Understanding the ion conductivity of self-standing poly-[ethylene oxide] composite films through non fickian diffusion mediated water uptake phenomena
Understanding the mechanism towards interaction of water with polymer composite is of significance in the arena of solid-state device application, biomaterial science etc. A systematic research work is presented on the swelling behaviour and its influence towards the ionic conduction of poly [ethyle...
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| Veröffentlicht in: | Journal of polymer research 2024-09, Vol.31 (9), Article 268 |
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| creator | Das, Anamika Mukhopadhyay, Madhumita Mukhopadhyay, Jayanta Mishra, Shweta Sutradhar, Soumyaditya Sarkar, Anwita Kulsi, Goutam Biswas, Satarupa Mukherjee, Moumita |
| description | Understanding the mechanism towards interaction of water with polymer composite is of significance in the arena of solid-state device application, biomaterial science etc. A systematic research work is presented on the swelling behaviour and its influence towards the ionic conduction of poly [ethylene oxide] (PEO) -salt films. The influence of salts (viz. NH
4
I and KBr termed as PSN- & PSK-series) on the diffusion trait of polymer is analysed using non-Fickian python programming. The presence of ions and its polarizability behaviour influences the aqueous equilibration, number density of bounded and free water molecules along with the extent of cross linkage. The contribution of osmotic pressure tends to balance the dynamic non-covalent interactions thereby enhancing the diffusion driven ionic conduction (10
–3
S.cm
−1
) process of PSK-films. Non Fickian diffusion is also found to accelerate the ionic conduction of PSK-series to 10
–2
S.cm
−1
. The dielectric relaxation and long-term endurance (18500 h) establish the stability and applicability of such functionalized films as ionic electrolytes, membranes etc. |
| doi_str_mv | 10.1007/s10965-024-04105-1 |
| format | Article |
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4
I and KBr termed as PSN- & PSK-series) on the diffusion trait of polymer is analysed using non-Fickian python programming. The presence of ions and its polarizability behaviour influences the aqueous equilibration, number density of bounded and free water molecules along with the extent of cross linkage. The contribution of osmotic pressure tends to balance the dynamic non-covalent interactions thereby enhancing the diffusion driven ionic conduction (10
–3
S.cm
−1
) process of PSK-films. Non Fickian diffusion is also found to accelerate the ionic conduction of PSK-series to 10
–2
S.cm
−1
. The dielectric relaxation and long-term endurance (18500 h) establish the stability and applicability of such functionalized films as ionic electrolytes, membranes etc.</description><identifier>ISSN: 1022-9760</identifier><identifier>EISSN: 1572-8935</identifier><identifier>DOI: 10.1007/s10965-024-04105-1</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Balancing ; Biomedical materials ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Dielectric relaxation ; Electrolytes ; Ethylene oxide ; Industrial Chemistry/Chemical Engineering ; Original Paper ; Osmosis ; Polymer films ; Polymer matrix composites ; Polymer Sciences ; Polymers ; Solid state devices ; Water chemistry</subject><ispartof>Journal of polymer research, 2024-09, Vol.31 (9), Article 268</ispartof><rights>The Polymer Society, Taipei 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-43a31c0290e2981f5d84c85487ffc47d2210a8be0e01d72ae086085c2154794d3</cites><orcidid>0000-0003-0637-5113</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10965-024-04105-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10965-024-04105-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Das, Anamika</creatorcontrib><creatorcontrib>Mukhopadhyay, Madhumita</creatorcontrib><creatorcontrib>Mukhopadhyay, Jayanta</creatorcontrib><creatorcontrib>Mishra, Shweta</creatorcontrib><creatorcontrib>Sutradhar, Soumyaditya</creatorcontrib><creatorcontrib>Sarkar, Anwita</creatorcontrib><creatorcontrib>Kulsi, Goutam</creatorcontrib><creatorcontrib>Biswas, Satarupa</creatorcontrib><creatorcontrib>Mukherjee, Moumita</creatorcontrib><title>Understanding the ion conductivity of self-standing poly-[ethylene oxide] composite films through non fickian diffusion mediated water uptake phenomena</title><title>Journal of polymer research</title><addtitle>J Polym Res</addtitle><description>Understanding the mechanism towards interaction of water with polymer composite is of significance in the arena of solid-state device application, biomaterial science etc. A systematic research work is presented on the swelling behaviour and its influence towards the ionic conduction of poly [ethylene oxide] (PEO) -salt films. The influence of salts (viz. NH
4
I and KBr termed as PSN- & PSK-series) on the diffusion trait of polymer is analysed using non-Fickian python programming. The presence of ions and its polarizability behaviour influences the aqueous equilibration, number density of bounded and free water molecules along with the extent of cross linkage. The contribution of osmotic pressure tends to balance the dynamic non-covalent interactions thereby enhancing the diffusion driven ionic conduction (10
–3
S.cm
−1
) process of PSK-films. Non Fickian diffusion is also found to accelerate the ionic conduction of PSK-series to 10
–2
S.cm
−1
