g-C3N4@COF heterojunction filler for polymer electrolytes enables fast Li+ transport and high mechanical strength
Solid polymer electrolytes (SPEs) show great promise for high-energy and high-safety lithium metal batteries. However, current SPEs suffer from low ionic conductivity and poor mechanical strength. Herein, the g-C 3 N 4 @COF heterojunction filler is constructed for SPEs for fast Li + transport and hi...
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| Veröffentlicht in: | Ionics 2024-11, Vol.30 (11), p.7051-7059 |
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| container_title | Ionics |
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| creator | Liu, Yongbiao Song, Yang Zhang, Yongshang Liu, Jiande Li, Lin Zhang, Linsen Du, Lulu |
| description | Solid polymer electrolytes (SPEs) show great promise for high-energy and high-safety lithium metal batteries. However, current SPEs suffer from low ionic conductivity and poor mechanical strength. Herein, the g-C
3
N
4
@COF heterojunction filler is constructed for SPEs for fast Li
+
transport and high Li
+
transference number. In addition, a robust 3D network is fabricated by using g-C
3
N
4
@COF heterojunction filler in order to further improve the mechanical robustness and electrochemical stability. As a consequence, the g-C
3
N
4
@COF-3D network/polymer electrolyte displays an ionic conductivity of 1.25×10
−4
S cm
−1
at 30 ℃, an electrochemical window of 5.0 V and the tensile strength of 8.613 MPa. Furthermore, the assembled LiFePO
4
//Li battery with the g-C
3
N
4
@COF-3D network/polymer electrolyte presents remarkable cycling stability with a capacity retention of 99.71% after 600 cycles. The above results indicate the great potential of the g-C
3
N
4
@COF-3D network/polymer electrolyte for advanced energy storage devices. |
| doi_str_mv | 10.1007/s11581-024-05796-8 |
| format | Article |
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3
N
4
@COF heterojunction filler is constructed for SPEs for fast Li
+
transport and high Li
+
transference number. In addition, a robust 3D network is fabricated by using g-C
3
N
4
@COF heterojunction filler in order to further improve the mechanical robustness and electrochemical stability. As a consequence, the g-C
3
N
4
@COF-3D network/polymer electrolyte displays an ionic conductivity of 1.25×10
−4
S cm
−1
at 30 ℃, an electrochemical window of 5.0 V and the tensile strength of 8.613 MPa. Furthermore, the assembled LiFePO
4
//Li battery with the g-C
3
N
4
@COF-3D network/polymer electrolyte presents remarkable cycling stability with a capacity retention of 99.71% after 600 cycles. The above results indicate the great potential of the g-C
3
N
4
@COF-3D network/polymer electrolyte for advanced energy storage devices.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-024-05796-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon nitride ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemistry ; Electrolytes ; Energy Storage ; Fillers ; Heterojunctions ; Ion currents ; Lithium batteries ; Molten salt electrolytes ; Optical and Electronic Materials ; Polymers ; Renewable and Green Energy ; Solid electrolytes ; Stability ; Tensile strength</subject><ispartof>Ionics, 2024-11, Vol.30 (11), p.7051-7059</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-2d94bc61889336168a08fad302345fcd079388ccf4349662169217d585fd3b9d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-024-05796-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-024-05796-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Liu, Yongbiao</creatorcontrib><creatorcontrib>Song, Yang</creatorcontrib><creatorcontrib>Zhang, Yongshang</creatorcontrib><creatorcontrib>Liu, Jiande</creatorcontrib><creatorcontrib>Li, Lin</creatorcontrib><creatorcontrib>Zhang, Linsen</creatorcontrib><creatorcontrib>Du, Lulu</creatorcontrib><title>g-C3N4@COF heterojunction filler for polymer electrolytes enables fast Li+ transport and high mechanical strength</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Solid polymer electrolytes (SPEs) show great promise for high-energy and high-safety lithium metal batteries. However, current SPEs suffer from low ionic conductivity and poor mechanical strength. Herein, the g-C
3
N
4
@COF heterojunction filler is constructed for SPEs for fast Li
+
transport and high Li
+
transference number. In addition, a robust 3D network is fabricated by using g-C
3
N
4
@COF heterojunction filler in order to further improve the mechanical robustness and electrochemical stability. As a consequence, the g-C
3
N
4
@COF-3D network/polymer electrolyte displays an ionic conductivity of 1.25×10
−4
S cm
−1
at 30 ℃, an electrochemical window of 5.0 V and the tensile strength of 8.613 MPa. Furthermore, the assembled LiFePO
4
//Li battery with the g-C
3
N
4
