An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation
In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl 2 on the surface of magnetic Fe 3 O 4 nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe 3 O 4 @Catechol/PZ-Phen-MnCl 2 ], then we evaluated its catalytic performanc...
Gespeichert in:
| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2024, Vol.34 (9), p.4100-4115 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4115 |
|---|---|
| container_issue | 9 |
| container_start_page | 4100 |
| container_title | Journal of inorganic and organometallic polymers and materials |
| container_volume | 34 |
| creator | Liu, Ying Zhang, Huili |
| description | In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl
2
on the surface of magnetic Fe
3
O
4
nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
], then we evaluated its catalytic performance in the synthesis of propargyl amines through the A
3
and KA
2
-coupling three-component reactions aromatic aldehydes or ketones, with alkynes, and amines. FT-IR, SEM, TEM, EDX, XRD, TGA, VSM, ICP-OES and elemental mapping analyzes confirmed the successful synthesis of Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocatalyst. The results of the coupling reactions confirmed that the Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocomposite is a very efficient catalyst for the preparation of various derivatives of propargyl amines. This method has significant features compared to the previous methods, which can be mentioned as follows: synthesis of products with very high efficiency, carrying out the reaction under mild conditions and compatible with the environment, using green and recyclable catalyst, can being applicable to a wide range of substrates and providing NMR analysis for all propargyl amine products.
Graphical Abstract |
| doi_str_mv | 10.1007/s10904-024-03086-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3122170604</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3122170604</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-f54080474da3bb07c867cd9a4f008237894b7971bde7a58f1f854892e3de559e3</originalsourceid><addsrcrecordid>eNp9kcFqGzEQhpeSQpO0L9CTIOdtRiutpe3NMXEaiJ1S2rOY3R25a9aSK8kBP09etLIdklsOYjTD__0z8BfFVw7fOIC6jhwakCVU-QnQk1J-KM55rWTJZc3PXv9SfCouYlwDCA01Py-ep45NUwrYpeGJGLqe3Vo7dAO5xBaU_vqeWR_Yz0BbDJgG75i3ufW5Xe1HNt0MjuL3gyBm5lWBbOmfaGQLXDlKQ4fjuGe_aBexHSlP3QozR2yJzneYcNzHdNw0K5fsxuc75j5sjnafi48Wx0hfXupl8Wd--3v2o3x4vLufTR_KTvAmlbaWoEEq2aNoW1Cdnqiub1BaAF0JpRvZqkbxtieFtbbc6lrqpiLRU103JC6Lq5PvNvh_O4rJrP0uuLzSCF5VXMEEZFZVJ1UXfIyBrNmGYYNhbziYQxjmFIbJYZhjGOYAiRMUs9itKLxZv0P9Bx-Cjis</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3122170604</pqid></control><display><type>article</type><title>An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation</title><source>SpringerNature Journals</source><creator>Liu, Ying ; Zhang, Huili</creator><creatorcontrib>Liu, Ying ; Zhang, Huili</creatorcontrib><description>In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl
2
on the surface of magnetic Fe
3
O
4
nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
], then we evaluated its catalytic performance in the synthesis of propargyl amines through the A
3
and KA
2
-coupling three-component reactions aromatic aldehydes or ketones, with alkynes, and amines. FT-IR, SEM, TEM, EDX, XRD, TGA, VSM, ICP-OES and elemental mapping analyzes confirmed the successful synthesis of Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocatalyst. The results of the coupling reactions confirmed that the Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocomposite is a very efficient catalyst for the preparation of various derivatives of propargyl amines. This method has significant features compared to the previous methods, which can be mentioned as follows: synthesis of products with very high efficiency, carrying out the reaction under mild conditions and compatible with the environment, using green and recyclable catalyst, can being applicable to a wide range of substrates and providing NMR analysis for all propargyl amine products.
Graphical Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-024-03086-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aldehydes ; Alkynes ; Amines ; Catalysts ; Catechol ; Chemical reactions ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coupling ; Inorganic Chemistry ; Iron oxides ; Ketones ; Manganese ; Nanocomposites ; NMR ; Nuclear magnetic resonance ; Organic Chemistry ; Polymer Sciences ; Research projects</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2024, Vol.34 (9), p.4100-4115</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-f54080474da3bb07c867cd9a4f008237894b7971bde7a58f1f854892e3de559e3</citedby><cites>FETCH-LOGICAL-c319t-f54080474da3bb07c867cd9a4f008237894b7971bde7a58f1f854892e3de559e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-024-03086-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-024-03086-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Liu, Ying</creatorcontrib><creatorcontrib>Zhang, Huili</creatorcontrib><title>An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl
2
on the surface of magnetic Fe
3
O
4
nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
], then we evaluated its catalytic performance in the synthesis of propargyl amines through the A
3
and KA
2
-coupling three-component reactions aromatic aldehydes or ketones, with alkynes, and amines. FT-IR, SEM, TEM, EDX, XRD, TGA, VSM, ICP-OES and elemental mapping analyzes confirmed the successful synthesis of Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocatalyst. The results of the coupling reactions confirmed that the Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocomposite is a very efficient catalyst for the preparation of various derivatives of propargyl amines. This method has significant features compared to the previous methods, which can be mentioned as follows: synthesis of products with very high efficiency, carrying out the reaction under mild conditions and compatible with the environment, using green and recyclable catalyst, can being applicable to a wide range of substrates and providing NMR analysis for all propargyl amine products.
