Photoactivable malachite green-based alkynylplatinum() 2,6-bis(-alkylbenzimidazol-2-yl)pyridine complexes
Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum( ii ) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are faci...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-09, Vol.6 (77), p.1676-1679 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Cheung, Andy Shun-Hoi Leung, Ming-Yi Fung, Tony Ho-Ching Yam, Vivian Wing-Wah |
| description | Photo-responsive malachite green moieties have been incorporated into an alkynylplatinum(
ii
) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.
Alkynylplatinum(
ii
) bzimpy complexes with photoactivable malachite green exhibit distinct self-assembly properties before and after photo-removal of the cyano group, which are brought about by the changes in the metal-metal and π-π interactions. |
| doi_str_mv | 10.1039/d4cc03558e |
| format | Article |
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ii
) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.
Alkynylplatinum(
ii
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ii
) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.
Alkynylplatinum(
ii
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ii
) bzimpy system. The photo-caged complexes in acetonitrile solutions exhibit self-assembly properties modulable by photo-removal of the cyano protecting group. Distinct aggregate morphologies, which are facilitated by the non-covalent metal-metal and π-π stacking interactions, have been observed before and after photo-irradiation.
Alkynylplatinum(
ii
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-09, Vol.6 (77), p.1676-1679 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_3108557579 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acetonitrile Malachite green Self-assembly |
| title | Photoactivable malachite green-based alkynylplatinum() 2,6-bis(-alkylbenzimidazol-2-yl)pyridine complexes |
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