Diborane, Diborene and M(I)‐η2‐Diborene Complexes Stabilized by Bicyclic (Alkyl)(Amino)Carbene (M=Cu and Ag)

BICAAC (bicyclic (alkyl)(amino)carbene) as ambiphilic carbene has been utilized to prepare stable neutral tetrahydrodiborane [BICAAC → ${\to }$ (H2)B−B(H2) ← ${\leftarrow }$ BICAAC] and dihydrodiborene [BICAAC→(H)B=B(H) ← ${\leftarrow }$ BICAAC] compounds. The Lewis base stabilized dihydrodiborene i...

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Veröffentlicht in:	European journal of inorganic chemistry 2024-11, Vol.27 (32), p.n/a
Hauptverfasser:	Adhikari, Manu, De, Sriman, Kumar Manar, Krishna, Kumar Thakur, Sandeep, Kamte, Rohit S., Koley, Debasis, Singh, Sanjay
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes carbene Carbenes coinage metal Coordination compounds Copper Copper chloride DFT Diborane diborene Lewis base Silver Transition metals
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