Potassium by Thallium Substitution: Symmetry Transformation Through Site Competition in Coordination Compounds

The study focused on the nitrilo‐tris‐(methylene phosphonate) [K2ntpH4]2 and [(K1−yTly)2ntpH4]2 complexes, which are a series of isovalent substitutions. The crystals of [K2ntpH4]2 are monoclinic and belong to the space group of symmetry P21/c with Z=4. When thallium substitutes potassium, the molec...

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Veröffentlicht in:	European journal of inorganic chemistry 2024-10, Vol.27 (28), p.n/a
Hauptverfasser:	Chausov, Feodor F., Somov, Nikolay V., Kazantseva, Irina S., Rybin, Dmitriy S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Coordination compounds Hydrogen bonds Interatomic distance Molecular structure Phosphonates Polyhedra Potassium Potassium Thallium Nitrilo-tris-(methylenephosphonate)s Isovalent substitution series Symmetry of crystal packing Substitutes Symmetry Thallium Van Arkel process
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