Amplified Response of Nickel Oxide-Decorated Lanthanum Phosphate Composite as an Anode Material for Asymmetric Supercapacitors
The rapidly expanding global population and fast economic growth has led to a shortage of energy and electricity resources. The scarcity of effective energy storage technologies and environmentally friendly electrical power alternatives is one of the greatest concerns in the modern era. Asymmetric s...
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| Veröffentlicht in: | Journal of electronic materials 2024-12, Vol.53 (12), p.7515-7530 |
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| creator | Baloch, Shahzaib Umair, Muhammad Shad, Naveed Akhtar El-Aziz, Khaled Abd Ullah, Asmat Qi, Fugang Ali, Hafiz T. Hussain, S. Jilani, Asim Javed, Yasir |
| description | The rapidly expanding global population and fast economic growth has led to a shortage of energy and electricity resources. The scarcity of effective energy storage technologies and environmentally friendly electrical power alternatives is one of the greatest concerns in the modern era. Asymmetric supercapacitors have garnered considerable attention due to their versatility in energy storage devices. However, they still require more effective electrode materials with superior electrochemical characteristics to improve their charge storage capacity, energy, and power parameters. To this end, in this work, nickel oxide (NiO), lanthanum phosphate (LaPO
4
), and nickel oxide-decorated lanthanum phosphate (NiO/LaPO
4
) nanosheets were synthesized by a facile hydrothermal method. The purity, crystallinity, and morphology of the materials were investigated using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS). The NiO-decorated LaPO
4
exhibited superior performance, providing higher specific capacity (
Q
s
) of 1054.4 C/g at 2.0 A/g. The developed electrode also demonstrated excellent electrical conductivity and stability (88% galvanostatic charge/discharge [GCD] retention for 1500 cycles) as determined by electrochemical impedance spectroscopy. The capacitive and diffusive contributions indicate that the fabricated material has an asymmetric storage nature. The results suggest that the prepared material could be used in asymmetric supercapacitor applications.
Graphical Abstract |
| doi_str_mv | 10.1007/s11664-024-11442-w |
| format | Article |
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4
), and nickel oxide-decorated lanthanum phosphate (NiO/LaPO
4
) nanosheets were synthesized by a facile hydrothermal method. The purity, crystallinity, and morphology of the materials were investigated using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS). The NiO-decorated LaPO
4
exhibited superior performance, providing higher specific capacity (
Q
s
) of 1054.4 C/g at 2.0 A/g. The developed electrode also demonstrated excellent electrical conductivity and stability (88% galvanostatic charge/discharge [GCD] retention for 1500 cycles) as determined by electrochemical impedance spectroscopy. The capacitive and diffusive contributions indicate that the fabricated material has an asymmetric storage nature. The results suggest that the prepared material could be used in asymmetric supercapacitor applications.
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4
), and nickel oxide-decorated lanthanum phosphate (NiO/LaPO
4
) nanosheets were synthesized by a facile hydrothermal method. The purity, crystallinity, and morphology of the materials were investigated using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS). The NiO-decorated LaPO
4
exhibited superior performance, providing higher specific capacity (
Q
s
) of 1054.4 C/g at 2.0 A/g. The developed electrode also demonstrated excellent electrical conductivity and stability (88% galvanostatic charge/discharge [GCD] retention for 1500 cycles) as determined by electrochemical impedance spectroscopy. The capacitive and diffusive contributions indicate that the fabricated material has an asymmetric storage nature. The results suggest that the prepared material could be used in asymmetric supercapacitor applications.
Graphical Abstract</description><subject>Alternative energy sources</subject><subject>Anodes</subject><subject>Asymmetry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Charge materials</subject><subject>Chemistry and Materials Science</subject><subject>Decoration</subject><subject>Economic development</subject><subject>Electric charge</subject><subject>Electrical resistivity</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electronics and Microelectronics</subject><subject>Electrons</subject><subject>Energy storage</subject><subject>Instrumentation</subject><subject>Lanthanide phosphates</subject><subject>Materials Science</subject><subject>Nickel oxides</subject><subject>Optical and Electronic Materials</subject><subject>Original Research Article</subject><subject>Photoelectrons</subject><subject>Solid State Physics</subject><subject>Spectrum analysis</subject><subject>Storage capacity</subject><subject>Supercapacitors</subject><subject>X ray photoelectron spectroscopy</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOAzEQRS0EEiHwA1SWqA0eP3Y3ZRSeUngIUtBZxmsTh-x6sTcKafh2DEGio5rRzLl3NBehY6CnQGl5lgCKQhDKBAEQgpH1DhqAFJxAVTzvogHlBRDJuNxHByktKAUJFQzQ57jplt55W-NHm7rQJouDw3fevNklvv_wtSXn1oSo-4xMddvPdbtq8MM8pG6eh3gSmi4knzudsG7xuA21xbd5Fb1eYhciHqdN09g-eoOfVp2NRnfa-D7EdIj2nF4me_Rbh2h2eTGbXJPp_dXNZDwlhlHak_yIrCpDpSlB1E6bkXAjadkLFGYElGluCmM5rxmvuSu5FBWrSs0tVKZkjg_Ryda2i-F9ZVOvFmEV23xRceDZQEhaZYptKRNDStE61UXf6LhRQNV3zGobs8q8-olZrbOIb0Upw-2rjX_W_6i-AF1lgew</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Baloch, Shahzaib</creator><creator>Umair, Muhammad</creator><creator>Shad, Naveed Akhtar</creator><creator>El-Aziz, Khaled Abd</creator><creator>Ullah, Asmat</creator><creator>Qi, Fugang</creator><creator>Ali, Hafiz T.