exo‐6b2‐Methyl‐Substituted Pentabenzocorannulene: Synthesis, Structural Analysis, and Properties

exo‐6b2‐Methyl‐substituted pentabenzocorannulene (exo‐PBC‐Me) was synthesized by the palladium‐catalyzed cyclization of 1,2,3‐triaryl‐1H‐cyclopenta[l]phenanthrene. Its bowl‐shaped geometry with an sp3 carbon atom in the backbone and a methyl group located at the convex (exo) face was verified by X‐r...

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Veröffentlicht in:	Angewandte Chemie 2024-09, Vol.136 (37), p.n/a
Hauptverfasser:	Wu, Guan‐Yi, Huang, Chun‐Lin, Kang, Hao‐Wen, Ou, Wei‐Ting, Ho, Yeu‐Shiuan, Cheng, Mu‐Jeng, Wu, Yao‐Ting
Format:	Artikel
Sprache:	eng
Schlagworte:	Banded structure buckybowl Carbon Chemical synthesis Contact potentials Crystallography Crystals cyclization Molecular orbitals Organic semiconductors Palladium pentabenzocorannulene Phenanthrene polar bowl crystals Structural analysis Substitutes
Online-Zugang:	Volltext
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