Thermoelectric Properties of Zinc Oxide Doped with Aluminum and Nickel Ions
In this work, a thermoelectric material with the nominal composition Zn 0.97 Al 0.02 Ni 0.01 O is synthesized using the chemical coprecipitation method. The synthesized powder consists of the main phase of wurtzite with a small content of Ni 1– z Zn z O; the change in the crystal-lattice parameters...
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| Veröffentlicht in: | Nanobiotechnology Reports (Online) 2024-04, Vol.19 (2), p.213-218 |
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| creator | Chernyshova, E. V. Kolesnikov, E. A. Bochkanov, F. Yu Argunov, E. V. Voronin, A. I. Khovaylo, V. V. |
| description | In this work, a thermoelectric material with the nominal composition Zn
0.97
Al
0.02
Ni
0.01
O is synthesized using the chemical coprecipitation method. The synthesized powder consists of the main phase of wurtzite with a small content of Ni
1–
z
Zn
z
O; the change in the crystal-lattice parameters of the main phase indicates the replacement of Zn
2+
with Al
3+
. The Ni
1–
z
Zn
z
O phase is predominantly located at the grain boundaries, blocking their growth during spark-plasma sintering. The resulting morphology enhances phonon scattering processes, which leads to a decrease in thermal conductivity. The electrical conductivity exhibits activation behavior and increases significantly in comparison with undoped ZnO, because the concentration of charge carriers increases with the substitution of Zn
2+
/Al
3+
. Thus, the chemical coprecipitation method allows one to obtain doped ZnO with an increase in thermoelectric performance of more than 2 times relative to undoped ZnO. |
| doi_str_mv | 10.1134/S2635167624600937 |
| format | Article |
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0.97
Al
0.02
Ni
0.01
O is synthesized using the chemical coprecipitation method. The synthesized powder consists of the main phase of wurtzite with a small content of Ni
1–
z
Zn
z
O; the change in the crystal-lattice parameters of the main phase indicates the replacement of Zn
2+
with Al
3+
. The Ni
1–
z
Zn
z
O phase is predominantly located at the grain boundaries, blocking their growth during spark-plasma sintering. The resulting morphology enhances phonon scattering processes, which leads to a decrease in thermal conductivity. The electrical conductivity exhibits activation behavior and increases significantly in comparison with undoped ZnO, because the concentration of charge carriers increases with the substitution of Zn
2+
/Al
3+
. Thus, the chemical coprecipitation method allows one to obtain doped ZnO with an increase in thermoelectric performance of more than 2 times relative to undoped ZnO.</description><identifier>ISSN: 2635-1676</identifier><identifier>ISSN: 1995-0780</identifier><identifier>EISSN: 2635-1684</identifier><identifier>EISSN: 1995-0799</identifier><identifier>DOI: 10.1134/S2635167624600937</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical synthesis ; Chemistry and Materials Science ; Coprecipitation ; Crystal lattices ; Current carriers ; Electrical resistivity ; Grain boundaries ; Industrial and Production Engineering ; Lattice parameters ; Machines ; Manufacturing ; Materials Science ; Nanomaterials for Functional and Structural Purposes ; Nanotechnology ; Processes ; Sintering (powder metallurgy) ; Spark plasma sintering ; Thermal conductivity ; Thermoelectric materials ; Thermoelectricity ; Wurtzite ; Zinc oxide</subject><ispartof>Nanobiotechnology Reports (Online), 2024-04, Vol.19 (2), p.213-218</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 2635-1676, Nanobiotechnology Reports, 2024, Vol. 19, No. 2, pp. 213–218. © Pleiades Publishing, Ltd., 2024. Russian Text © The Author(s), 2024, published in Rossiiskie Nanotekhnologii, 2024, Vol. 19, No. 3, pp. 327–333.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-5609816ae2246e4dc4c1cb59d919fc96d81f3443b1040949a646a0ce5f19e64e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S2635167624600937$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S2635167624600937$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27907,27908,41471,42540,51302</link.rule.ids></links><search><creatorcontrib>Chernyshova, E. V.</creatorcontrib><creatorcontrib>Kolesnikov, E. A.</creatorcontrib><creatorcontrib>Bochkanov, F. Yu</creatorcontrib><creatorcontrib>Argunov, E. V.</creatorcontrib><creatorcontrib>Voronin, A. I.</creatorcontrib><creatorcontrib>Khovaylo, V. V.</creatorcontrib><title>Thermoelectric Properties of Zinc Oxide Doped with Aluminum and Nickel Ions</title><title>Nanobiotechnology Reports (Online)</title><addtitle>Nanotechnol Russia</addtitle><description>In this work, a thermoelectric material with the nominal composition Zn
0.97
Al
0.02
Ni
0.01
O is synthesized using the chemical coprecipitation method. The synthesized powder consists of the main phase of wurtzite with a small content of Ni
1–
z
Zn
z
O; the change in the crystal-lattice parameters of the main phase indicates the replacement of Zn
2+
with Al
3+
. The Ni
1–
z
Zn
z
O phase is predominantly located at the grain boundaries, blocking their growth during spark-plasma sintering. The resulting morphology enhances phonon scattering processes, which leads to a decrease in thermal conductivity. The electrical conductivity exhibits activation behavior and increases significantly in comparison with undoped ZnO, because the concentration of charge carriers increases with the substitution of Zn
2+
/Al
3+
