Intermolecular Interactions and Isostructurality in the Series of Volatile Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) Complexes with β-Ketoimines

We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures a...

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Veröffentlicht in:Journal of structural chemistry 2024-10, Vol.65 (10), p.1961-1981
Hauptverfasser: Baidina, I. A., Pervukhina, N. V., Gromilov, S. A.
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container_end_page 1981
container_issue 10
container_start_page 1961
container_title Journal of structural chemistry
container_volume 65
creator Baidina, I. A.
Pervukhina, N. V.
Gromilov, S. A.
description We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures and intermolecular interactions of β-ketoiminates with the general formula M (L) 2 (L = ( R 1-C(O)CH-C(N- R 3)- R 2) 2 ; R 1, R 2 = CH 3 , CF 3 , C(CH 3 ) 3 , C(OCH 3 )(CH 2 ) 2 in various combinations; R 3 = H, CH 3 ) are studied.
doi_str_mv 10.1134/S0022476624100081
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subjects Atomic
Atomic/Molecular Structure and Spectra
Chemical analysis
Chemical vapor deposition
Chemistry
Chemistry and Materials Science
Copper
Inorganic Chemistry
Metal films
Molecular
Nickel
Optical and Plasma Physics
Palladium
Physical Chemistry
Platinum
Solid State Physics
title Intermolecular Interactions and Isostructurality in the Series of Volatile Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) Complexes with β-Ketoimines
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