. The dielectric relaxation and long-term endurance (18500 h) establish the stability and applicability of such functionalized films as ionic electrolytes, membranes etc.</description><subject>Balancing</subject><subject>Biomedical materials</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dielectric relaxation</subject><subject>Electrolytes</subject><subject>Ethylene oxide</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Original Paper</subject><subject>Osmosis</subject><subject>Polymer films</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Solid state devices</subject><subject>Water chemistry</subject><issn>1022-9760</issn><issn>1572-8935</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kbFuFTEQRVeISISEH6CyRG0Ye9drb4kiIEiRaJIKRZaxx-852bUX2wt5X8Lv4vAQ6WhmprjnTnG67jWDtwxAvisMplFQ4AOFgYGg7Fl3yoTkVE29eN5u4JxOcoQX3ctS7gCEkKM67X7dRIe5VBNdiDtS90hCisSm6DZbw49QDyR5UnD29F9qTfOBfsW6P8wYkaSH4PC2McuaSqhIfJiX0rpy2nZ7ElufD_Y-mEhc8H4rjx8WdMFUdORnm5lsazX3SNY9xrRgNOfdiTdzwVd_91l38_HD9cUlvfry6fPF-ytqOUClQ296ZoFPgHxSzAunBqvEoKT3dpCOcwZGfUNAYE5yg6BGUMJyJgY5Da4_694ce9ecvm9Yqr5LW47tpe5hUlL2ahxaih9TNqdSMnq95rCYfNAM9KMAfRSgmwD9R4BmDeqPUGnhuMP8VP0f6jevJov-</recordid><startdate>20240901</startdate><enddate>20240901</enddate><creator>Das, Anamika</creator><creator>Mukhopadhyay, Madhumita</creator><creator>Mukhopadhyay, Jayanta</creator><creator>Mishra, Shweta</creator><creator>Sutradhar, Soumyaditya</creator><creator>Sarkar, Anwita</creator><creator>Kulsi, Goutam</creator><creator>Biswas, Satarupa</creator><creator>Mukherjee, Moumita</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-0637-5113</orcidid></search><sort><creationdate>20240901</creationdate><title>Understanding the ion conductivity of self-standing poly-[ethylene oxide] composite films through non fickian diffusion mediated water uptake phenomena</title><author>Das, Anamika ; Mukhopadhyay, Madhumita ; Mukhopadhyay, Jayanta ; Mishra, Shweta ; Sutradhar, Soumyaditya ; Sarkar, Anwita ; Kulsi, Goutam ; Biswas, Satarupa ; Mukherjee, Moumita</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-43a31c0290e2981f5d84c85487ffc47d2210a8be0e01d72ae086085c2154794d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Balancing</topic><topic>Biomedical materials</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dielectric relaxation</topic><topic>Electrolytes</topic><topic>Ethylene oxide</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Original Paper</topic><topic>Osmosis</topic><topic>Polymer films</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Solid state devices</topic><topic>Water chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Das, Anamika</creatorcontrib><creatorcontrib>Mukhopadhyay, Madhumita</creatorcontrib><creatorcontrib>Mukhopadhyay, Jayanta</creatorcontrib><creatorcontrib>Mishra, Shweta</creatorcontrib><creatorcontrib>Sutradhar, Soumyaditya</creatorcontrib><creatorcontrib>Sarkar, Anwita</creatorcontrib><creatorcontrib>Kulsi, Goutam</creatorcontrib><creatorcontrib>Biswas, Satarupa</creatorcontrib><creatorcontrib>Mukherjee, Moumita</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of polymer research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Das, Anamika</au><au>Mukhopadhyay, Madhumita</au><au>Mukhopadhyay, Jayanta</au><au>Mishra, Shweta</au><au>Sutradhar, Soumyaditya</au><au>Sarkar, Anwita</au><au>Kulsi, Goutam</au><au>Biswas, Satarupa</au><au>Mukherjee, Moumita</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Understanding the ion conductivity of self-standing poly-[ethylene oxide] composite films through non fickian diffusion mediated water uptake phenomena</atitle><jtitle>Journal of polymer research</jtitle><stitle>J Polym Res</stitle><date>2024-09-01</date><risdate>2024</risdate><volume>31</volume><issue>9</issue><artnum>268</artnum><issn>1022-9760</issn><eissn>1572-8935</eissn><abstract>Understanding the mechanism towards interaction of water with polymer composite is of significance in the arena of solid-state device application, biomaterial science etc. A systematic research work is presented on the swelling behaviour and its influence towards the ionic conduction of poly [ethylene oxide] (PEO) -salt films. The influence of salts (viz. NH
4
I and KBr termed as PSN- & PSK-series) on the diffusion trait of polymer is analysed using non-Fickian python programming. The presence of ions and its polarizability behaviour influences the aqueous equilibration, number density of bounded and free water molecules along with the extent of cross linkage. The contribution of osmotic pressure tends to balance the dynamic non-covalent interactions thereby enhancing the diffusion driven ionic conduction (10
–3
S.cm
−1
) process of PSK-films. Non Fickian diffusion is also found to accelerate the ionic conduction of PSK-series to 10
–2
S.cm
−1
. The dielectric relaxation and long-term endurance (18500 h) establish the stability and applicability of such functionalized films as ionic electrolytes, membranes etc.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10965-024-04105-1</doi><orcidid>https://orcid.org/0000-0003-0637-5113</orcidid></addata></record> |
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| subjects | Balancing Biomedical materials Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Dielectric relaxation Electrolytes Ethylene oxide Industrial Chemistry/Chemical Engineering Original Paper Osmosis Polymer films Polymer matrix composites Polymer Sciences Polymers Solid state devices Water chemistry |
| title | Understanding the ion conductivity of self-standing poly-[ethylene oxide] composite films through non fickian diffusion mediated water uptake phenomena |
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