Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide
An aroylhydrazone compound N ’-(5-chloro-2-hydroxybenzylidene)-3-methylbenzohydrazide (H 2 L) has been synthesized and characterized by elemental analysis, infrared and electronic spectra, and 1 H NMR spectrum. With the aroylhydrazone and maltol (HL a ) or ethyl maltol (HL b ) as ligands, two oxidov...
Gespeichert in:
| Veröffentlicht in: | Journal of structural chemistry 2024-10, Vol.65 (10), p.1994-2003 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2003 |
|---|---|
| container_issue | 10 |
| container_start_page | 1994 |
| container_title | Journal of structural chemistry |
| container_volume | 65 |
| creator | Zou, D. -H. Liang, M. Chen, W. |
| description | An aroylhydrazone compound
N
’-(5-chloro-2-hydroxybenzylidene)-3-methylbenzohydrazide (H
2
L) has been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectrum. With the aroylhydrazone and maltol (HL
a
) or ethyl maltol (HL
b
) as ligands, two oxidovanadium(V) complexes, [VOLL
a
] (1) and [VOLL
b
] (2), have been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectra. Structures of the complexes were further confirmed by single crystal X-ray determination. The V atoms in the complexes are coordinated by the ONO donor atoms of the aroylhydrazone ligand L, OO donor atoms of maltolate (L
a
) or ethyl maltolate (L
b
) ligand, and one oxido O atom, forming octahedral coordination. The complexes function as effective olefin epoxidation catalysts with hydrogen peroxide as terminal oxidant and sodium hydrogen carbonate as a co-catalyst. |
| doi_str_mv | 10.1134/S002247662410010X |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3127038025</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3127038025</sourcerecordid><originalsourceid>FETCH-LOGICAL-c198t-5a218b63bc1e50cdaebeca17a381e29eedd5ede77e9e1aa181797ebbc89bb5293</originalsourceid><addsrcrecordid>eNp1kc1OGzEUhS1EpQbaB2BniQ1ImPp6MvF4iYbwI1GQmhaxG3nGN2TQZBxsD4pZ8Rrd82R9kjpKpS6qrq7uPd85d3EIOQB-CpCNv8w4F2IsJxMxBs6BP-yQEeQyY4WUapeMNjLb6B_JnvdPnHNVqMmIvM9iHxboW39CH9g3HWnpog-6o7PghiYMDj3VvaGlTscY2oZOV3bdGh1a21M7p3dpsS-616Ydlkf3x7S0y1WH6-Q7R9e-oKFzZ5f09tfbT3aUs3LRWWeZYFfROLuONfavsWsN9njMMvYVwyJ2m6NdJEC_JuUT-TDXncfPf-Y--XEx_V5esZu7y-vy7IY1oIrAci2gqCdZ3QDmvDEaa2w0SJ0VgEIhGpOjQSlRIWgNBUglsa6bQtV1LlS2Tw63uStnnwf0oXqyg-vTyyoDIXlWcJEnCrZU46z3DufVyrVL7WIFvNqUUf1TRvKIrccntn9E9zf5_6bfWceQWA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3127038025</pqid></control><display><type>article</type><title>Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide</title><source>Springer Nature - Complete Springer Journals</source><creator>Zou, D. -H. ; Liang, M. ; Chen, W.</creator><creatorcontrib>Zou, D. -H. ; Liang, M. ; Chen, W.</creatorcontrib><description>An aroylhydrazone compound
N
’-(5-chloro-2-hydroxybenzylidene)-3-methylbenzohydrazide (H
2
L) has been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectrum. With the aroylhydrazone and maltol (HL
a
) or ethyl maltol (HL
b
) as ligands, two oxidovanadium(V) complexes, [VOLL
a
] (1) and [VOLL
b
] (2), have been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectra. Structures of the complexes were further confirmed by single crystal X-ray determination. The V atoms in the complexes are coordinated by the ONO donor atoms of the aroylhydrazone ligand L, OO donor atoms of maltolate (L
a
) or ethyl maltolate (L
b
) ligand, and one oxido O atom, forming octahedral coordination. The complexes function as effective olefin epoxidation catalysts with hydrogen peroxide as terminal oxidant and sodium hydrogen carbonate as a co-catalyst.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S002247662410010X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic structure ; Atomic/Molecular Structure and Spectra ; Catalysts ; Chemical analysis ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Electronic spectra ; Epoxidation ; Hydrogen peroxide ; Infrared analysis ; Infrared spectra ; Inorganic Chemistry ; Ligands ; Molecular ; NMR ; Nuclear magnetic resonance ; Optical and Plasma Physics ; Oxidizing agents ; Physical Chemistry ; Single crystals ; Sodium bicarbonate ; Solid State Physics ; X ray spectra</subject><ispartof>Journal of structural chemistry, 2024-10, Vol.65 (10), p.1994-2003</ispartof><rights>Pleiades Publishing, Ltd. 2024</rights><rights>Pleiades Publishing, Ltd. 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-5a218b63bc1e50cdaebeca17a381e29eedd5ede77e9e1aa181797ebbc89bb5293</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S002247662410010X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S002247662410010X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Zou, D. -H.</creatorcontrib><creatorcontrib>Liang, M.</creatorcontrib><creatorcontrib>Chen, W.</creatorcontrib><title>Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>An aroylhydrazone compound
N
’-(5-chloro-2-hydroxybenzylidene)-3-methylbenzohydrazide (H
2
L) has been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectrum. With the aroylhydrazone and maltol (HL
a
) or ethyl maltol (HL
b
) as ligands, two oxidovanadium(V) complexes, [VOLL
a
] (1) and [VOLL
b
] (2), have been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectra. Structures of the complexes were further confirmed by single crystal X-ray determination. The V atoms in the complexes are coordinated by the ONO donor atoms of the aroylhydrazone ligand L, OO donor atoms of maltolate (L
