Crystal Structure and Topological Features of Two New Indene Derivatives
7-Bromo-5-( tert -butyl)-2-phenyl-1 H -indene ( 1 ) and 6,7-dibromo-2,4-dimethyl-2,3-dihydro-1 H -inden-1-one ( 2 ) are analyzed by single crystal X-ray diffraction. The conformational structure, vibrational spectrum of molecules, topology and hierarchical complexity of crystal structures are discus...
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| Veröffentlicht in: | Journal of structural chemistry 2024-10, Vol.65 (10), p.2029-2040 |
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| container_issue | 10 |
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| container_title | Journal of structural chemistry |
| container_volume | 65 |
| creator | Kireev, V. E. Banaru, A. M. Bataev, V. A. Kononovich, D. S. Voskoboynikov, A. Z. Aksenov, S. M. |
| description | 7-Bromo-5-(
tert
-butyl)-2-phenyl-1
H
-indene (
1
) and 6,7-dibromo-2,4-dimethyl-2,3-dihydro-1
H
-inden-1-one (
2
) are analyzed by single crystal X-ray diffraction. The conformational structure, vibrational spectrum of molecules, topology and hierarchical complexity of crystal structures are discussed. The structure of
1
is layered and contains (100) molecular layers of the
tts
topological type. The structure of
2
does not contain long molecular ensembles but demonstrates short Br⋯O contacts linking molecules into a centrosymmetric dimer. |
| doi_str_mv | 10.1134/S0022476624100135 |
| format | Article |
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tert
-butyl)-2-phenyl-1
H
-indene (
1
) and 6,7-dibromo-2,4-dimethyl-2,3-dihydro-1
H
-inden-1-one (
2
) are analyzed by single crystal X-ray diffraction. The conformational structure, vibrational spectrum of molecules, topology and hierarchical complexity of crystal structures are discussed. The structure of
1
is layered and contains (100) molecular layers of the
tts
topological type. The structure of
2
does not contain long molecular ensembles but demonstrates short Br⋯O contacts linking molecules into a centrosymmetric dimer.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476624100135</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Crystal structure ; Indene ; Inorganic Chemistry ; Molecular ; Molecular structure ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics ; Topology ; Vibrational spectra</subject><ispartof>Journal of structural chemistry, 2024-10, Vol.65 (10), p.2029-2040</ispartof><rights>Pleiades Publishing, Ltd. 2024</rights><rights>Pleiades Publishing, Ltd. 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-671776cea16d32d04d2926426fb3000fcfd40029b630f4c6d8402f144b95e0633</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476624100135$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476624100135$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Kireev, V. E.</creatorcontrib><creatorcontrib>Banaru, A. M.</creatorcontrib><creatorcontrib>Bataev, V. A.</creatorcontrib><creatorcontrib>Kononovich, D. S.</creatorcontrib><creatorcontrib>Voskoboynikov, A. Z.</creatorcontrib><creatorcontrib>Aksenov, S. M.</creatorcontrib><title>Crystal Structure and Topological Features of Two New Indene Derivatives</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>7-Bromo-5-(
tert
-butyl)-2-phenyl-1
H
-indene (
1
) and 6,7-dibromo-2,4-dimethyl-2,3-dihydro-1
H
-inden-1-one (
2
) are analyzed by single crystal X-ray diffraction. The conformational structure, vibrational spectrum of molecules, topology and hierarchical complexity of crystal structures are discussed. The structure of
1
is layered and contains (100) molecular layers of the
tts
topological type. The structure of
2
does not contain long molecular ensembles but demonstrates short Br⋯O contacts linking molecules into a centrosymmetric dimer.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Indene</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Molecular structure</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Topology</subject><subject>Vibrational spectra</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1UMtKAzEUDaJgrX6Au4Dr0ZtHk8lSqn1A0UXrekjzKFPqpCYzLf17M1RwIa4unNc9HITuCTwSwvjTEoBSLoWgnAAQNrpAAzKSrCilVJdo0NNFz1-jm5S2AKBKJQZoNo6n1OodXraxM20XHdaNxauwD7uwqU1mJk73eMLB49Ux4Dd3xPPGusbhFxfrg27rg0u36MrrXXJ3P3eIPiavq_GsWLxP5-PnRWGIKttCSCKlME4TYRm1wC1VVHAq_JrlUt54y3NXtRYMPDfClhyoJ5yv1ciBYGyIHs65-xi-Opfaahu62OSXFSNUAuNcQVaRs8rEkFJ0vtrH-lPHU0Wg6ger_gyWPfTsSVnbbFz8Tf7f9A2meGrD</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Kireev, V. E.</creator><creator>Banaru, A. M.</creator><creator>Bataev, V. A.</creator><creator>Kononovich, D. S.</creator><creator>Voskoboynikov, A. Z.</creator><creator>Aksenov, S. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20241001</creationdate><title>Crystal Structure and Topological Features of Two New Indene Derivatives</title><author>Kireev, V. E. ; Banaru, A. M. ; Bataev, V. A. ; Kononovich, D. S. ; Voskoboynikov, A. Z. ; Aksenov, S. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-671776cea16d32d04d2926426fb3000fcfd40029b630f4c6d8402f144b95e0633</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Indene</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Molecular structure</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Topology</topic><topic>Vibrational spectra</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kireev, V. E.</creatorcontrib><creatorcontrib>Banaru, A. M.</creatorcontrib><creatorcontrib>Bataev, V. A.</creatorcontrib><creatorcontrib>Kononovich, D. S.</creatorcontrib><creatorcontrib>Voskoboynikov, A. Z.</creatorcontrib><creatorcontrib>Aksenov, S. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kireev, V. E.</au><au>Banaru, A. M.</au><au>Bataev, V. A.</au><au>Kononovich, D. S.</au><au>Voskoboynikov, A. Z.</au><au>Aksenov, S. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal Structure and Topological Features of Two New Indene Derivatives</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2024-10-01</date><risdate>2024</risdate><volume>65</volume><issue>10</issue><spage>2029</spage><epage>2040</epage><pages>2029-2040</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>7-Bromo-5-(
tert
-butyl)-2-phenyl-1
H
-indene (
1
) and 6,7-dibromo-2,4-dimethyl-2,3-dihydro-1
H
-inden-1-one (
2
) are analyzed by single crystal X-ray diffraction. The conformational structure, vibrational spectrum of molecules, topology and hierarchical complexity of crystal structures are discussed. The structure of
1
is layered and contains (100) molecular layers of the
tts
topological type. The structure of
2
does not contain long molecular ensembles but demonstrates short Br⋯O contacts linking molecules into a centrosymmetric dimer.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476624100135</doi><tpages>12</tpages></addata></record> |
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| issn | 0022-4766 1573-8779 |
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| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Crystal structure Indene Inorganic Chemistry Molecular Molecular structure Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics Topology Vibrational spectra |
| title | Crystal Structure and Topological Features of Two New Indene Derivatives |
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