Device-Free Colorimetric Sensing of Lead in Water by Kinetically Trapping Lead(II) Rhodizonate into a Solid-solution of Cellulose Paper
Anthropogenic lead pollution remains a serious environmental concern due to the high incidence of human exposure worldwide and its severe health impact, particularly to children. We report a device-free colorimetric sensor for lead(II) ions in water based on the microdrop detection of the lead(II) r...
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| Veröffentlicht in: | Sensing and imaging 2024-10, Vol.25 (1), Article 61 |
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| creator | Sultana, Kazi Afroza Hernandez, Javier Sheets, Shane Biswas, Manik Chandra Kikumoto Dias, Juliana Ariza, Melissa Islam, Md Tariqul Noveron, Juan C. |
| description | Anthropogenic lead pollution remains a serious environmental concern due to the high incidence of human exposure worldwide and its severe health impact, particularly to children. We report a device-free colorimetric sensor for lead(II) ions in water based on the microdrop detection of the lead(II) rhodizonate complex trapped into a solid-solution of cellulose paper. This allows for the selective colorimetric detection of Pb
2+
with a qualitative and quantitative detection limit of ~ 1 ppm. Comparative studies with Li
+
, Na
+
, K
+
, Ca
2+
, Mg
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Ni
2+
, Cu
2+
, Zn
2+
, Fe
2+
, Hg
2+
, Co
2+
, Ce
2+
, Mn
2+
, Cr
2+
, Cr
2+
, and Au
3+
show high detectability for Pb
2+
due to the unique charge transfer band present in the kinetically trapped Pb-RA complex. We demonstrated that without the solid-solution matrix, the lead(II) rhodizonate complex polymerizes into an extended solid. The mechanism and kinetics of Pb
2+
detection were studied by UV-visible spectroscopy, XRD, transmission electron microscope (TEM), and dynamic light scattering analysis (DLS). This device-free sensing method for Pb
2+
is highly portable and suitable for applications on the field.
Graphical Abstract |
| doi_str_mv | 10.1007/s11220-024-00482-5 |
| format | Article |
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2+
with a qualitative and quantitative detection limit of ~ 1 ppm. Comparative studies with Li
+
, Na
+
, K
+
, Ca
2+
, Mg
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Ni
2+
, Cu
2+
, Zn
2+
, Fe
2+
, Hg
2+
, Co
2+
, Ce
2+
, Mn
2+
, Cr
2+
, Cr
2+
, and Au
3+
show high detectability for Pb
2+
due to the unique charge transfer band present in the kinetically trapped Pb-RA complex. We demonstrated that without the solid-solution matrix, the lead(II) rhodizonate complex polymerizes into an extended solid. The mechanism and kinetics of Pb
2+
detection were studied by UV-visible spectroscopy, XRD, transmission electron microscope (TEM), and dynamic light scattering analysis (DLS). This device-free sensing method for Pb
2+
is highly portable and suitable for applications on the field.
