The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries
In this work, rutile-phase Ti 0.95 Nb 0.95 O 4 /C (TNO/C) composites with different carbon contents were obtained through solvothermal method and subsequent calcination. The effect of carbon component on the microstructure and electrochemical performances of TNO/C composites were investigated. The r...
Gespeichert in:
| Veröffentlicht in: | Ionics 2024-10, Vol.30 (10), p.5969-5977 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5977 |
|---|---|
| container_issue | 10 |
| container_start_page | 5969 |
| container_title | Ionics |
| container_volume | 30 |
| creator | Lei, Lei Zhao, Shuo Ding, Rui Li, Zhou Liu, Yang Xian, Xiaochao |
| description | In this work, rutile-phase Ti
0.95
Nb
0.95
O
4
/C (TNO/C) composites with different carbon contents were obtained through solvothermal method and subsequent calcination. The effect of carbon component on the microstructure and electrochemical performances of TNO/C composites were investigated. The results indicate more oxygen vacancies, and higher contents of Nb
4+
and Ti
3+
can be obtained under higher carbon content, leading to enhanced conductivity. Besides serving as conductive agent, carbon component in TNO/C composites also acts as an active component for Li
+
storage, and pseudocapacitance provided by carbon component increases with the increasing of its relative content. Therefore, TNO/C-27.0 composites with the highest carbon content in the as-prepared composites deliver the highest reversible capacities at different current densities and excellent cycling capability of 488 mAh·g
−1
at 0.3 A·g
−1
after 300 cycles and 331 mAh·g
−1
at 1.0 A·g
−1
after 500 cycles. |
| doi_str_mv | 10.1007/s11581-024-05717-9 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3113110909</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3113110909</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-f2c8cdce6b41167c7f95e6c0b5e6e31d7c20ca273d1fd12802584cdc6b909e443</originalsourceid><addsrcrecordid>eNp9kE9LxDAQxYMouK5-AU8Fz3Enadq0R1n8B4t7Wc-hTadulrapSfbg0W9uuhW8CcMMw7zfG3iE3DK4ZwBy5RnLCkaBCwqZZJKWZ2TBipxTkDmckwWUQlIJQl6SK-8PAHnOuFyQ790eE2c7TGyb6MrVdki07Uc74BCSuIR4xw51cFbvsTe66pIRXWtdXw0a_cTtDNyX2Vs99a1YrWcHb0I8V7EG25z8OxP25thTE33rKgR0Bv01uWirzuPN71yS96fH3fqFbrbPr-uHDdUcINCW60I3GvNaMJZLLdsyw1xDHTumrJFRpisu04a1DeMF8KwQEcjrEkoUIl2Su9l3dPbziD6ogz26Ib5UKWOxIAqjis8q7az3Dls1OtNX7ksxUFPUao5axajVKWo1QekM-SgePtD9Wf9D_QDKdoGs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3113110909</pqid></control><display><type>article</type><title>The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries</title><source>SpringerLink Journals - AutoHoldings</source><creator>Lei, Lei ; Zhao, Shuo ; Ding, Rui ; Li, Zhou ; Liu, Yang ; Xian, Xiaochao</creator><creatorcontrib>Lei, Lei ; Zhao, Shuo ; Ding, Rui ; Li, Zhou ; Liu, Yang ; Xian, Xiaochao</creatorcontrib><description>In this work, rutile-phase Ti
0.95
Nb
0.95
O
4
/C (TNO/C) composites with different carbon contents were obtained through solvothermal method and subsequent calcination. The effect of carbon component on the microstructure and electrochemical performances of TNO/C composites were investigated. The results indicate more oxygen vacancies, and higher contents of Nb
4+
and Ti
3+
can be obtained under higher carbon content, leading to enhanced conductivity. Besides serving as conductive agent, carbon component in TNO/C composites also acts as an active component for Li
+
storage, and pseudocapacitance provided by carbon component increases with the increasing of its relative content. Therefore, TNO/C-27.0 composites with the highest carbon content in the as-prepared composites deliver the highest reversible capacities at different current densities and excellent cycling capability of 488 mAh·g
−1
at 0.3 A·g
−1
after 300 cycles and 331 mAh·g
−1
at 1.0 A·g
−1
after 500 cycles.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-024-05717-9</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Carbon content ; Chemistry ; Chemistry and Materials Science ; Composite materials ; Condensed Matter Physics ; Electrochemistry ; Energy Storage ; Lattice vacancies ; Lithium-ion batteries ; Optical and Electronic Materials ; Renewable and Green Energy</subject><ispartof>Ionics, 2024-10, Vol.30 (10), p.5969-5977</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-f2c8cdce6b41167c7f95e6c0b5e6e31d7c20ca273d1fd12802584cdc6b909e443</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-024-05717-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-024-05717-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Lei, Lei</creatorcontrib><creatorcontrib>Zhao, Shuo</creatorcontrib><creatorcontrib>Ding, Rui</creatorcontrib><creatorcontrib>Li, Zhou</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Xian, Xiaochao</creatorcontrib><title>The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries</title><title>Ionics</title><addtitle>Ionics</addtitle><description>In this work, rutile-phase Ti
0.95
Nb
0.95
O
4
/C (TNO/C) composites with different carbon contents were obtained through solvothermal method and subsequent calcination. The effect of carbon component on the microstructure and electrochemical performances of TNO/C composites were investigated. The results indicate more oxygen vacancies, and higher contents of Nb