Graphical Abstract</description><subject>Aldehydes</subject><subject>Alkynes</subject><subject>Amines</subject><subject>Catalysts</subject><subject>Catechol</subject><subject>Chemical reactions</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coupling</subject><subject>Inorganic Chemistry</subject><subject>Iron oxides</subject><subject>Ketones</subject><subject>Manganese</subject><subject>Nanocomposites</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Organic Chemistry</subject><subject>Polymer Sciences</subject><subject>Research projects</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kcFqGzEQhpeSQpO0L9CTIOdtRiutpe3NMXEaiJ1S2rOY3R25a9aSK8kBP09etLIdklsOYjTD__0z8BfFVw7fOIC6jhwakCVU-QnQk1J-KM55rWTJZc3PXv9SfCouYlwDCA01Py-ep45NUwrYpeGJGLqe3Vo7dAO5xBaU_vqeWR_Yz0BbDJgG75i3ufW5Xe1HNt0MjuL3gyBm5lWBbOmfaGQLXDlKQ4fjuGe_aBexHSlP3QozR2yJzneYcNzHdNw0K5fsxuc75j5sjnafi48Wx0hfXupl8Wd--3v2o3x4vLufTR_KTvAmlbaWoEEq2aNoW1Cdnqiub1BaAF0JpRvZqkbxtieFtbbc6lrqpiLRU103JC6Lq5PvNvh_O4rJrP0uuLzSCF5VXMEEZFZVJ1UXfIyBrNmGYYNhbziYQxjmFIbJYZhjGOYAiRMUs9itKLxZv0P9Bx-Cjis</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Liu, Ying</creator><creator>Zhang, Huili</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2024</creationdate><title>An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation</title><author>Liu, Ying ; Zhang, Huili</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-f54080474da3bb07c867cd9a4f008237894b7971bde7a58f1f854892e3de559e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aldehydes</topic><topic>Alkynes</topic><topic>Amines</topic><topic>Catalysts</topic><topic>Catechol</topic><topic>Chemical reactions</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coupling</topic><topic>Inorganic Chemistry</topic><topic>Iron oxides</topic><topic>Ketones</topic><topic>Manganese</topic><topic>Nanocomposites</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Organic Chemistry</topic><topic>Polymer Sciences</topic><topic>Research projects</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Ying</creatorcontrib><creatorcontrib>Zhang, Huili</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Ying</au><au>Zhang, Huili</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2024</date><risdate>2024</risdate><volume>34</volume><issue>9</issue><spage>4100</spage><epage>4115</epage><pages>4100-4115</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>In this research project, we first synthesized the magnetic manganese nanocatalyst by immobilizing the MnCl
2
on the surface of magnetic Fe
3
O
4
nanoparticles modified with catechol and piperazine/phenanthroline ligand [Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
], then we evaluated its catalytic performance in the synthesis of propargyl amines through the A
3
and KA
2
-coupling three-component reactions aromatic aldehydes or ketones, with alkynes, and amines. FT-IR, SEM, TEM, EDX, XRD, TGA, VSM, ICP-OES and elemental mapping analyzes confirmed the successful synthesis of Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocatalyst. The results of the coupling reactions confirmed that the Fe
3
O
4
@Catechol/PZ-Phen-MnCl
2
nanocomposite is a very efficient catalyst for the preparation of various derivatives of propargyl amines. This method has significant features compared to the previous methods, which can be mentioned as follows: synthesis of products with very high efficiency, carrying out the reaction under mild conditions and compatible with the environment, using green and recyclable catalyst, can being applicable to a wide range of substrates and providing NMR analysis for all propargyl amine products.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-024-03086-4</doi><tpages>16</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1574-1443 |
| ispartof | Journal of inorganic and organometallic polymers and materials, 2024, Vol.34 (9), p.4100-4115 |
| issn | 1574-1443 1574-1451 |
| language | eng |
| recordid | cdi_proquest_journals_3122170604 |
| source | SpringerNature Journals |
| subjects | Aldehydes Alkynes Amines Catalysts Catechol Chemical reactions Chemical synthesis Chemistry Chemistry and Materials Science Coupling Inorganic Chemistry Iron oxides Ketones Manganese Nanocomposites NMR Nuclear magnetic resonance Organic Chemistry Polymer Sciences Research projects |
| title | An Attractive and Efficient Method for Preparation of Propargyl Amines: Presentation of a Novel Magnetically Reusable Manganese Nanocatalyst for C-N Bond Formation |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T17%3A28%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20Attractive%20and%20Efficient%20Method%20for%20Preparation%20of%20Propargyl%20Amines:%20Presentation%20of%20a%20Novel%20Magnetically%20Reusable%20Manganese%20Nanocatalyst%20for%20C-N%20Bond%20Formation&rft.jtitle=Journal%20of%20inorganic%20and%20organometallic%20polymers%20and%20materials&rft.au=Liu,%20Ying&rft.date=2024&rft.volume=34&rft.issue=9&rft.spage=4100&rft.epage=4115&rft.pages=4100-4115&rft.issn=1574-1443&rft.eissn=1574-1451&rft_id=info:doi/10.1007/s10904-024-03086-4&rft_dat=%3Cproquest_cross%3E3122170604%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3122170604&rft_id=info:pmid/&rfr_iscdi=true |