Comparative Analysis of Cure Behaviors, Mechanical Properties, and Swelling Resistance in EPDM/SBR Composites with HNTs, APTES-Modified HNTs, and RH-Modified HNTs
Rubber blending is a prominent technique for enhancing properties in final rubber products. This study investigates the interplay of filler concentration and surface modification in EPDM/SBR blend composites with halloysite nanotubes (HNTs). The effects of γ-Aminopropyltriethoxysilane (APTES) and re...
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| Veröffentlicht in: | SILICON 2024-10, Vol.16 (15), p.5691-5714 |
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| creator | Arunkumar, A. Venkataraman, S. R. Vishvanathperumal, S. Navaneethakrishnan, V. |
| description | Rubber blending is a prominent technique for enhancing properties in final rubber products. This study investigates the interplay of filler concentration and surface modification in EPDM/SBR blend composites with halloysite nanotubes (HNTs). The effects of γ-Aminopropyltriethoxysilane (APTES) and resorcinol-hexamethylenetetramine (RH) modifiers were examined. Comparing rubber blend composites with modified and unmodified HNTs, the findings reveal significant enhancements using RH-modified HNTs. These composites outperform those with APTES-modified and unmodified HNTs, notably improving mechanical properties. The addition of fillers increases crosslink density and filler-rubber interaction, reducing mole percent uptake. These trends result in significantly improved abrasion resistance in the composites. FESEM images show that RH-modified HNTs have superior distribution compared to APTES-modified and unmodified HNTs, highlighting their effective interaction and dispersion. These findings can guide the optimization and production of outdoor applications. |
| doi_str_mv | 10.1007/s12633-024-03117-2 |
| format | Article |
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These trends result in significantly improved abrasion resistance in the composites. FESEM images show that RH-modified HNTs have superior distribution compared to APTES-modified and unmodified HNTs, highlighting their effective interaction and dispersion. 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| subjects | Abrasion resistance Aminopropyltriethoxysilane Blending effects Chemistry Chemistry and Materials Science Comparative analysis Composite materials Environmental Chemistry Fillers Graphene Hexamethylenetetramine Inorganic Chemistry Lasers Materials Science Mechanical engineering Mechanical properties Nanocomposites Optical Devices Optics Photonics Polymer Sciences Polymers Rubber Silicon |
| title | Comparative Analysis of Cure Behaviors, Mechanical Properties, and Swelling Resistance in EPDM/SBR Composites with HNTs, APTES-Modified HNTs, and RH-Modified HNTs |
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