Study on the visible-light absorption of quartz with different valence states of iron
In order to study the effect of impurity iron in different valence states on the coloration mechanism of quartz, colorless synthetic quartz fabricated via ion implantation and its natural counterpart citrine with iron were compared after heating under different atmospheres. Ultraviolet-visible spect...
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| Veröffentlicht in: | CrystEngComm 2024-08, Vol.26 (34), p.4649-4656 |
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| container_issue | 34 |
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| container_title | CrystEngComm |
| container_volume | 26 |
| creator | Wu, Tong Zhao, Xiaoqing Yu, Jie Chen, Rui Cao, Dongyu Tang, Miao Lu, Jinkang Ye, Wei Zhou, Wenbo Xu, Mingli Yang, Miao Xu, Xuhui Ye, Dong |
| description | In order to study the effect of impurity iron in different valence states on the coloration mechanism of quartz, colorless synthetic quartz fabricated
via
ion implantation and its natural counterpart citrine with iron were compared after heating under different atmospheres. Ultraviolet-visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and Fourier transform infrared spectroscopy were used to analyze the absorption property, valence states of iron, and type of O of both natural citrine and ion-implanted quartz. Experimental results showed the yellow color in quartz was mainly related to the charge transfer between Fe
3+
and Fe
2+
, oxygen vacancies and the lattice oxygen, whereas the pink color in quartz was related to oxygen vacancies at a high temperature of 1200 °C.
Synthetic colorless quartz with ion-implanted iron is compared with natural citrine quartz containing iron to study their coloring mechanisms after heating in different atmospheres. |
| doi_str_mv | 10.1039/d4ce00250d |
| format | Article |
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via
ion implantation and its natural counterpart citrine with iron were compared after heating under different atmospheres. Ultraviolet-visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and Fourier transform infrared spectroscopy were used to analyze the absorption property, valence states of iron, and type of O of both natural citrine and ion-implanted quartz. Experimental results showed the yellow color in quartz was mainly related to the charge transfer between Fe
3+
and Fe
2+
, oxygen vacancies and the lattice oxygen, whereas the pink color in quartz was related to oxygen vacancies at a high temperature of 1200 °C.
Synthetic colorless quartz with ion-implanted iron is compared with natural citrine quartz containing iron to study their coloring mechanisms after heating in different atmospheres.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d4ce00250d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Charge transfer ; Color ; Electromagnetic absorption ; Electron paramagnetic resonance ; Fourier transforms ; High temperature ; Infrared analysis ; Infrared spectroscopy ; Ion implantation ; Iron ; Lattice vacancies ; Oxygen ; Photoelectrons ; Quartz ; Valence ; X ray photoelectron spectroscopy</subject><ispartof>CrystEngComm, 2024-08, Vol.26 (34), p.4649-4656</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-cc17a754e8bf12c0a3969fc6e05bd1b1bef769c458ccb0d1fbaeb01a727574833</cites><orcidid>0009-0004-3101-1105 ; 0000-0002-0721-7304 ; 0000-0002-5151-4074</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wu, Tong</creatorcontrib><creatorcontrib>Zhao, Xiaoqing</creatorcontrib><creatorcontrib>Yu, Jie</creatorcontrib><creatorcontrib>Chen, Rui</creatorcontrib><creatorcontrib>Cao, Dongyu</creatorcontrib><creatorcontrib>Tang, Miao</creatorcontrib><creatorcontrib>Lu, Jinkang</creatorcontrib><creatorcontrib>Ye, Wei</creatorcontrib><creatorcontrib>Zhou, Wenbo</creatorcontrib><creatorcontrib>Xu, Mingli</creatorcontrib><creatorcontrib>Yang, Miao</creatorcontrib><creatorcontrib>Xu, Xuhui</creatorcontrib><creatorcontrib>Ye, Dong</creatorcontrib><title>Study on the visible-light absorption of quartz with different valence states of iron</title><title>CrystEngComm</title><description>In order to study the effect of impurity iron in different valence states on the coloration mechanism of quartz, colorless synthetic quartz fabricated
via
ion implantation and its natural counterpart citrine with iron were compared after heating under different atmospheres. Ultraviolet-visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and Fourier transform infrared spectroscopy were used to analyze the absorption property, valence states of iron, and type of O of both natural citrine and ion-implanted quartz. Experimental results showed the yellow color in quartz was mainly related to the charge transfer between Fe
3+
and Fe
2+
, oxygen vacancies and the lattice oxygen, whereas the pink color in quartz was related to oxygen vacancies at a high temperature of 1200 °C.