@COF-3D network/polymer electrolyte presents remarkable cycling stability with a capacity retention of 99.71% after 600 cycles. The above results indicate the great potential of the g-C
3
N
4
@COF-3D network/polymer electrolyte for advanced energy storage devices.</description><subject>Carbon nitride</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Fillers</subject><subject>Heterojunctions</subject><subject>Ion currents</subject><subject>Lithium batteries</subject><subject>Molten salt electrolytes</subject><subject>Optical and Electronic Materials</subject><subject>Polymers</subject><subject>Renewable and Green Energy</subject><subject>Solid electrolytes</subject><subject>Stability</subject><subject>Tensile strength</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWB9_wFXApURvkpk8dkqxKhS70XVIM0lnyjTTJumi_97RCu5cnXPhnHPhQ-iGwj0FkA-Z0lpRAqwiUEstiDpBE6oEIyAFnKIJ6EoSCZU8Rxc5rwGEoExO0G5Fpvy9epwuZrj1xadhvY-udEPEoet7n3AYEt4O_WEzet97V9J4FJ-xj3bZjxpsLnje3eGSbMzbIRVsY4PbbtXijXetjZ2zPc4l-bgq7RU6C7bP_vpXL9Hn7Plj-krmi5e36dOcOAZQCGt0tXSCKqU5F1QoCyrYhgPjVR1cA1JzpZwLFa-0EIwKzahsalWHhi91wy_R7XF3m4bd3udi1sM-xfGl4ZRTxRnXdEyxY8qlIefkg9mmbmPTwVAw32jNEa0Z0ZoftEaNJX4s5TEcVz79Tf_T-gL3TXvj</recordid><startdate>20241101</startdate><enddate>20241101</enddate><creator>Liu, Yongbiao</creator><creator>Song, Yang</creator><creator>Zhang, Yongshang</creator><creator>Liu, Jiande</creator><creator>Li, Lin</creator><creator>Zhang, Linsen</creator><creator>Du, Lulu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20241101</creationdate><title>g-C3N4@COF heterojunction filler for polymer electrolytes enables fast Li+ transport and high mechanical strength</title><author>Liu, Yongbiao ; Song, Yang ; Zhang, Yongshang ; Liu, Jiande ; Li, Lin ; Zhang, Linsen ; Du, Lulu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-2d94bc61889336168a08fad302345fcd079388ccf4349662169217d585fd3b9d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Carbon nitride</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Fillers</topic><topic>Heterojunctions</topic><topic>Ion currents</topic><topic>Lithium batteries</topic><topic>Molten salt electrolytes</topic><topic>Optical and Electronic Materials</topic><topic>Polymers</topic><topic>Renewable and Green Energy</topic><topic>Solid electrolytes</topic><topic>Stability</topic><topic>Tensile strength</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yongbiao</creatorcontrib><creatorcontrib>Song, Yang</creatorcontrib><creatorcontrib>Zhang, Yongshang</creatorcontrib><creatorcontrib>Liu, Jiande</creatorcontrib><creatorcontrib>Li, Lin</creatorcontrib><creatorcontrib>Zhang, Linsen</creatorcontrib><creatorcontrib>Du, Lulu</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yongbiao</au><au>Song, Yang</au><au>Zhang, Yongshang</au><au>Liu, Jiande</au><au>Li, Lin</au><au>Zhang, Linsen</au><au>Du, Lulu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>g-C3N4@COF heterojunction filler for polymer electrolytes enables fast Li+ transport and high mechanical strength</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2024-11-01</date><risdate>2024</risdate><volume>30</volume><issue>11</issue><spage>7051</spage><epage>7059</epage><pages>7051-7059</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Solid polymer electrolytes (SPEs) show great promise for high-energy and high-safety lithium metal batteries. However, current SPEs suffer from low ionic conductivity and poor mechanical strength. Herein, the g-C
3
N
4
@COF heterojunction filler is constructed for SPEs for fast Li
+
transport and high Li
+
transference number. In addition, a robust 3D network is fabricated by using g-C
3
N
4
@COF heterojunction filler in order to further improve the mechanical robustness and electrochemical stability. As a consequence, the g-C
3
N
4
@COF-3D network/polymer electrolyte displays an ionic conductivity of 1.25×10
−4
S cm
−1
at 30 ℃, an electrochemical window of 5.0 V and the tensile strength of 8.613 MPa. Furthermore, the assembled LiFePO
4
//Li battery with the g-C
3
N
4
@COF-3D network/polymer electrolyte presents remarkable cycling stability with a capacity retention of 99.71% after 600 cycles. The above results indicate the great potential of the g-C
3
N
4
@COF-3D network/polymer electrolyte for advanced energy storage devices.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-024-05796-8</doi><tpages>9</tpages></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Carbon nitride Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Electrolytes Energy Storage Fillers Heterojunctions Ion currents Lithium batteries Molten salt electrolytes Optical and Electronic Materials Polymers Renewable and Green Energy Solid electrolytes Stability Tensile strength |
| title | g-C3N4@COF heterojunction filler for polymer electrolytes enables fast Li+ transport and high mechanical strength |
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