a
) or ethyl maltolate (L
b
) ligand, and one oxido O atom, forming octahedral coordination. The complexes function as effective olefin epoxidation catalysts with hydrogen peroxide as terminal oxidant and sodium hydrogen carbonate as a co-catalyst.</description><subject>Atomic</subject><subject>Atomic structure</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Catalysts</subject><subject>Chemical analysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Electronic spectra</subject><subject>Epoxidation</subject><subject>Hydrogen peroxide</subject><subject>Infrared analysis</subject><subject>Infrared spectra</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Optical and Plasma Physics</subject><subject>Oxidizing agents</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Sodium bicarbonate</subject><subject>Solid State Physics</subject><subject>X ray spectra</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kc1OGzEUhS1EpQbaB2BniQ1ImPp6MvF4iYbwI1GQmhaxG3nGN2TQZBxsD4pZ8Rrd82R9kjpKpS6qrq7uPd85d3EIOQB-CpCNv8w4F2IsJxMxBs6BP-yQEeQyY4WUapeMNjLb6B_JnvdPnHNVqMmIvM9iHxboW39CH9g3HWnpog-6o7PghiYMDj3VvaGlTscY2oZOV3bdGh1a21M7p3dpsS-616Ydlkf3x7S0y1WH6-Q7R9e-oKFzZ5f09tfbT3aUs3LRWWeZYFfROLuONfavsWsN9njMMvYVwyJ2m6NdJEC_JuUT-TDXncfPf-Y--XEx_V5esZu7y-vy7IY1oIrAci2gqCdZ3QDmvDEaa2w0SJ0VgEIhGpOjQSlRIWgNBUglsa6bQtV1LlS2Tw63uStnnwf0oXqyg-vTyyoDIXlWcJEnCrZU46z3DufVyrVL7WIFvNqUUf1TRvKIrccntn9E9zf5_6bfWceQWA</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Zou, D. -H.</creator><creator>Liang, M.</creator><creator>Chen, W.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20241001</creationdate><title>Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide</title><author>Zou, D. -H. ; Liang, M. ; Chen, W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-5a218b63bc1e50cdaebeca17a381e29eedd5ede77e9e1aa181797ebbc89bb5293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic</topic><topic>Atomic structure</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Catalysts</topic><topic>Chemical analysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Electronic spectra</topic><topic>Epoxidation</topic><topic>Hydrogen peroxide</topic><topic>Infrared analysis</topic><topic>Infrared spectra</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Optical and Plasma Physics</topic><topic>Oxidizing agents</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Sodium bicarbonate</topic><topic>Solid State Physics</topic><topic>X ray spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zou, D. -H.</creatorcontrib><creatorcontrib>Liang, M.</creatorcontrib><creatorcontrib>Chen, W.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zou, D. -H.</au><au>Liang, M.</au><au>Chen, W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2024-10-01</date><risdate>2024</risdate><volume>65</volume><issue>10</issue><spage>1994</spage><epage>2003</epage><pages>1994-2003</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>An aroylhydrazone compound
N
’-(5-chloro-2-hydroxybenzylidene)-3-methylbenzohydrazide (H
2
L) has been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectrum. With the aroylhydrazone and maltol (HL
a
) or ethyl maltol (HL
b
) as ligands, two oxidovanadium(V) complexes, [VOLL
a
] (1) and [VOLL
b
] (2), have been synthesized and characterized by elemental analysis, infrared and electronic spectra, and
1
H NMR spectra. Structures of the complexes were further confirmed by single crystal X-ray determination. The V atoms in the complexes are coordinated by the ONO donor atoms of the aroylhydrazone ligand L, OO donor atoms of maltolate (L
a
) or ethyl maltolate (L
b
) ligand, and one oxido O atom, forming octahedral coordination. The complexes function as effective olefin epoxidation catalysts with hydrogen peroxide as terminal oxidant and sodium hydrogen carbonate as a co-catalyst.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S002247662410010X</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2024-10, Vol.65 (10), p.1994-2003 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_3127038025 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Atomic Atomic structure Atomic/Molecular Structure and Spectra Catalysts Chemical analysis Chemical synthesis Chemistry Chemistry and Materials Science Crystal structure Electronic spectra Epoxidation Hydrogen peroxide Infrared analysis Infrared spectra Inorganic Chemistry Ligands Molecular NMR Nuclear magnetic resonance Optical and Plasma Physics Oxidizing agents Physical Chemistry Single crystals Sodium bicarbonate Solid State Physics X ray spectra |
| title | Synthesis, X-Ray Crystal Structures and Catalytic Epoxidation of Oxidovanadium(V) Complexes Derived from N’-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-23T10%3A40%3A56IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20X-Ray%20Crystal%20Structures%20and%20Catalytic%20Epoxidation%20of%20Oxidovanadium(V)%20Complexes%20Derived%20from%20N%E2%80%99-(5-Chloro-2-Hydroxybenzylidene)-3-Methylbenzohydrazide&rft.jtitle=Journal%20of%20structural%20chemistry&rft.au=Zou,%20D.%20-H.&rft.date=2024-10-01&rft.volume=65&rft.issue=10&rft.spage=1994&rft.epage=2003&rft.pages=1994-2003&rft.issn=0022-4766&rft.eissn=1573-8779&rft_id=info:doi/10.1134/S002247662410010X&rft_dat=%3Cproquest_cross%3E3127038025%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3127038025&rft_id=info:pmid/&rfr_iscdi=true |