Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution
Incomplete removal of antibiotics by most known wastewater treatment plants is a global challenge. Therefore, graphitic carbon nitride-modified cerium ferrite (CeFe 2 O 4 @g-C 3 N 4 ) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe 2 O 4 @g-C 3 N 4...
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| Veröffentlicht in: | International journal of mechanical and materials engineering 2024-12, Vol.19 (1), p.37, Article 37 |
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| creator | Adewuyi, Adewale Oderinde, Rotimi A. |
| description | Incomplete removal of antibiotics by most known wastewater treatment plants is a global challenge. Therefore, graphitic carbon nitride-modified cerium ferrite (CeFe
2
O
4
@g-C
3
N
4
) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe
2
O
4
@g-C
3
N
4
showed activity in the visible light with a Tauc plot revealing the bandgap energy (2.46 eV). The scanning electron micrograph (SEM) result revealed the surface of CeFe
2
O
4
@g-C
3
N
4
to be heterogeneous, while the transmission electron micrograph (TEM) image confirmed a flaky with rod and oval shaped surface (average particle size of 42.22 nm). CeFe
2
O
4
@g-C
3
N
4
exhibited a 100% removal of all the studied antibiotics from aqueous solution in a photocatalytic degradation that is described by pseudo-1st-order kinetics. CeFe
2
O
4
@g-C
3
N
4
demonstrated a high regeneration capacity, which is above 90% at the 12th cycle of treatment without any observable changes in its phase structure which suggests a promising chemical stability and reusability. CeFe
2
O
4
@g-C
3
N
4
compared favourably with some selected antibiotic degradable photocatalysts suggesting the economic viable of CeFe
2
O
4
@g-C
3
N
4
as photocatalyst for the purification of antibiotics-contaminated water.
Graphical Abstract |
| doi_str_mv | 10.1186/s40712-024-00183-7 |
| format | Article |
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2
O
4
@g-C
3
N
4
) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe
2
O
4
@g-C
3
N
4
showed activity in the visible light with a Tauc plot revealing the bandgap energy (2.46 eV). The scanning electron micrograph (SEM) result revealed the surface of CeFe
2
O
4
@g-C
3
N
4
to be heterogeneous, while the transmission electron micrograph (TEM) image confirmed a flaky with rod and oval shaped surface (average particle size of 42.22 nm). CeFe
2
O
4
@g-C
3
N
4
exhibited a 100% removal of all the studied antibiotics from aqueous solution in a photocatalytic degradation that is described by pseudo-1st-order kinetics. CeFe
2
O
4
@g-C
3
N
4
demonstrated a high regeneration capacity, which is above 90% at the 12th cycle of treatment without any observable changes in its phase structure which suggests a promising chemical stability and reusability. CeFe
2
O
4
@g-C
3
N
4
compared favourably with some selected antibiotic degradable photocatalysts suggesting the economic viable of CeFe
2
O
4
@g-C
3
N
4
as photocatalyst for the purification of antibiotics-contaminated water.