. Thus, the chemical coprecipitation method allows one to obtain doped ZnO with an increase in thermoelectric performance of more than 2 times relative to undoped ZnO.</description><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Coprecipitation</subject><subject>Crystal lattices</subject><subject>Current carriers</subject><subject>Electrical resistivity</subject><subject>Grain boundaries</subject><subject>Industrial and Production Engineering</subject><subject>Lattice parameters</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Materials Science</subject><subject>Nanomaterials for Functional and Structural Purposes</subject><subject>Nanotechnology</subject><subject>Processes</subject><subject>Sintering (powder metallurgy)</subject><subject>Spark plasma sintering</subject><subject>Thermal conductivity</subject><subject>Thermoelectric materials</subject><subject>Thermoelectricity</subject><subject>Wurtzite</subject><subject>Zinc oxide</subject><issn>2635-1676</issn><issn>1995-0780</issn><issn>2635-1684</issn><issn>1995-0799</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsNR-AG8LnqM72c00eyz1T4vFCtaLl5BuJnY1ydbdBPXbm1LRg3ia4fF7b4bH2CmIcwCpLh5ilAngGGOFQmg5PmCDnRQBpurwZx_jMRuFYNciUVIgShyw29WGfO2oItN6a_i9d1vyraXAXcmfbGP48sMWxC97veDvtt3wSdXVtulqnjcFv7PmlSo-d004YUdlXgUafc8he7y-Wk1n0WJ5M59OFpEBnbZRgkKngDnF_bukCqMMmHWiCw26NBqLFEqplFyDUEIrnaPCXBhKStCEiuSQne1zt969dRTa7MV1vulPZhJEnMZC6bSnYE8Z70LwVGZbb-vcf2Ygsl1t2Z_aek-894SebZ7J_yb_b_oCewhtHQ</recordid><startdate>20240401</startdate><enddate>20240401</enddate><creator>Chernyshova, E. V.</creator><creator>Kolesnikov, E. A.</creator><creator>Bochkanov, F. Yu</creator><creator>Argunov, E. V.</creator><creator>Voronin, A. I.</creator><creator>Khovaylo, V. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240401</creationdate><title>Thermoelectric Properties of Zinc Oxide Doped with Aluminum and Nickel Ions</title><author>Chernyshova, E. V. ; Kolesnikov, E. A. ; Bochkanov, F. Yu ; Argunov, E. V. ; Voronin, A. I. ; Khovaylo, V. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-5609816ae2246e4dc4c1cb59d919fc96d81f3443b1040949a646a0ce5f19e64e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Coprecipitation</topic><topic>Crystal lattices</topic><topic>Current carriers</topic><topic>Electrical resistivity</topic><topic>Grain boundaries</topic><topic>Industrial and Production Engineering</topic><topic>Lattice parameters</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Materials Science</topic><topic>Nanomaterials for Functional and Structural Purposes</topic><topic>Nanotechnology</topic><topic>Processes</topic><topic>Sintering (powder metallurgy)</topic><topic>Spark plasma sintering</topic><topic>Thermal conductivity</topic><topic>Thermoelectric materials</topic><topic>Thermoelectricity</topic><topic>Wurtzite</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chernyshova, E. V.</creatorcontrib><creatorcontrib>Kolesnikov, E. A.</creatorcontrib><creatorcontrib>Bochkanov, F. Yu</creatorcontrib><creatorcontrib>Argunov, E. V.</creatorcontrib><creatorcontrib>Voronin, A. I.</creatorcontrib><creatorcontrib>Khovaylo, V. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Nanobiotechnology Reports (Online)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chernyshova, E. V.</au><au>Kolesnikov, E. A.</au><au>Bochkanov, F. Yu</au><au>Argunov, E. V.</au><au>Voronin, A. I.</au><au>Khovaylo, V. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermoelectric Properties of Zinc Oxide Doped with Aluminum and Nickel Ions</atitle><jtitle>Nanobiotechnology Reports (Online)</jtitle><stitle>Nanotechnol Russia</stitle><date>2024-04-01</date><risdate>2024</risdate><volume>19</volume><issue>2</issue><spage>213</spage><epage>218</epage><pages>213-218</pages><issn>2635-1676</issn><issn>1995-0780</issn><eissn>2635-1684</eissn><eissn>1995-0799</eissn><abstract>In this work, a thermoelectric material with the nominal composition Zn
0.97
Al
0.02
Ni
0.01
O is synthesized using the chemical coprecipitation method. The synthesized powder consists of the main phase of wurtzite with a small content of Ni
1–
z
Zn
z
O; the change in the crystal-lattice parameters of the main phase indicates the replacement of Zn
2+
with Al
3+
. The Ni
1–
z
Zn
z
O phase is predominantly located at the grain boundaries, blocking their growth during spark-plasma sintering. The resulting morphology enhances phonon scattering processes, which leads to a decrease in thermal conductivity. The electrical conductivity exhibits activation behavior and increases significantly in comparison with undoped ZnO, because the concentration of charge carriers increases with the substitution of Zn
2+
/Al
3+
. Thus, the chemical coprecipitation method allows one to obtain doped ZnO with an increase in thermoelectric performance of more than 2 times relative to undoped ZnO.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S2635167624600937</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2635-1676 |
| ispartof | Nanobiotechnology Reports (Online), 2024-04, Vol.19 (2), p.213-218 |
| issn | 2635-1676 1995-0780 2635-1684 1995-0799 |
| language | eng |
| recordid | cdi_proquest_journals_3102820498 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemical synthesis Chemistry and Materials Science Coprecipitation Crystal lattices Current carriers Electrical resistivity Grain boundaries Industrial and Production Engineering Lattice parameters Machines Manufacturing Materials Science Nanomaterials for Functional and Structural Purposes Nanotechnology Processes Sintering (powder metallurgy) Spark plasma sintering Thermal conductivity Thermoelectric materials Thermoelectricity Wurtzite Zinc oxide |
| title | Thermoelectric Properties of Zinc Oxide Doped with Aluminum and Nickel Ions |
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