Is poly(propylene carbonate) biodegradable? Synthesis of poly(propylene carbonate)‐containing star and block copolymers and comprehensive investigation on their biodegradation
Storing CO2 and converting it into valuable substances are crucial for addressing climate change. While poly(propylene carbonate) (PPC), formed through the copolymerization of CO2 and propylene oxide, holds promise in commercial applications, practical limitations arise due to inherent property cons...
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| Veröffentlicht in: | Journal of polymer science (2020) 2024-11, Vol.62 (22), p.4945-4952 |
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| container_title | Journal of polymer science (2020) |
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| creator | Yang, Hee‐Seong Cho, Woo Yeon Seo, Yeong Hyun Chae, Ju‐Hyung Lee, Pyung Cheon Lee, Bun Yeoul Lee, In‐Hwan |
| description | Storing CO2 and converting it into valuable substances are crucial for addressing climate change. While poly(propylene carbonate) (PPC), formed through the copolymerization of CO2 and propylene oxide, holds promise in commercial applications, practical limitations arise due to inherent property constraints. Additionally, the lack of systematic research on PPC biodegradation complicates its post‐use disposal. In this study, we synthesized various polymers, including PPC homopolymers, PPC/castor oil star copolymers, and PPC/poly(l‐lactic acid) multiblock copolymers (PPC‐mb‐PLLAs), not only to mitigate the brittle properties of PPC but also to systematically explore their biodegradability. Both natural soil and industrial composting conditions were employed to assess the biodegradation of the polymers. Furthermore, metagenomic analysis identified the microorganisms responsible for polymer degradation, offering valuable insights into the mechanism of the biodegradation process. |
| doi_str_mv | 10.1002/pol.20240529 |
| format | Article |
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In this study, we synthesized various polymers, including PPC homopolymers, PPC/castor oil star copolymers, and PPC/poly(l‐lactic acid) multiblock copolymers (PPC‐mb‐PLLAs), not only to mitigate the brittle properties of PPC but also to systematically explore their biodegradability. Both natural soil and industrial composting conditions were employed to assess the biodegradation of the polymers. 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Furthermore, metagenomic analysis identified the microorganisms responsible for polymer degradation, offering valuable insights into the mechanism of the biodegradation process.</description><subject>Biodegradation</subject><subject>block copolymer</subject><subject>Block copolymers</subject><subject>carbon dioxide</subject><subject>Castor oil</subject><subject>Chemical synthesis</subject><subject>Composting</subject><subject>Copolymerization</subject><subject>Lactic acid</subject><subject>poly(propylene carbonate)</subject><subject>Polymers</subject><subject>Propylene oxide</subject><subject>Soil analysis</subject><subject>Soil properties</subject><issn>2642-4150</issn><issn>2642-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kc1Kw0AQx4MoWKo3H2DBi4Kt-5kmJynFj0KhgnoOm82k3Zruxt20kpuP4Kv4Sj6JW6viRWFghuH3n_8ME0VHBPcJxvS8tlWfYsqxoOlO1KExpz1O4nT3pxZ4Pzr0foEDzkTMcdyJ3sYeBWV7UjtbtxUYQEq63BrZwCnKtS1g5mQh8wou0F1rmjl47ZEt_1a9v7wqaxqpjTYz5BvpkDQFyiurHpGyG90SnP9sKrusHczBeL0GpM0afKNnstHWoBDBTbtfW2z6B9FeKSsPh1-5Gz1cXd6PbnqT6fV4NJz0FOWJ6CWAiSgJxRxDmohU8ZKlUnBZFnlKmGJyMFAiKcRABJJykHEuVZFgSmLgBFg3Ot7ODTc-rcJe2cKunAmWGSM0SQSJkzRQZ1tKOeu9gzKrnV5K12YEZ5u_ZOHe7PsvAWdb_FlX0P7LZrfTyTA4CcE-AH2Ilco</recordid><startdate>20241115</startdate><enddate>20241115</enddate><creator>Yang, Hee‐Seong</creator><creator>Cho, Woo Yeon</creator><creator>Seo, Yeong Hyun</creator><creator>Chae, Ju‐Hyung</creator><creator>Lee, Pyung Cheon</creator><creator>Lee, Bun Yeoul</creator><creator>Lee, In‐Hwan</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-4848-939X</orcidid></search><sort><creationdate>20241115</creationdate><title>Is poly(propylene carbonate) biodegradable? Synthesis of poly(propylene carbonate)‐containing star and block copolymers and comprehensive investigation on their biodegradation</title><author>Yang, Hee‐Seong ; Cho, Woo Yeon ; Seo, Yeong Hyun ; Chae, Ju‐Hyung ; Lee, Pyung Cheon ; Lee, Bun Yeoul ; Lee, In‐Hwan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2485-8e015f12040e9859c4f39a54afdb913c3a77c58d575e0124ea6bacd80216e41e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Biodegradation</topic><topic>block copolymer</topic><topic>Block copolymers</topic><topic>carbon dioxide</topic><topic>Castor oil</topic><topic>Chemical synthesis</topic><topic>Composting</topic><topic>Copolymerization</topic><topic>Lactic acid</topic><topic>poly(propylene carbonate)</topic><topic>Polymers</topic><topic>Propylene oxide</topic><topic>Soil analysis</topic><topic>Soil properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Hee‐Seong</creatorcontrib><creatorcontrib>Cho, Woo Yeon</creatorcontrib><creatorcontrib>Seo, Yeong Hyun</creatorcontrib><creatorcontrib>Chae, Ju‐Hyung</creatorcontrib><creatorcontrib>Lee, Pyung Cheon</creatorcontrib><creatorcontrib>Lee, Bun Yeoul</creatorcontrib><creatorcontrib>Lee, In‐Hwan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of polymer science (2020)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Hee‐Seong</au><au>Cho, Woo Yeon</au><au>Seo, Yeong Hyun</au><au>Chae, Ju‐Hyung</au><au>Lee, Pyung Cheon</au><au>Lee, Bun Yeoul</au><au>Lee, In‐Hwan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Is poly(propylene carbonate) biodegradable? 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| ispartof | Journal of polymer science (2020), 2024-11, Vol.62 (22), p.4945-4952 |
| issn | 2642-4150 2642-4169 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Biodegradation block copolymer Block copolymers carbon dioxide Castor oil Chemical synthesis Composting Copolymerization Lactic acid poly(propylene carbonate) Polymers Propylene oxide Soil analysis Soil properties |
| title | Is poly(propylene carbonate) biodegradable? Synthesis of poly(propylene carbonate)‐containing star and block copolymers and comprehensive investigation on their biodegradation |
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