Intramolecular interaction induced C-C cleavages in fructose conversion in polar aprotic solvents-origin of the formation of excess formic acid and oligomers

Understanding the mechanism of excess formic acid formation in the dehydration of fructose to HMF would be beneficial to improve HMF selectivity and carbon efficiency. The production of formic acid from keto- d -fructose in polar aprotic solvents, such as THF, DIO, and MTHF, and MIBK solvents withou...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2024-10, Vol.26 (41), p.26537-26549
Hauptverfasser:	Ge, Chenyu, Sun, Qianxin, Zhang, Ruoyu, Zhu, Liangfang, Hu, Changwei
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetic acid Acids Boiling points Carbon Catalysis Chemical bonds Dehydration Formic acid Fructose Molecular chains Molecular dynamics Oligomers Solvents
Online-Zugang:	Volltext
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