Tuning the efficiency of KBr/PVA solid polymer electrolyte based dye-sensitized solar cell using electron irradiation
Effect of 10 MeV Electron irradiation on Dye-Sensitized Solar cell Efficiency based on KBr/PVA Solid Polymer Electrolyte (SPE) was studied using various techniques. Raman and XPS studies reveals that the irradiation affects the micro-structure/surface chemistry and is attributed to the crosslinking,...
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| creator | Mahantesha, B. K. Ravindrachary, V. Rashmi, L. Padmakumari, R. Sanjeev, Ganesh Petwal, V. C. |
| description | Effect of 10 MeV Electron irradiation on Dye-Sensitized Solar cell Efficiency based on KBr/PVA Solid Polymer Electrolyte (SPE) was studied using various techniques. Raman and XPS studies reveals that the irradiation affects the micro-structure/surface chemistry and is attributed to the crosslinking, chain scission, the free radical formation and carbonization induced by irradiation within the samples. The FESEM and AFM studies shows the evolution of elevated square stage like structure and results into amorphization of the SPE at a higher irradiation dose. These structural modifications are reflected in the form of enhancement of dielectric and conductivity properties of the SPE with irradiation dose. These results suggests that the irradiation creates the complexes within the sample and forms hydrogen depleted carbon network within the polymeric matrix. As a result of this modification the electrical conductivity increases with irradiation dose and the maximum conductivity of 3.42 × 10
–2
S/cm is observed for 300 kGy at 373 K temperature. The electrical measurements suggests that the modified conductivity results follows Jonscher’s power law for all the samples. Using the pristine and 300 kGy dose irradiated SPE samples the dye-sensitized solar cell (DSSC) was fabricated and the efficiency of the same was studied. |
| doi_str_mv | 10.1007/s11082-024-06956-w |
| format | Article |
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–2
S/cm is observed for 300 kGy at 373 K temperature. The electrical measurements suggests that the modified conductivity results follows Jonscher’s power law for all the samples. Using the pristine and 300 kGy dose irradiated SPE samples the dye-sensitized solar cell (DSSC) was fabricated and the efficiency of the same was studied.</description><identifier>ISSN: 1572-817X</identifier><identifier>ISSN: 0306-8919</identifier><identifier>EISSN: 1572-817X</identifier><identifier>DOI: 10.1007/s11082-024-06956-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Amorphization ; Chain scission ; Characterization and Evaluation of Materials ; Computer Communication Networks ; Crosslinking ; Dye-sensitized solar cells ; Dyes ; Efficiency ; Electrical Engineering ; Electrical measurement ; Electrical resistivity ; Electrolytes ; Electron irradiation ; Free radicals ; Lasers ; Optical Devices ; Optics ; Photonics ; Physics ; Physics and Astronomy ; Polymers ; Radiation dosage ; Solar storms ; X ray photoelectron spectroscopy</subject><ispartof>Optical and quantum electronics, 2024-11, Vol.56 (12), Article 1963</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c115w-3dcd842f6bbfbd69f2fbc2f2668ed676ac5c6da4f019f45f97c120fe53500d713</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11082-024-06956-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11082-024-06956-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Mahantesha, B. K.</creatorcontrib><creatorcontrib>Ravindrachary, V.</creatorcontrib><creatorcontrib>Rashmi, L.</creatorcontrib><creatorcontrib>Padmakumari, R.</creatorcontrib><creatorcontrib>Sanjeev, Ganesh</creatorcontrib><creatorcontrib>Petwal, V. C.</creatorcontrib><title>Tuning the efficiency of KBr/PVA solid polymer electrolyte based dye-sensitized solar cell using electron irradiation</title><title>Optical and quantum electronics</title><addtitle>Opt Quant Electron</addtitle><description>Effect of 10 MeV Electron irradiation on Dye-Sensitized Solar cell Efficiency based on KBr/PVA Solid Polymer Electrolyte (SPE) was studied using various techniques. Raman and XPS studies reveals that the irradiation affects the micro-structure/surface chemistry and is attributed to the crosslinking, chain scission, the free radical formation and carbonization induced by irradiation within the samples. The FESEM and AFM studies shows the evolution of elevated square stage like structure and results into amorphization of the SPE at a higher irradiation dose. These structural modifications are reflected in the form of enhancement of dielectric and conductivity properties of the SPE with irradiation dose. These results suggests that the irradiation creates the complexes within the sample and forms hydrogen depleted carbon network within the polymeric matrix. As a result of this modification the electrical conductivity increases with irradiation dose and the maximum conductivity of 3.42 × 10
