Synthesis of Yb3+-Doped Cs2NaScF6 Single Crystals and EPR Spectroscopy of the Dopant Yb3+ ion

Single crystals of Yb 3+ -doped Cs 2 NaScF 6 are synthesized under hydrothermal conditions and dopant Yb 3+ ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb 3+ center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the...

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Veröffentlicht in:	Applied magnetic resonance 2024-09, Vol.55 (9), p.1129-1135
Hauptverfasser:	Falin, M. L., Latypov, V. A., Khaidukov, N. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atoms and Molecules in Strong Fields Chemical synthesis Dopants Electron paramagnetic resonance Electron spin Electrons Laser Matter Interaction Ligands Magnetic fields Organic Chemistry Original Paper Physical Chemistry Physics Physics and Astronomy Single crystals Solid State Physics Spectroscopy/Spectrometry Structural models Symmetry Temperature
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Zusammenfassung:	Single crystals of Yb 3+ -doped Cs 2 NaScF 6 are synthesized under hydrothermal conditions and dopant Yb 3+ ions are studied using electron paramagnetic resonance spectroscopy. The paramagnetic Yb 3+ center of cubic symmetry is detected. The parameters of the corresponding spin Hamiltonians and the ground state Г 6 are determined. A structural model of the complex under study is proposed. The experimental results are analyzed by comparison with those for the paramagnetic Yb 3+ ion in other lattices.
ISSN:	0937-9347 1613-7507
DOI:	10.1007/s00723-024-01656-w