Highly sensitive temperature sensing of Na(Y1.5Na0.5)F6 glass-ceramics based on Dy3+/Pr3+ energy transfer

A novel variety of Na(Y1.5Na0.5)F6 (NYNF) glass-ceramics (GCs), co-doped with Dy3+/Pr3+, exhibiting remarkable temperature sensitivity, has been developed using the high-temperature melt-quenching technique. The influence of rare earth ion doping on the matrix lattice was thoroughly analyzed via X-r...

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Veröffentlicht in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2024-11, Vol.12 (46), p.18905-18916
Hauptverfasser: Ren, Kaikai, Wei, Di, Cai, Xinyi, Liang Ke, Ying, Junyi, Fu, Chaohui, Zhang, Yuepin
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container_issue 46
container_start_page 18905
container_title Journal of materials chemistry. C, Materials for optical and electronic devices
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creator Ren, Kaikai
Wei, Di
Cai, Xinyi
Liang Ke
Ying, Junyi
Fu, Chaohui
Zhang, Yuepin
description A novel variety of Na(Y1.5Na0.5)F6 (NYNF) glass-ceramics (GCs), co-doped with Dy3+/Pr3+, exhibiting remarkable temperature sensitivity, has been developed using the high-temperature melt-quenching technique. The influence of rare earth ion doping on the matrix lattice was thoroughly analyzed via X-ray diffraction, while the size and distribution of nano-scale grains were examined using transmission electron microscopy. These analyses collectively confirmed the successful synthesis of the GCs. Furthermore, the optical characteristics of NYNF GCs were investigated, revealing that the optimal concentration for Pr3+ doping is 0.5 mol%. Additionally, the study delved into how varying concentrations of Pr3+ doping influence the luminescence of GCs. The doped samples demonstrated superior temperature sensitivity, achieving a maximum relative sensitivity of 1.302% K−1 and a high activation energy of 0.31 eV. These findings suggest that Dy3+/Pr3+ co-doped NYNF GCs hold promise as an exceptional optical material for applications in non-contact temperature sensors and high sensitivity electronic display.
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source Royal Society Of Chemistry Journals 2008-
subjects Doping
Energy transfer
Glass ceramics
High temperature
Optical materials
Optical properties
Temperature sensors
title Highly sensitive temperature sensing of Na(Y1.5Na0.5)F6 glass-ceramics based on Dy3+/Pr3+ energy transfer
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