminate stabilized chlorogermylene and chlorostannylene featuring a RNH unit attached to the backbone carbon atom have been prepared and structurally characterized. In addition, the coordination mode of this β‐diketiminate ligand can be changed depending on the different reaction condition, and the ligand can also participate in the reaction. |
| doi_str_mv | 10.1002/ejic.202400378 |
| format | Article |
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Amino‐functionalized β‐diketiminate stabilized chlorogermylene and chlorostannylene featuring a RNH unit attached to the backbone carbon atom have been prepared and structurally characterized. In addition, the coordination mode of this β‐diketiminate ligand can be changed depending on the different reaction condition, and the ligand can also participate in the reaction.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.202400378</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Germylene ; Main group element ; N-heterocyclic ; NMR spectroscopy ; Single crystals ; Stannylene ; β-Diketiminate</subject><ispartof>European journal of inorganic chemistry, 2024-11, Vol.27 (33), p.n/a</ispartof><rights>2024 Wiley-VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1178-d64e8367f684e21409495a0aa0f09255fb2535bd9e517be8acd991c9272074b63</cites><orcidid>0000-0003-2282-1566</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.202400378$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.202400378$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Sun, Tianyi</creatorcontrib><creatorcontrib>Kong, Cheng</creatorcontrib><creatorcontrib>Wu, Linlin</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><title>Synthesis and Reactivity of the Amino‐Functionalized β‐Diketiminate Ligand Stabilized Germylene and Stannylene</title><title>European journal of inorganic chemistry</title><description>Amino‐functionalized β‐diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β‐diketiminate stabilized tert‐butoxygermylene 3 and tert‐butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis‐stannylene 5 containing a four‐membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X‐ray analysis.
Amino‐functionalized β‐diketiminate stabilized chlorogermylene and chlorostannylene featuring a RNH unit attached to the backbone carbon atom have been prepared and structurally characterized. In addition, the coordination mode of this β‐diketiminate ligand can be changed depending on the different reaction condition, and the ligand can also participate in the reaction.</description><subject>Germylene</subject><subject>Main group element</subject><subject>N-heterocyclic</subject><subject>NMR spectroscopy</subject><subject>Single crystals</subject><subject>Stannylene</subject><subject>β-Diketiminate</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkEtOwzAURS0EEqUwZWyJcYp_-XhYlbYUVUKiMLac5AVcUqfEKSiMWAJrYSEsgpXgkgqGjN7nnvukdxE6pWRACWHnsDTZgBEmCOFxsod6lEgZkChh-74XXARUiuQQHTm3JJ4hPOoht2ht8wDOOKxtjm9AZ415Nk2LqwJ7AQ9XxlZfb--TjfVKZXVpXiHHnx9-d2EeoTEe0A3gubnfXlg0OjUdM4V61ZZgAe8Ea3_GY3RQ6NLBya720d1kfDu6DObX09loOA8ySuMkyCMBCY_iIkoEMCqIFDLURGtSEMnCsEhZyMM0lxDSOIVEZ7mUNJMsZiQWacT76Ky7u66rpw24Ri2rTe0_cIpTzqMkpj6EPhp0VFZXztVQqHVtVrpuFSVqG6zaBqt-g_UG2RleTAntP7QaX81Gf95vBlSAGA</recordid><startdate>20241121</startdate><enddate>20241121</enddate><creator>Sun, Tianyi</creator><creator>Kong, Cheng</creator><creator>Wu, Linlin</creator><creator>Wang, Hao</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-2282-1566</orcidid></search><sort><creationdate>20241121</creationdate><title>Synthesis and Reactivity of the Amino‐Functionalized β‐Diketiminate Ligand Stabilized Germylene and Stannylene</title><author>Sun, Tianyi ; Kong, Cheng ; Wu, Linlin ; Wang, Hao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1178-d64e8367f684e21409495a0aa0f09255fb2535bd9e517be8acd991c9272074b63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Germylene</topic><topic>Main group element</topic><topic>N-heterocyclic</topic><topic>NMR spectroscopy</topic><topic>Single crystals</topic><topic>Stannylene</topic><topic>β-Diketiminate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Tianyi</creatorcontrib><creatorcontrib>Kong, Cheng</creatorcontrib><creatorcontrib>Wu, Linlin</creatorcontrib><creatorcontrib>Wang, Hao</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>European journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Tianyi</au><au>Kong, Cheng</au><au>Wu, Linlin</au><au>Wang, Hao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Reactivity of the Amino‐Functionalized β‐Diketiminate Ligand Stabilized Germylene and Stannylene</atitle><jtitle>European journal of inorganic chemistry</jtitle><date>2024-11-21</date><risdate>2024</risdate><volume>27</volume><issue>33</issue><epage>n/a</epage><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>Amino‐functionalized β‐diketiminate stabilized chlorogermylene 1 and chlorostannylene 2 have been prepared and structurally characterized. The reactions of 1 or 2 with KOtBu afforded the β‐diketiminate stabilized tert‐butoxygermylene 3 and tert‐butoxystannylene 4, respectively. On the other hand, the reaction of 2 with LiN(SiMe3)2 led to the isolation of the bis‐stannylene 5 containing a four‐membered Sn2N2 ring. All new compounds have been characterized by multiple NMR spectroscopy and single crystal X‐ray analysis.
Amino‐functionalized β‐diketiminate stabilized chlorogermylene and chlorostannylene featuring a RNH unit attached to the backbone carbon atom have been prepared and structurally characterized. In addition, the coordination mode of this β‐diketiminate ligand can be changed depending on the different reaction condition, and the ligand can also participate in the reaction.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ejic.202400378</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-2282-1566</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Germylene Main group element N-heterocyclic NMR spectroscopy Single crystals Stannylene β-Diketiminate |
| title | Synthesis and Reactivity of the Amino‐Functionalized β‐Diketiminate Ligand Stabilized Germylene and Stannylene |
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