Organic Semiconductor Devices Fabricated with Recycled Tetra Pak®-Based Electrodes and para-Quinone Methides

This work presents the synthesis of para-quinone methides (p-QMs), which were deposited as films using the high vacuum sublimation technique after being chemically characterized. The p-QMs films were characterized morphologically and structurally using scanning electron microscopy, atomic force micr...

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Veröffentlicht in:Coatings (Basel) 2024-08, Vol.14 (8), p.998
Hauptverfasser: Sánchez Vergara, María Elena, Santillán Esquivel, Eva Alejandra, Ballinas-Indilí, Ricardo, Lozada-Flores, Octavio, Miranda-Ruvalcaba, René, Álvarez-Toledano, Cecilio
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container_issue 8
container_start_page 998
container_title Coatings (Basel)
container_volume 14
creator Sánchez Vergara, María Elena
Santillán Esquivel, Eva Alejandra
Ballinas-Indilí, Ricardo
Lozada-Flores, Octavio
Miranda-Ruvalcaba, René
Álvarez-Toledano, Cecilio
description This work presents the synthesis of para-quinone methides (p-QMs), which were deposited as films using the high vacuum sublimation technique after being chemically characterized. The p-QMs films were characterized morphologically and structurally using scanning electron microscopy, atomic force microscopy, and X-ray diffraction. In addition, their optical behavior was studied by means of ultraviolet–visible spectroscopy, and the optical gaps obtained were in the range of 2.21–2.71 eV for indirect transitions, indicating the semiconductor behavior of the p-QMs. The above was verified through the manufacture and evaluation of the electrical behavior of rigid semiconductor devices, in which fluorine-doped tin oxide-coated glass slides (FTO) were used as an anode and substrate. Finally, as an original, ecological, and low-cost application, the FTO was replaced by substrates and anodes made from recycled Tetra Pak®, generating flexible semiconductor devices. Although the electrical current transported depends on the type of p-QMs, the substituent in its structure, and the morphology, the kinds of substrate and anode also influence the type of electrical behavior of the device. This current–voltage study demonstrates that p-QM2 with 4-Cl-Ph as a radical, p-QM3 with 4-Et2N-Ph as a radical, and p-QM6 with 5-(1,3-benzodioxol) as a radical can be used in optoelectronics as semiconductor films.
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Although the electrical current transported depends on the type of p-QMs, the substituent in its structure, and the morphology, the kinds of substrate and anode also influence the type of electrical behavior of the device. This current–voltage study demonstrates that p-QM2 with 4-Cl-Ph as a radical, p-QM3 with 4-Et2N-Ph as a radical, and p-QM6 with 5-(1,3-benzodioxol) as a radical can be used in optoelectronics as semiconductor films.</description><identifier>ISSN: 2079-6412</identifier><identifier>EISSN: 2079-6412</identifier><identifier>DOI: 10.3390/coatings14080998</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Aluminum ; Anodes ; Atomic properties ; Carbon ; Electrodes ; Fluorine ; Glass substrates ; High vacuum ; Low density polyethylenes ; Mechanical properties ; Microscopy ; Morphology ; Optoelectronics ; Polymers ; Quinone ; Quinones ; Semiconductor devices ; Semiconductors ; Silicon wafers ; Sublimation ; Tin oxides</subject><ispartof>Coatings (Basel), 2024-08, Vol.14 (8), p.998</ispartof><rights>COPYRIGHT 2024 MDPI AG</rights><rights>2024 by the authors. Licensee MDPI, Basel, Switzerland. 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source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; MDPI - Multidisciplinary Digital Publishing Institute; Alma/SFX Local Collection
subjects Aluminum
Anodes
Atomic properties
Carbon
Electrodes
Fluorine
Glass substrates
High vacuum
Low density polyethylenes
Mechanical properties
Microscopy
Morphology
Optoelectronics
Polymers
Quinone
Quinones
Semiconductor devices
Semiconductors
Silicon wafers
Sublimation
Tin oxides
title Organic Semiconductor Devices Fabricated with Recycled Tetra Pak®-Based Electrodes and para-Quinone Methides
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