Structural transformation of silver( i )–thiolate coordination polymer film at solid–liquid interfaces

We report that the ligand-exchange reaction between [Ag( o -SPhCO 2 H)] n deposited on a solid substrate and the free p -HSPhCOOH ligand in solution results in crystal transformation from [Ag( o -SPhCO 2 H)] n to [Ag( p -SPhCO 2 H)] n on the substrate. Structural analysis revealed a structural trans...

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Veröffentlicht in:	CrystEngComm 2024-11, Vol.26 (44), p.6269-6273
Hauptverfasser:	Fukuoka, Myu, Takashima, Yohei, Akamatsu, Kensuke, Demessence, Aude, Tsuruoka, Takaaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Coordination polymers Environment and Society Environmental Sciences Ligands Liquid-solid interfaces Polymer films Silver Structural analysis Substrates Topology
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Zusammenfassung:	We report that the ligand-exchange reaction between [Ag( o -SPhCO 2 H)] n deposited on a solid substrate and the free p -HSPhCOOH ligand in solution results in crystal transformation from [Ag( o -SPhCO 2 H)] n to [Ag( p -SPhCO 2 H)] n on the substrate. Structural analysis revealed a structural transformation between CPs with different topologies via ligand exchange.
ISSN:	1466-8033 1466-8033
DOI:	10.1039/D4CE01023J