Graphical Abstract</description><identifier>ISSN: 1557-2072</identifier><identifier>ISSN: 1557-2064</identifier><identifier>EISSN: 1557-2072</identifier><identifier>DOI: 10.1007/s11220-024-00482-5</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Calcium ions ; Cellulose ; Charge transfer ; Cobalt ; Colorimetry ; Comparative studies ; Electrical Engineering ; Engineering ; Human influences ; Imaging ; Lead ; Microwaves ; Photon correlation spectroscopy ; Portable equipment ; Radiology ; RF and Optical Engineering ; Solid solutions</subject><ispartof>Sensing and imaging, 2024-10, Vol.25 (1), Article 61</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-e9629dd0c4a2e9969de3f1d15f58c11875f2b160d74722b05c20fb194aed32ac3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11220-024-00482-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11220-024-00482-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sultana, Kazi Afroza</creatorcontrib><creatorcontrib>Hernandez, Javier</creatorcontrib><creatorcontrib>Sheets, Shane</creatorcontrib><creatorcontrib>Biswas, Manik Chandra</creatorcontrib><creatorcontrib>Kikumoto Dias, Juliana</creatorcontrib><creatorcontrib>Ariza, Melissa</creatorcontrib><creatorcontrib>Islam, Md Tariqul</creatorcontrib><creatorcontrib>Noveron, Juan C.</creatorcontrib><title>Device-Free Colorimetric Sensing of Lead in Water by Kinetically Trapping Lead(II) Rhodizonate into a Solid-solution of Cellulose Paper</title><title>Sensing and imaging</title><addtitle>Sens Imaging</addtitle><description>Anthropogenic lead pollution remains a serious environmental concern due to the high incidence of human exposure worldwide and its severe health impact, particularly to children. We report a device-free colorimetric sensor for lead(II) ions in water based on the microdrop detection of the lead(II) rhodizonate complex trapped into a solid-solution of cellulose paper. This allows for the selective colorimetric detection of Pb
2+
with a qualitative and quantitative detection limit of ~ 1 ppm. Comparative studies with Li
+
, Na
+
, K
+
, Ca
2+
, Mg
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Ni
2+
, Cu
2+
, Zn
2+
, Fe
2+
, Hg
2+
, Co
2+
, Ce
2+
, Mn
2+
, Cr
2+
, Cr
2+
, and Au
3+
show high detectability for Pb
2+
due to the unique charge transfer band present in the kinetically trapped Pb-RA complex. We demonstrated that without the solid-solution matrix, the lead(II) rhodizonate complex polymerizes into an extended solid. The mechanism and kinetics of Pb
2+
detection were studied by UV-visible spectroscopy, XRD, transmission electron microscope (TEM), and dynamic light scattering analysis (DLS). This device-free sensing method for Pb
2+
is highly portable and suitable for applications on the field.
Graphical Abstract</description><subject>Calcium ions</subject><subject>Cellulose</subject><subject>Charge transfer</subject><subject>Cobalt</subject><subject>Colorimetry</subject><subject>Comparative studies</subject><subject>Electrical Engineering</subject><subject>Engineering</subject><subject>Human influences</subject><subject>Imaging</subject><subject>Lead</subject><subject>Microwaves</subject><subject>Photon correlation spectroscopy</subject><subject>Portable equipment</subject><subject>Radiology</subject><subject>RF and Optical Engineering</subject><subject>Solid solutions</subject><issn>1557-2072</issn><issn>1557-2064</issn><issn>1557-2072</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE9KAzEYRwdRsFYv4CrgRhfRJPOvs5RqtVhQbMVlyEy-qSkxGZMZod7AW_QsPZmpFXTlKt_ivV_gRdExJeeUkPzCU8oYwYQlmJBkwHC6E_VomuaYkZzt_rn3owPvFwFKkizrRZ9X8K4qwCMHgIZWW6deoXWqQlMwXpk5sjWagJDrlTLoWbTgULlEd8pAqyqh9RLNnGiaDbnBTsfjM_T4YqX6sCbQSJnWIoGmViuJvdVdq6wJo-vVELTutPWAHkQD7jDaq4X2cPTz9qOn0fVseIsn9zfj4eUEV4yQFkORsUJKUiWCQVFkhYS4ppKmdTqoKB3kac1KmhGZJzljJUmDVpe0SATImIkq7kcn293G2bcOfMsXtnMmfMljSvNQr0jyQLEtVTnrvYOaN6GMcEtOCd8k59vkPCTn38l5GqR4K_kAmzm43-l_rC-IM4Yp</recordid><startdate>20241015</startdate><enddate>20241015</enddate><creator>Sultana, Kazi Afroza</creator><creator>Hernandez, Javier</creator><creator>Sheets, Shane</creator><creator>Biswas, Manik Chandra</creator><creator>Kikumoto Dias, Juliana</creator><creator>Ariza, Melissa</creator><creator>Islam, Md Tariqul</creator><creator>Noveron, Juan C.