Phase transition in Eu2Zr2–xO7–2x (x = 0–1) solid solutions: A combined structural and spectroscopic study

Zirconate pyrochlores have been extensively studied as candidate waste forms for the immobilization of actinide wastes due to their flexible crystal chemistry, excellent structural stability, and exceptional radiation tolerance. Herein, we report the synthesis of a series of compounds Eu2Zr2–xO7–2x...

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Veröffentlicht in:	Journal of the American Ceramic Society 2024-11, Vol.107 (11), p.7604-7618
Hauptverfasser:	Kong, Linggen, Wang, Zhiyang, Karatchevtseva, Inna, Zhang, Yingjie
Format:	Artikel
Sprache:	eng
Schlagworte:	Actinides Chemical synthesis Crystal defects Diffuse reflectance spectroscopy europium zirconate Fluorite Immobilization order to disorder phase transition Phase transitions pyrochlore Pyrochlores Radiation tolerance Radioactive wastes Raman spectroscopy Solid solutions Structural stability Waste management Zirconium
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