Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3
The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3,...
Gespeichert in:
| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2024-10, Vol.650 (19), p.n/a |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | n/a |
|---|---|
| container_issue | 19 |
| container_start_page | |
| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
| container_volume | 650 |
| creator | Friedrich, Ute Schmidt, Franz Korber, Nikolaus |
| description | The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3, [K@[18]crown‐6]1.5[Cs@[18]crown‐6][Cs@([18]crown‐6)2]0.5[Sn5Bi3] ⋅ 3.98NH3, [Na@DB[18]crown‐6]2[Na(NH3)6][Sn5Bi3] ⋅ 14NH3 and [Cs@[2.2.2]crypt]6[Sn5Bi3]2 ⋅ 9.53NH3. The [Sn5Bi3]3− anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure. |
| doi_str_mv | 10.1002/zaac.202400086 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3117385520</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3117385520</sourcerecordid><originalsourceid>FETCH-LOGICAL-c2426-8efadf1962a377e01272dda2f8c3b648a1d0726ec6807f5091e4c45ccd0e7b463</originalsourceid><addsrcrecordid>eNqFkM1Kw0AURgdRsFa3rgOuU-_8J8s2-AcFF1UQRYbpZMZOiUmdSZF05SP4jD6JKRVdurqbc74LB6FTDCMMQM43WpsRAcIAIBN7aIA5wSmVLN9HAwDGUkIxPURHMS57BAPnAzSZdXW7sNHHRNdlMvP1S2WTInSx1VXy8PXxGXSXFAsdtGlt8Bvd-qZOGpc8zWo-8fSZHqMDp6toT37uEN1fXtwV1-n09uqmGE9TQxgRaWadLh3OBdFUSguYSFKWmrjM0LlgmcYlSCKsERlIxyHHlhnGjSnByjkTdIjOdrur0LytbWzVslmHun-pKMaSZpwT6KnRjjKhiTFYp1bBv-rQKQxq20ltO6nfTr2Q74R3X9nuH1o9jsfFn_sNSYxrqQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3117385520</pqid></control><display><type>article</type><title>Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3</title><source>Access via Wiley Online Library</source><creator>Friedrich, Ute ; Schmidt, Franz ; Korber, Nikolaus</creator><creatorcontrib>Friedrich, Ute ; Schmidt, Franz ; Korber, Nikolaus</creatorcontrib><description>The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3, [K@[18]crown‐6]1.5[Cs@[18]crown‐6][Cs@([18]crown‐6)2]0.5[Sn5Bi3] ⋅ 3.98NH3, [Na@DB[18]crown‐6]2[Na(NH3)6][Sn5Bi3] ⋅ 14NH3 and [Cs@[2.2.2]crypt]6[Sn5Bi3]2 ⋅ 9.53NH3. The [Sn5Bi3]3− anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.202400086</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>alkali metals ; Ammonia ; Anions ; Chelating agents ; Chelation ; Crystallization ; Electronic structure ; heterometallic clusters ; Liquid ammonia ; Mass spectrometry ; Single crystals ; tinbismuthide ; Zintl phase</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2024-10, Vol.650 (19), p.n/a</ispartof><rights>2024 The Author(s). Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH</rights><rights>2024. This article is published under http://creativecommons.org/licenses/by-nc/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c2426-8efadf1962a377e01272dda2f8c3b648a1d0726ec6807f5091e4c45ccd0e7b463</cites><orcidid>0000-0002-1880-8126</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.202400086$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.202400086$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Friedrich, Ute</creatorcontrib><creatorcontrib>Schmidt, Franz</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><title>Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3, [K@[18]crown‐6]1.5[Cs@[18]crown‐6][Cs@([18]crown‐6)2]0.5[Sn5Bi3] ⋅ 3.98NH3, [Na@DB[18]crown‐6]2[Na(NH3)6][Sn5Bi3] ⋅ 14NH3 and [Cs@[2.2.2]crypt]6[Sn5Bi3]2 ⋅ 9.53NH3. The [Sn5Bi3]3− anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.