4+
and Ti
3+
can be obtained under higher carbon content, leading to enhanced conductivity. Besides serving as conductive agent, carbon component in TNO/C composites also acts as an active component for Li
+
storage, and pseudocapacitance provided by carbon component increases with the increasing of its relative content. Therefore, TNO/C-27.0 composites with the highest carbon content in the as-prepared composites deliver the highest reversible capacities at different current densities and excellent cycling capability of 488 mAh·g
−1
at 0.3 A·g
−1
after 300 cycles and 331 mAh·g
−1
at 1.0 A·g
−1
after 500 cycles.</description><subject>Carbon content</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Lattice vacancies</subject><subject>Lithium-ion batteries</subject><subject>Optical and Electronic Materials</subject><subject>Renewable and Green Energy</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE9LxDAQxYMouK5-AU8Fz3Enadq0R1n8B4t7Wc-hTadulrapSfbg0W9uuhW8CcMMw7zfG3iE3DK4ZwBy5RnLCkaBCwqZZJKWZ2TBipxTkDmckwWUQlIJQl6SK-8PAHnOuFyQ790eE2c7TGyb6MrVdki07Uc74BCSuIR4xw51cFbvsTe66pIRXWtdXw0a_cTtDNyX2Vs99a1YrWcHb0I8V7EG25z8OxP25thTE33rKgR0Bv01uWirzuPN71yS96fH3fqFbrbPr-uHDdUcINCW60I3GvNaMJZLLdsyw1xDHTumrJFRpisu04a1DeMF8KwQEcjrEkoUIl2Su9l3dPbziD6ogz26Ib5UKWOxIAqjis8q7az3Dls1OtNX7ksxUFPUao5axajVKWo1QekM-SgePtD9Wf9D_QDKdoGs</recordid><startdate>20241001</startdate><enddate>20241001</enddate><creator>Lei, Lei</creator><creator>Zhao, Shuo</creator><creator>Ding, Rui</creator><creator>Li, Zhou</creator><creator>Liu, Yang</creator><creator>Xian, Xiaochao</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20241001</creationdate><title>The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries</title><author>Lei, Lei ; Zhao, Shuo ; Ding, Rui ; Li, Zhou ; Liu, Yang ; Xian, Xiaochao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-f2c8cdce6b41167c7f95e6c0b5e6e31d7c20ca273d1fd12802584cdc6b909e443</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Carbon content</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Lattice vacancies</topic><topic>Lithium-ion batteries</topic><topic>Optical and Electronic Materials</topic><topic>Renewable and Green Energy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lei, Lei</creatorcontrib><creatorcontrib>Zhao, Shuo</creatorcontrib><creatorcontrib>Ding, Rui</creatorcontrib><creatorcontrib>Li, Zhou</creatorcontrib><creatorcontrib>Liu, Yang</creatorcontrib><creatorcontrib>Xian, Xiaochao</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lei, Lei</au><au>Zhao, Shuo</au><au>Ding, Rui</au><au>Li, Zhou</au><au>Liu, Yang</au><au>Xian, Xiaochao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2024-10-01</date><risdate>2024</risdate><volume>30</volume><issue>10</issue><spage>5969</spage><epage>5977</epage><pages>5969-5977</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>In this work, rutile-phase Ti
0.95
Nb
0.95
O
4
/C (TNO/C) composites with different carbon contents were obtained through solvothermal method and subsequent calcination. The effect of carbon component on the microstructure and electrochemical performances of TNO/C composites were investigated. The results indicate more oxygen vacancies, and higher contents of Nb
4+
and Ti
3+
can be obtained under higher carbon content, leading to enhanced conductivity. Besides serving as conductive agent, carbon component in TNO/C composites also acts as an active component for Li
+
storage, and pseudocapacitance provided by carbon component increases with the increasing of its relative content. Therefore, TNO/C-27.0 composites with the highest carbon content in the as-prepared composites deliver the highest reversible capacities at different current densities and excellent cycling capability of 488 mAh·g
−1
at 0.3 A·g
−1
after 300 cycles and 331 mAh·g
−1
at 1.0 A·g
−1
after 500 cycles.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-024-05717-9</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-7047 |
| ispartof | Ionics, 2024-10, Vol.30 (10), p.5969-5977 |
| issn | 0947-7047 1862-0760 |
| language | eng |
| recordid | cdi_proquest_journals_3113110909 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Carbon content Chemistry Chemistry and Materials Science Composite materials Condensed Matter Physics Electrochemistry Energy Storage Lattice vacancies Lithium-ion batteries Optical and Electronic Materials Renewable and Green Energy |
| title | The role of carbon component on the electrochemical performances of Ti0.95Nb0.95O4/C composites as anode of lithium-ion batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T11%3A07%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20role%20of%20carbon%20component%20on%20the%20electrochemical%20performances%20of%20Ti0.95Nb0.95O4/C%20composites%20as%20anode%20of%20lithium-ion%20batteries&rft.jtitle=Ionics&rft.au=Lei,%20Lei&rft.date=2024-10-01&rft.volume=30&rft.issue=10&rft.spage=5969&rft.epage=5977&rft.pages=5969-5977&rft.issn=0947-7047&rft.eissn=1862-0760&rft_id=info:doi/10.1007/s11581-024-05717-9&rft_dat=%3Cproquest_cross%3E3113110909%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3113110909&rft_id=info:pmid/&rfr_iscdi=true |