Differences Photopolymerizations and Characterizations of Monomers Liquid Crystal between Mesogen Reactive RM 257 and Cholesteryl Acrylate using method of UV Curing

Mesogen reactive RM257 and cholesteryl acrylate are two types of liquid crystal with the characteristic property of possesing polymerizable groups. Cholesteryl acrylate has interesting properties that can form a helical spiral structure. Previous research in maintaining the helical structure has not...

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Veröffentlicht in:Journal of physics. Conference series 2024-10, Vol.2866 (1), p.12012
Hauptverfasser: Afrizal, Budi, Setia, Riswoko, Asep, Lestari, Fuji, Ningsih, Selvia
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Budi, Setia
Riswoko, Asep
Lestari, Fuji
Ningsih, Selvia
description Mesogen reactive RM257 and cholesteryl acrylate are two types of liquid crystal with the characteristic property of possesing polymerizable groups. Cholesteryl acrylate has interesting properties that can form a helical spiral structure. Previous research in maintaining the helical structure has not been maximized. In this study, we will explain how the UV curing process is a way to fix the helical structure. Monomer phase of cholesteryl acrylate only appears at mesophase temperature, in order to maintain the helical structure of the cholesterl acrylic compound is polymerized. Mesogen reactive RM257 is monomer liquid crystal that acrylate functions as back bone polymer chain. Cholesteryl acrylate and RM257 each monomers is polymerized using UV light with 55 watt of wavelength which has 365 nm. The polymerization process produces a new functional group formed by C-O esters at wave numbers 1047 cm −1 and 1055 cm −1 . XRD diffraction pattern showed peaks at 2θ in 7.5°,15°, and 20°. Photo SEM image showed crosslinked morphology structure. Based on the results of this study, it is hoped that the polymer RM257 and acrylate coliform can be smart materials for sensor applications and further technological material composites.
doi_str_mv 10.1088/1742-6596/2866/1/012012
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subjects Crystal structure
Curing
Diffraction patterns
Esters
Functional groups
Liquid crystals
Monomers
Polymerization
Polymers
Smart materials
Ultraviolet radiation
Wave diffraction
title Differences Photopolymerizations and Characterizations of Monomers Liquid Crystal between Mesogen Reactive RM 257 and Cholesteryl Acrylate using method of UV Curing
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