Graphical Abstract</description><identifier>ISSN: 3004-8958</identifier><identifier>ISSN: 1823-0334</identifier><identifier>EISSN: 3004-8958</identifier><identifier>EISSN: 2198-2791</identifier><identifier>DOI: 10.1186/s40712-024-00183-7</identifier><language>eng</language><publisher>Singapore: Springer Nature Singapore</publisher><subject>Ampicillin ; Antibiotics ; Aqueous solutions ; Boron nitride ; Carbon ; Carbon nitride ; Cerium ; Ciprofloxacin ; Electron micrographs ; Engineering ; Erythromycin ; Ferrites ; Iron compounds ; Mechanical Engineering ; Original Paper ; Photocatalysis ; Photocatalysts ; Photodegradation ; Purification ; Sewage ; Solid phases ; Structural Materials ; Theoretical and Applied Mechanics ; Wastewater ; Wastewater treatment ; Water purification ; Water treatment plants</subject><ispartof>International journal of mechanical and materials engineering, 2024-12, Vol.19 (1), p.37, Article 37</ispartof><rights>The Author(s) 2024</rights><rights>COPYRIGHT 2024 Springer</rights><rights>The Author(s) 2024. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c311t-91c4f4f8c4c85c7bd705e0e484bf70104fd251f5643b4bcfc8bb2ca74f5328013</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Adewuyi, Adewale</creatorcontrib><creatorcontrib>Oderinde, Rotimi A.</creatorcontrib><title>Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution</title><title>International journal of mechanical and materials engineering</title><addtitle>J Mater. Sci: Mater Eng</addtitle><description>Incomplete removal of antibiotics by most known wastewater treatment plants is a global challenge. Therefore, graphitic carbon nitride-modified cerium ferrite (CeFe
2
O
4
@g-C
3
N
4
) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe
2
O
4
@g-C
3
N
4
showed activity in the visible light with a Tauc plot revealing the bandgap energy (2.46 eV). The scanning electron micrograph (SEM) result revealed the surface of CeFe
2
O
4
@g-C
3
N
4
to be heterogeneous, while the transmission electron micrograph (TEM) image confirmed a flaky with rod and oval shaped surface (average particle size of 42.22 nm). CeFe
2
O
4
@g-C
3
N
4
exhibited a 100% removal of all the studied antibiotics from aqueous solution in a photocatalytic degradation that is described by pseudo-1st-order kinetics. CeFe
2
O
4
@g-C
3
N
4
demonstrated a high regeneration capacity, which is above 90% at the 12th cycle of treatment without any observable changes in its phase structure which suggests a promising chemical stability and reusability. CeFe
2
O
4
@g-C
3
N
4
compared favourably with some selected antibiotic degradable photocatalysts suggesting the economic viable of CeFe
2
O
4
@g-C
3
N
4
as photocatalyst for the purification of antibiotics-contaminated water.
Graphical Abstract</description><subject>Ampicillin</subject><subject>Antibiotics</subject><subject>Aqueous solutions</subject><subject>Boron nitride</subject><subject>Carbon</subject><subject>Carbon nitride</subject><subject>Cerium</subject><subject>Ciprofloxacin</subject><subject>Electron micrographs</subject><subject>Engineering</subject><subject>Erythromycin</subject><subject>Ferrites</subject><subject>Iron compounds</subject><subject>Mechanical Engineering</subject><subject>Original Paper</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Purification</subject><subject>Sewage</subject><subject>Solid phases</subject><subject>Structural Materials</subject><subject>Theoretical and Applied Mechanics</subject><subject>Wastewater</subject><subject>Wastewater treatment</subject><subject>Water purification</subject><subject>Water treatment plants</subject><issn>3004-8958</issn><issn>1823-0334</issn><issn>3004-8958</issn><issn>2198-2791</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kc2KFDEUhQtRcBjnBVwF3FpjfrtS7oZBR2HAja5DKrm3O1KVlEkK7OfxRU1PCbqSBHJJzndy4HTda0ZvGdOHd0XSgfGectlTyrToh2fdlaBU9npU-vk_88vuppQwUSXFeOADv-p-PWS7nkINjjibpxRJDDUHD_2SfMAAnjjIYVsIQs6hwntiIwHE4ALEStZTqsnZaudzqQRTJvUExMMxW29raH4JiQtrTjinn9aF-JbYZW30PD_N0RPI53rKaTm3V9K2_bFB2gopad4uFq-6F2jnAjd_zuvu28cPX-8_9Y9fHj7f3z32TjBW-5E5iRK1k04rN0x-oAooSC0nHCijEj1XDNVBiklODp2eJu7sIFEJrikT192b3belbRFKNd_TlmP70gjG5dhIRZvqdlcd7QwmREw1W9eWhyW4FAFDu7_TTDEh6Dg0gO-Ay6mUDGjWHBabz4ZRcynQ7AWaVqB5KtBcILFDpYnjEfLfLP-hfgNy4qIA</recordid><startdate>20241201</startdate><enddate>20241201</enddate><creator>Adewuyi, Adewale</creator><creator>Oderinde, Rotimi A.