Thermal Behavior of Perovskite-Like Phases in the GdAlO3–SrO System

The results of a study of the GdAlO 3 –SrO section, which is one of the internal sections of the Gd 2 O 3 –SrO–Al 2 O 3 ternary system, are presented. In the GdAlO 3 –SrO section three triple compounds, Gd 2 SrAl 2 O 7 , GdSrAlO 4 , and GdSr 2 AlO 5 , crystallizing in the tetragonal system, are synt...

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Veröffentlicht in:Glass physics and chemistry 2024-04, Vol.50 (2), p.174-178
Hauptverfasser: Popova, V. F., Tugova, E. A.
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description The results of a study of the GdAlO 3 –SrO section, which is one of the internal sections of the Gd 2 O 3 –SrO–Al 2 O 3 ternary system, are presented. In the GdAlO 3 –SrO section three triple compounds, Gd 2 SrAl 2 O 7 , GdSrAlO 4 , and GdSr 2 AlO 5 , crystallizing in the tetragonal system, are synthesized. The data on the mechanism of their solid-phase formation are systematized. The results of the thermal stability of perovskite-like phases in the GdAlO 3 –SrO system are presented in a wide temperature range of 1100–1800°C in air. The congruent character of the melting of Gd 2 SrAl 2 O 7 , GdSrAlO 4 , and GdSr 2 AlO 5 complex oxides is established and their melting temperatures are determined.
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subjects Aluminates
Aluminum oxide
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Gadolinium compounds
Gadolinium oxides
Glass
Materials Science
Natural Materials
Perovskites
Physical Chemistry
Solid phases
Strontium oxides
Ternary systems
Thermal stability
Thermodynamic properties
title Thermal Behavior of Perovskite-Like Phases in the GdAlO3–SrO System
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