</description><subject>alkali metals</subject><subject>Ammonia</subject><subject>Anions</subject><subject>Chelating agents</subject><subject>Chelation</subject><subject>Crystallization</subject><subject>Electronic structure</subject><subject>heterometallic clusters</subject><subject>Liquid ammonia</subject><subject>Mass spectrometry</subject><subject>Single crystals</subject><subject>tinbismuthide</subject><subject>Zintl phase</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkM1Kw0AURgdRsFa3rgOuU-_8J8s2-AcFF1UQRYbpZMZOiUmdSZF05SP4jD6JKRVdurqbc74LB6FTDCMMQM43WpsRAcIAIBN7aIA5wSmVLN9HAwDGUkIxPURHMS57BAPnAzSZdXW7sNHHRNdlMvP1S2WTInSx1VXy8PXxGXSXFAsdtGlt8Bvd-qZOGpc8zWo-8fSZHqMDp6toT37uEN1fXtwV1-n09uqmGE9TQxgRaWadLh3OBdFUSguYSFKWmrjM0LlgmcYlSCKsERlIxyHHlhnGjSnByjkTdIjOdrur0LytbWzVslmHun-pKMaSZpwT6KnRjjKhiTFYp1bBv-rQKQxq20ltO6nfTr2Q74R3X9nuH1o9jsfFn_sNSYxrqQ</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Friedrich, Ute</creator><creator>Schmidt, Franz</creator><creator>Korber, Nikolaus</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1880-8126</orcidid></search><sort><creationdate>20241001</creationdate><title>Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3</title><author>Friedrich, Ute ; Schmidt, Franz ; Korber, Nikolaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2426-8efadf1962a377e01272dda2f8c3b648a1d0726ec6807f5091e4c45ccd0e7b463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>alkali metals</topic><topic>Ammonia</topic><topic>Anions</topic><topic>Chelating agents</topic><topic>Chelation</topic><topic>Crystallization</topic><topic>Electronic structure</topic><topic>heterometallic clusters</topic><topic>Liquid ammonia</topic><topic>Mass spectrometry</topic><topic>Single crystals</topic><topic>tinbismuthide</topic><topic>Zintl phase</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Friedrich, Ute</creatorcontrib><creatorcontrib>Schmidt, Franz</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><collection>Wiley Online Library Open Access</collection><collection>Wiley Online Library (Open Access Collection)</collection><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Friedrich, Ute</au><au>Schmidt, Franz</au><au>Korber, Nikolaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2024-10-01</date><risdate>2024</risdate><volume>650</volume><issue>19</issue><epage>n/a</epage><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3, [K@[18]crown‐6]1.5[Cs@[18]crown‐6][Cs@([18]crown‐6)2]0.5[Sn5Bi3] ⋅ 3.98NH3, [Na@DB[18]crown‐6]2[Na(NH3)6][Sn5Bi3] ⋅ 14NH3 and [Cs@[2.2.2]crypt]6[Sn5Bi3]2 ⋅ 9.53NH3. The [Sn5Bi3]3− anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/zaac.202400086</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-1880-8126</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0044-2313 |
| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 2024-10, Vol.650 (19), p.n/a |
| issn | 0044-2313 1521-3749 |
| language | eng |
| recordid | cdi_proquest_journals_3117385520 |
| source | Access via Wiley Online Library |
| subjects | alkali metals Ammonia Anions Chelating agents Chelation Crystallization Electronic structure heterometallic clusters Liquid ammonia Mass spectrometry Single crystals tinbismuthide Zintl phase |
| title | Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T15%3A16%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Single%20Crystal%20X%E2%80%90ray%20Characterization%20of%20%5BSn5Bi3%5D3&rft.jtitle=Zeitschrift%20f%C3%BCr%20anorganische%20und%20allgemeine%20Chemie%20(1950)&rft.au=Friedrich,%20Ute&rft.date=2024-10-01&rft.volume=650&rft.issue=19&rft.epage=n/a&rft.issn=0044-2313&rft.eissn=1521-3749&rft_id=info:doi/10.1002/zaac.202400086&rft_dat=%3Cproquest_cross%3E3117385520%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3117385520&rft_id=info:pmid/&rfr_iscdi=true |