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope></search><sort><creationdate>20241015</creationdate><title>Device-Free Colorimetric Sensing of Lead in Water by Kinetically Trapping Lead(II) Rhodizonate into a Solid-solution of Cellulose Paper</title><author>Sultana, Kazi Afroza ; Hernandez, Javier ; Sheets, Shane ; Biswas, Manik Chandra ; Kikumoto Dias, Juliana ; Ariza, Melissa ; Islam, Md Tariqul ; Noveron, Juan C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-e9629dd0c4a2e9969de3f1d15f58c11875f2b160d74722b05c20fb194aed32ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Calcium ions</topic><topic>Cellulose</topic><topic>Charge transfer</topic><topic>Cobalt</topic><topic>Colorimetry</topic><topic>Comparative studies</topic><topic>Electrical Engineering</topic><topic>Engineering</topic><topic>Human influences</topic><topic>Imaging</topic><topic>Lead</topic><topic>Microwaves</topic><topic>Photon correlation spectroscopy</topic><topic>Portable equipment</topic><topic>Radiology</topic><topic>RF and Optical Engineering</topic><topic>Solid solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sultana, Kazi Afroza</creatorcontrib><creatorcontrib>Hernandez, Javier</creatorcontrib><creatorcontrib>Sheets, Shane</creatorcontrib><creatorcontrib>Biswas, Manik Chandra</creatorcontrib><creatorcontrib>Kikumoto Dias, Juliana</creatorcontrib><creatorcontrib>Ariza, Melissa</creatorcontrib><creatorcontrib>Islam, Md Tariqul</creatorcontrib><creatorcontrib>Noveron, Juan C.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Sensing and imaging</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sultana, Kazi Afroza</au><au>Hernandez, Javier</au><au>Sheets, Shane</au><au>Biswas, Manik Chandra</au><au>Kikumoto Dias, Juliana</au><au>Ariza, Melissa</au><au>Islam, Md Tariqul</au><au>Noveron, Juan C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Device-Free Colorimetric Sensing of Lead in Water by Kinetically Trapping Lead(II) Rhodizonate into a Solid-solution of Cellulose Paper</atitle><jtitle>Sensing and imaging</jtitle><stitle>Sens Imaging</stitle><date>2024-10-15</date><risdate>2024</risdate><volume>25</volume><issue>1</issue><artnum>61</artnum><issn>1557-2072</issn><issn>1557-2064</issn><eissn>1557-2072</eissn><abstract>Anthropogenic lead pollution remains a serious environmental concern due to the high incidence of human exposure worldwide and its severe health impact, particularly to children. We report a device-free colorimetric sensor for lead(II) ions in water based on the microdrop detection of the lead(II) rhodizonate complex trapped into a solid-solution of cellulose paper. This allows for the selective colorimetric detection of Pb
2+
with a qualitative and quantitative detection limit of ~ 1 ppm. Comparative studies with Li
+
, Na
+
, K
+
, Ca
2+
, Mg
2+
, Sr
2+
, Ba
2+
, Cd
2+
, Ni
2+
, Cu
2+
, Zn
2+
, Fe
2+
, Hg
2+
, Co
2+
, Ce
2+
, Mn
2+
, Cr
2+
, Cr
2+
, and Au
3+
show high detectability for Pb
2+
due to the unique charge transfer band present in the kinetically trapped Pb-RA complex. We demonstrated that without the solid-solution matrix, the lead(II) rhodizonate complex polymerizes into an extended solid. The mechanism and kinetics of Pb
2+
detection were studied by UV-visible spectroscopy, XRD, transmission electron microscope (TEM), and dynamic light scattering analysis (DLS). This device-free sensing method for Pb
2+
is highly portable and suitable for applications on the field.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11220-024-00482-5</doi></addata></record> |
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| ispartof | Sensing and imaging, 2024-10, Vol.25 (1), Article 61 |
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| language | eng |
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| source | SpringerNature Journals |
| subjects | Calcium ions Cellulose Charge transfer Cobalt Colorimetry Comparative studies Electrical Engineering Engineering Human influences Imaging Lead Microwaves Photon correlation spectroscopy Portable equipment Radiology RF and Optical Engineering Solid solutions |
| title | Device-Free Colorimetric Sensing of Lead in Water by Kinetically Trapping Lead(II) Rhodizonate into a Solid-solution of Cellulose Paper |
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