–2
S/cm is observed for 300 kGy at 373 K temperature. The electrical measurements suggests that the modified conductivity results follows Jonscher’s power law for all the samples. Using the pristine and 300 kGy dose irradiated SPE samples the dye-sensitized solar cell (DSSC) was fabricated and the efficiency of the same was studied.</description><subject>Amorphization</subject><subject>Chain scission</subject><subject>Characterization and Evaluation of Materials</subject><subject>Computer Communication Networks</subject><subject>Crosslinking</subject><subject>Dye-sensitized solar cells</subject><subject>Dyes</subject><subject>Efficiency</subject><subject>Electrical Engineering</subject><subject>Electrical measurement</subject><subject>Electrical resistivity</subject><subject>Electrolytes</subject><subject>Electron irradiation</subject><subject>Free radicals</subject><subject>Lasers</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Polymers</subject><subject>Radiation dosage</subject><subject>Solar storms</subject><subject>X ray photoelectron spectroscopy</subject><issn>1572-817X</issn><issn>0306-8919</issn><issn>1572-817X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kF1LwzAUhoMoOKd_wKuA13FJ2qTd5Rx-4UAvpngX0uRkZnTtTFpG_fV2dqBXXp1z4HneAy9Cl4xeM0qzSWSM5pxQnhIqp0KS3REaMZFxkrPs_fjPforOYlxTSmUq6Ai1y7by1Qo3H4DBOW88VKbDtcNPN2Hy8jbDsS69xdu67DYQMJRgmtAfDeBCR7DYdkAiVNE3_qs_e1wHbKAscRv3yQejwj4Ebb1ufF2doxOnywgXhzlGr3e3y_kDWTzfP85nC2IYEzuSWGPzlDtZFK6wcuq4Kwx3XMocrMykNsJIq1NH2dSlwk0zwzh1IBJBqc1YMkZXQ-421J8txEat6zZU_UuVsIQnQvJU9BQfKBPqGAM4tQ1-o0OnGFX7etVQr-rrVT_1ql0vJYMUe7haQfiN_sf6BjepgLw</recordid><startdate>20241123</startdate><enddate>20241123</enddate><creator>Mahantesha, B. 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K.</creatorcontrib><creatorcontrib>Ravindrachary, V.</creatorcontrib><creatorcontrib>Rashmi, L.</creatorcontrib><creatorcontrib>Padmakumari, R.</creatorcontrib><creatorcontrib>Sanjeev, Ganesh</creatorcontrib><creatorcontrib>Petwal, V. C.</creatorcontrib><collection>CrossRef</collection><jtitle>Optical and quantum electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mahantesha, B. K.</au><au>Ravindrachary, V.</au><au>Rashmi, L.</au><au>Padmakumari, R.</au><au>Sanjeev, Ganesh</au><au>Petwal, V. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning the efficiency of KBr/PVA solid polymer electrolyte based dye-sensitized solar cell using electron irradiation</atitle><jtitle>Optical and quantum electronics</jtitle><stitle>Opt Quant Electron</stitle><date>2024-11-23</date><risdate>2024</risdate><volume>56</volume><issue>12</issue><artnum>1963</artnum><issn>1572-817X</issn><issn>0306-8919</issn><eissn>1572-817X</eissn><abstract>Effect of 10 MeV Electron irradiation on Dye-Sensitized Solar cell Efficiency based on KBr/PVA Solid Polymer Electrolyte (SPE) was studied using various techniques. Raman and XPS studies reveals that the irradiation affects the micro-structure/surface chemistry and is attributed to the crosslinking, chain scission, the free radical formation and carbonization induced by irradiation within the samples. The FESEM and AFM studies shows the evolution of elevated square stage like structure and results into amorphization of the SPE at a higher irradiation dose. These structural modifications are reflected in the form of enhancement of dielectric and conductivity properties of the SPE with irradiation dose. These results suggests that the irradiation creates the complexes within the sample and forms hydrogen depleted carbon network within the polymeric matrix. As a result of this modification the electrical conductivity increases with irradiation dose and the maximum conductivity of 3.42 × 10
–2
S/cm is observed for 300 kGy at 373 K temperature. The electrical measurements suggests that the modified conductivity results follows Jonscher’s power law for all the samples. Using the pristine and 300 kGy dose irradiated SPE samples the dye-sensitized solar cell (DSSC) was fabricated and the efficiency of the same was studied.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11082-024-06956-w</doi></addata></record> |
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| subjects | Amorphization Chain scission Characterization and Evaluation of Materials Computer Communication Networks Crosslinking Dye-sensitized solar cells Dyes Efficiency Electrical Engineering Electrical measurement Electrical resistivity Electrolytes Electron irradiation Free radicals Lasers Optical Devices Optics Photonics Physics Physics and Astronomy Polymers Radiation dosage Solar storms X ray photoelectron spectroscopy |
| title | Tuning the efficiency of KBr/PVA solid polymer electrolyte based dye-sensitized solar cell using electron irradiation |
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