</creator><creator>Hussain, S.</creator><creator>Jilani, Asim</creator><creator>Javed, Yasir</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4161-3543</orcidid></search><sort><creationdate>20241201</creationdate><title>Amplified Response of Nickel Oxide-Decorated Lanthanum Phosphate Composite as an Anode Material for Asymmetric Supercapacitors</title><author>Baloch, Shahzaib ; Umair, Muhammad ; Shad, Naveed Akhtar ; El-Aziz, Khaled Abd ; Ullah, Asmat ; Qi, Fugang ; Ali, Hafiz T. ; Hussain, S. ; Jilani, Asim ; Javed, Yasir</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-543588c05c714dfac94f95e2b16c9102a3c6ce33d23d3f73548287a3e18c72f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Alternative energy sources</topic><topic>Anodes</topic><topic>Asymmetry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Charge materials</topic><topic>Chemistry and Materials Science</topic><topic>Decoration</topic><topic>Economic development</topic><topic>Electric charge</topic><topic>Electrical resistivity</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electronics and Microelectronics</topic><topic>Electrons</topic><topic>Energy storage</topic><topic>Instrumentation</topic><topic>Lanthanide phosphates</topic><topic>Materials Science</topic><topic>Nickel oxides</topic><topic>Optical and Electronic Materials</topic><topic>Original Research Article</topic><topic>Photoelectrons</topic><topic>Solid State Physics</topic><topic>Spectrum analysis</topic><topic>Storage capacity</topic><topic>Supercapacitors</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baloch, Shahzaib</creatorcontrib><creatorcontrib>Umair, Muhammad</creatorcontrib><creatorcontrib>Shad, Naveed Akhtar</creatorcontrib><creatorcontrib>El-Aziz, Khaled Abd</creatorcontrib><creatorcontrib>Ullah, Asmat</creatorcontrib><creatorcontrib>Qi, Fugang</creatorcontrib><creatorcontrib>Ali, Hafiz T.</creatorcontrib><creatorcontrib>Hussain, S.</creatorcontrib><creatorcontrib>Jilani, Asim</creatorcontrib><creatorcontrib>Javed, Yasir</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baloch, Shahzaib</au><au>Umair, Muhammad</au><au>Shad, Naveed Akhtar</au><au>El-Aziz, Khaled Abd</au><au>Ullah, Asmat</au><au>Qi, Fugang</au><au>Ali, Hafiz T.</au><au>Hussain, S.</au><au>Jilani, Asim</au><au>Javed, Yasir</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Amplified Response of Nickel Oxide-Decorated Lanthanum Phosphate Composite as an Anode Material for Asymmetric Supercapacitors</atitle><jtitle>Journal of electronic materials</jtitle><stitle>J. Electron. Mater</stitle><date>2024-12-01</date><risdate>2024</risdate><volume>53</volume><issue>12</issue><spage>7515</spage><epage>7530</epage><pages>7515-7530</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><abstract>The rapidly expanding global population and fast economic growth has led to a shortage of energy and electricity resources. The scarcity of effective energy storage technologies and environmentally friendly electrical power alternatives is one of the greatest concerns in the modern era. Asymmetric supercapacitors have garnered considerable attention due to their versatility in energy storage devices. However, they still require more effective electrode materials with superior electrochemical characteristics to improve their charge storage capacity, energy, and power parameters. To this end, in this work, nickel oxide (NiO), lanthanum phosphate (LaPO
4
), and nickel oxide-decorated lanthanum phosphate (NiO/LaPO
4
) nanosheets were synthesized by a facile hydrothermal method. The purity, crystallinity, and morphology of the materials were investigated using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and x-ray photoelectron spectroscopy (XPS). The NiO-decorated LaPO
4
exhibited superior performance, providing higher specific capacity (
Q
s
) of 1054.4 C/g at 2.0 A/g. The developed electrode also demonstrated excellent electrical conductivity and stability (88% galvanostatic charge/discharge [GCD] retention for 1500 cycles) as determined by electrochemical impedance spectroscopy. The capacitive and diffusive contributions indicate that the fabricated material has an asymmetric storage nature. The results suggest that the prepared material could be used in asymmetric supercapacitor applications.
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| issn | 0361-5235 1543-186X |
| language | eng |
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| source | Springer Online Journals Complete |
| subjects | Alternative energy sources Anodes Asymmetry Characterization and Evaluation of Materials Charge materials Chemistry and Materials Science Decoration Economic development Electric charge Electrical resistivity Electrochemical impedance spectroscopy Electrode materials Electrodes Electronics and Microelectronics Electrons Energy storage Instrumentation Lanthanide phosphates Materials Science Nickel oxides Optical and Electronic Materials Original Research Article Photoelectrons Solid State Physics Spectrum analysis Storage capacity Supercapacitors X ray photoelectron spectroscopy |
| title | Amplified Response of Nickel Oxide-Decorated Lanthanum Phosphate Composite as an Anode Material for Asymmetric Supercapacitors |
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