Copper(I) Catalysed Diboron(4) Reduction of Nitrous Oxide

A process for the catalytic reduction of nitrous oxide using NHC‐ligated copper(I) tert‐butoxide precatalysts and B2pin2 as the reductant is reported. These reactions proceed under mild conditions via copper(I)‐boryl intermediates which react with N2O by facile O‐atom insertion into the Cu−B bond an...

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Veröffentlicht in:	Angewandte Chemie 2024-11, Vol.136 (45), p.n/a
Hauptverfasser:	Hood, Thomas M., Charman, Rex S. C., Liptrot, David J., Chaplin, Adrian B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Boryl ligands Carbene ligands Catalysis Chemical reduction Copper Intermediates Nitrous oxide Reducing agents
Online-Zugang:	Volltext
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