</creator><general>Springer Nature Singapore</general><general>Springer</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>IAO</scope><scope>7TB</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FR3</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20241201</creationdate><title>Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution</title><author>Adewuyi, Adewale ; Oderinde, Rotimi A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-91c4f4f8c4c85c7bd705e0e484bf70104fd251f5643b4bcfc8bb2ca74f5328013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Ampicillin</topic><topic>Antibiotics</topic><topic>Aqueous solutions</topic><topic>Boron nitride</topic><topic>Carbon</topic><topic>Carbon nitride</topic><topic>Cerium</topic><topic>Ciprofloxacin</topic><topic>Electron micrographs</topic><topic>Engineering</topic><topic>Erythromycin</topic><topic>Ferrites</topic><topic>Iron compounds</topic><topic>Mechanical Engineering</topic><topic>Original Paper</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Purification</topic><topic>Sewage</topic><topic>Solid phases</topic><topic>Structural Materials</topic><topic>Theoretical and Applied Mechanics</topic><topic>Wastewater</topic><topic>Wastewater treatment</topic><topic>Water purification</topic><topic>Water treatment plants</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Adewuyi, Adewale</creatorcontrib><creatorcontrib>Oderinde, Rotimi A.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>CrossRef</collection><collection>Gale Academic OneFile</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>International journal of mechanical and materials engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Adewuyi, Adewale</au><au>Oderinde, Rotimi A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution</atitle><jtitle>International journal of mechanical and materials engineering</jtitle><stitle>J Mater. Sci: Mater Eng</stitle><date>2024-12-01</date><risdate>2024</risdate><volume>19</volume><issue>1</issue><spage>37</spage><pages>37-</pages><artnum>37</artnum><issn>3004-8958</issn><issn>1823-0334</issn><eissn>3004-8958</eissn><eissn>2198-2791</eissn><abstract>Incomplete removal of antibiotics by most known wastewater treatment plants is a global challenge. Therefore, graphitic carbon nitride-modified cerium ferrite (CeFe
2
O
4
@g-C
3
N
4
) was synthesized to remove antibiotics (ampicillin, ciprofloxacin and erythromycin) from water. CeFe
2
O
4
@g-C
3
N
4
showed activity in the visible light with a Tauc plot revealing the bandgap energy (2.46 eV). The scanning electron micrograph (SEM) result revealed the surface of CeFe
2
O
4
@g-C
3
N
4
to be heterogeneous, while the transmission electron micrograph (TEM) image confirmed a flaky with rod and oval shaped surface (average particle size of 42.22 nm). CeFe
2
O
4
@g-C
3
N
4
exhibited a 100% removal of all the studied antibiotics from aqueous solution in a photocatalytic degradation that is described by pseudo-1st-order kinetics. CeFe
2
O
4
@g-C
3
N
4
demonstrated a high regeneration capacity, which is above 90% at the 12th cycle of treatment without any observable changes in its phase structure which suggests a promising chemical stability and reusability. CeFe
2
O
4
@g-C
3
N
4
compared favourably with some selected antibiotic degradable photocatalysts suggesting the economic viable of CeFe
2
O
4
@g-C
3
N
4
as photocatalyst for the purification of antibiotics-contaminated water.
Graphical Abstract</abstract><cop>Singapore</cop><pub>Springer Nature Singapore</pub><doi>10.1186/s40712-024-00183-7</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | International journal of mechanical and materials engineering, 2024-12, Vol.19 (1), p.37, Article 37 |
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| language | eng |
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| source | Springer Nature OA Free Journals; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings |
| subjects | Ampicillin Antibiotics Aqueous solutions Boron nitride Carbon Carbon nitride Cerium Ciprofloxacin Electron micrographs Engineering Erythromycin Ferrites Iron compounds Mechanical Engineering Original Paper Photocatalysis Photocatalysts Photodegradation Purification Sewage Solid phases Structural Materials Theoretical and Applied Mechanics Wastewater Wastewater treatment Water purification Water treatment plants |
| title | Graphitic carbon nitride-modified cerium ferrite: an efficient photocatalyst for the degradation of ciprofloxacin, ampicillin, and erythromycin in aqueous solution |
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