Dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution in a photoelectrochemical cell
This paper describes photoelectrochemical dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide in a PEC cell consisting of a mesoporous WO 3 photoanode and Pt cathode. The cyclization reaction is effectively driven by this PEC system at room temperature with blue LED irradiation und...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-08, Vol.6 (7), p.9416-9419 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Li, Haoran Qiao, Kaikai Jiang, Wenfeng Li, Fei Shi, Lei |
| description | This paper describes photoelectrochemical dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide in a PEC cell consisting of a mesoporous WO
3
photoanode and Pt cathode. The cyclization reaction is effectively driven by this PEC system at room temperature with blue LED irradiation under external oxidant- and metal-free conditions, delivering a series of benzolactones and benzolactams in up to 95% isolated yields. Meanwhile, hydrogen is released as the only byproduct of this process.
Visible light-driven dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution has been developed in a photoelectrochemical cell. |
| doi_str_mv | 10.1039/d4cc02792b |
| format | Article |
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3
photoanode and Pt cathode. The cyclization reaction is effectively driven by this PEC system at room temperature with blue LED irradiation under external oxidant- and metal-free conditions, delivering a series of benzolactones and benzolactams in up to 95% isolated yields. Meanwhile, hydrogen is released as the only byproduct of this process.
Visible light-driven dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution has been developed in a photoelectrochemical cell.</description><identifier>ISSN: 1359-7345</identifier><identifier>ISSN: 1364-548X</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d4cc02792b</identifier><identifier>PMID: 39136152</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Dehydrogenation ; Hydrogen evolution ; Oxidizing agents ; Photoanodes ; Photoelectrochemical devices ; Room temperature</subject><ispartof>Chemical communications (Cambridge, England), 2024-08, Vol.6 (7), p.9416-9419</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c226t-4682c5d7a7254489dc760cf954eee08e2ad2af448356af8ddba37b84d607cc1f3</cites><orcidid>0000-0002-3686-7576 ; 0000-0002-4898-7022</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39136152$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Haoran</creatorcontrib><creatorcontrib>Qiao, Kaikai</creatorcontrib><creatorcontrib>Jiang, Wenfeng</creatorcontrib><creatorcontrib>Li, Fei</creatorcontrib><creatorcontrib>Shi, Lei</creatorcontrib><title>Dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution in a photoelectrochemical cell</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>This paper describes photoelectrochemical dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide in a PEC cell consisting of a mesoporous WO
3
photoanode and Pt cathode. The cyclization reaction is effectively driven by this PEC system at room temperature with blue LED irradiation under external oxidant- and metal-free conditions, delivering a series of benzolactones and benzolactams in up to 95% isolated yields. Meanwhile, hydrogen is released as the only byproduct of this process.
Visible light-driven dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution has been developed in a photoelectrochemical cell.</description><subject>Dehydrogenation</subject><subject>Hydrogen evolution</subject><subject>Oxidizing agents</subject><subject>Photoanodes</subject><subject>Photoelectrochemical devices</subject><subject>Room temperature</subject><issn>1359-7345</issn><issn>1364-548X</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkc1LHEEQxRtJUGO8eE9o8CKBMT39OXNM1kQDgpcEvA091TVuy8z0pntGWfGPT6-rJqQuVVT9eDzqEXJUstOSifqzkwCMm5q3O2S_FFoWSlbXbzazqgsjpNoj71K6ZblKVe2SPVFnrFR8nzye4XLtYrjB0U7-DimsofcPeQ4jDR3lhY3rvsXxIXigFryjdnT_rO3gHdJ7Py3pixDFu9DPTwp-pJaulmEK2CNMMcASBw-2p4B9_5687Wyf8PC5H5Bf37_9XFwUl1fnPxZfLgvgXE-F1BUH5Yw1XElZ1Q6MZtDVSiIiq5Bbx22XL0Jp21XOtVaYtpJOMwNQduKAnGx1VzH8njFNzeDTxoAdMcypEazmQptaVxk9_g-9DXMcs7sNZaQySvNMfdpSEENKEbtmFf2QX9KUrNlk0pzJxeIpk68Z_vgsObcDulf0JYQMfNgCMcHr9W-o4g_IDJKr</recordid><startdate>20240827</startdate><enddate>20240827</enddate><creator>Li, Haoran</creator><creator>Qiao, Kaikai</creator><creator>Jiang, Wenfeng</creator><creator>Li, Fei</creator><creator>Shi, Lei</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-3686-7576</orcidid><orcidid>https://orcid.org/0000-0002-4898-7022</orcidid></search><sort><creationdate>20240827</creationdate><title>Dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution in a photoelectrochemical cell</title><author>Li, Haoran ; Qiao, Kaikai ; Jiang, Wenfeng ; Li, Fei ; Shi, Lei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c226t-4682c5d7a7254489dc760cf954eee08e2ad2af448356af8ddba37b84d607cc1f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Dehydrogenation</topic><topic>Hydrogen evolution</topic><topic>Oxidizing agents</topic><topic>Photoanodes</topic><topic>Photoelectrochemical devices</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Haoran</creatorcontrib><creatorcontrib>Qiao, Kaikai</creatorcontrib><creatorcontrib>Jiang, Wenfeng</creatorcontrib><creatorcontrib>Li, Fei</creatorcontrib><creatorcontrib>Shi, Lei</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Haoran</au><au>Qiao, Kaikai</au><au>Jiang, Wenfeng</au><au>Li, Fei</au><au>Shi, Lei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution in a photoelectrochemical cell</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2024-08-27</date><risdate>2024</risdate><volume>6</volume><issue>7</issue><spage>9416</spage><epage>9419</epage><pages>9416-9419</pages><issn>1359-7345</issn><issn>1364-548X</issn><eissn>1364-548X</eissn><abstract>This paper describes photoelectrochemical dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide in a PEC cell consisting of a mesoporous WO
3
photoanode and Pt cathode. The cyclization reaction is effectively driven by this PEC system at room temperature with blue LED irradiation under external oxidant- and metal-free conditions, delivering a series of benzolactones and benzolactams in up to 95% isolated yields. Meanwhile, hydrogen is released as the only byproduct of this process.
Visible light-driven dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution has been developed in a photoelectrochemical cell.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39136152</pmid><doi>10.1039/d4cc02792b</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-3686-7576</orcidid><orcidid>https://orcid.org/0000-0002-4898-7022</orcidid></addata></record> |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-08, Vol.6 (7), p.9416-9419 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Dehydrogenation Hydrogen evolution Oxidizing agents Photoanodes Photoelectrochemical devices Room temperature |
| title | Dehydrogenative cyclization of 2-arylbenzoic acid and 2-arylbenzamide with hydrogen evolution in a photoelectrochemical cell |
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