Synthetic colorless quartz with ion-implanted iron is compared with natural citrine quartz containing iron to study their coloring mechanisms after heating in different atmospheres.</description><subject>Charge transfer</subject><subject>Color</subject><subject>Electromagnetic absorption</subject><subject>Electron paramagnetic resonance</subject><subject>Fourier transforms</subject><subject>High temperature</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Ion implantation</subject><subject>Iron</subject><subject>Lattice vacancies</subject><subject>Oxygen</subject><subject>Photoelectrons</subject><subject>Quartz</subject><subject>Valence</subject><subject>X ray photoelectron spectroscopy</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpN0E1LAzEQBuAgCtbqxbsQ8CasTppkP47S1g8oeNCelyQ7sSnrbptkW-qvd2tFPb0D8zADLyGXDG4Z8OKuEgYBRhKqIzJgIk2THDg__jefkrMQlgBMMAYDMn-NXbWjbUPjAunGBadrTGr3vohU6dD6VXT9srV03SkfP-nWxQWtnLXosYl0o2psDNIQVcSwd863zTk5saoOePGTQzJ_mL6Nn5LZy-Pz-H6WGJZBTEwfKpMCc23ZyIDiRVpYkyJIXTHNNNosLYyQuTEaKma1Qg1MZaNMZiLnfEiuD3dXvl13GGK5bDvf9C9LDkUmpJQs7dXNQRnfhuDRlivvPpTflQzKfW3lRIyn37VNenx1wD6YX_dXK_8CxN1qVA</recordid><startdate>20240827</startdate><enddate>20240827</enddate><creator>Wu, Tong</creator><creator>Zhao, Xiaoqing</creator><creator>Yu, Jie</creator><creator>Chen, Rui</creator><creator>Cao, Dongyu</creator><creator>Tang, Miao</creator><creator>Lu, Jinkang</creator><creator>Ye, Wei</creator><creator>Zhou, Wenbo</creator><creator>Xu, Mingli</creator><creator>Yang, Miao</creator><creator>Xu, Xuhui</creator><creator>Ye, Dong</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0009-0004-3101-1105</orcidid><orcidid>https://orcid.org/0000-0002-0721-7304</orcidid><orcidid>https://orcid.org/0000-0002-5151-4074</orcidid></search><sort><creationdate>20240827</creationdate><title>Study on the visible-light absorption of quartz with different valence states of iron</title><author>Wu, Tong ; Zhao, Xiaoqing ; Yu, Jie ; Chen, Rui ; Cao, Dongyu ; Tang, Miao ; Lu, Jinkang ; Ye, Wei ; Zhou, Wenbo ; Xu, Mingli ; Yang, Miao ; Xu, Xuhui ; Ye, Dong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-cc17a754e8bf12c0a3969fc6e05bd1b1bef769c458ccb0d1fbaeb01a727574833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Charge transfer</topic><topic>Color</topic><topic>Electromagnetic absorption</topic><topic>Electron paramagnetic resonance</topic><topic>Fourier transforms</topic><topic>High temperature</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Ion implantation</topic><topic>Iron</topic><topic>Lattice vacancies</topic><topic>Oxygen</topic><topic>Photoelectrons</topic><topic>Quartz</topic><topic>Valence</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Tong</creatorcontrib><creatorcontrib>Zhao, Xiaoqing</creatorcontrib><creatorcontrib>Yu, Jie</creatorcontrib><creatorcontrib>Chen, Rui</creatorcontrib><creatorcontrib>Cao, Dongyu</creatorcontrib><creatorcontrib>Tang, Miao</creatorcontrib><creatorcontrib>Lu, Jinkang</creatorcontrib><creatorcontrib>Ye, Wei</creatorcontrib><creatorcontrib>Zhou, Wenbo</creatorcontrib><creatorcontrib>Xu, Mingli</creatorcontrib><creatorcontrib>Yang, Miao</creatorcontrib><creatorcontrib>Xu, Xuhui</creatorcontrib><creatorcontrib>Ye, Dong</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Tong</au><au>Zhao, Xiaoqing</au><au>Yu, Jie</au><au>Chen, Rui</au><au>Cao, Dongyu</au><au>Tang, Miao</au><au>Lu, Jinkang</au><au>Ye, Wei</au><au>Zhou, Wenbo</au><au>Xu, Mingli</au><au>Yang, Miao</au><au>Xu, Xuhui</au><au>Ye, Dong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on the visible-light absorption of quartz with different valence states of iron</atitle><jtitle>CrystEngComm</jtitle><date>2024-08-27</date><risdate>2024</risdate><volume>26</volume><issue>34</issue><spage>4649</spage><epage>4656</epage><pages>4649-4656</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>In order to study the effect of impurity iron in different valence states on the coloration mechanism of quartz, colorless synthetic quartz fabricated
via
ion implantation and its natural counterpart citrine with iron were compared after heating under different atmospheres. Ultraviolet-visible spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and Fourier transform infrared spectroscopy were used to analyze the absorption property, valence states of iron, and type of O of both natural citrine and ion-implanted quartz. Experimental results showed the yellow color in quartz was mainly related to the charge transfer between Fe
3+
and Fe
2+
, oxygen vacancies and the lattice oxygen, whereas the pink color in quartz was related to oxygen vacancies at a high temperature of 1200 °C.
Synthetic colorless quartz with ion-implanted iron is compared with natural citrine quartz containing iron to study their coloring mechanisms after heating in different atmospheres.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4ce00250d</doi><tpages>8</tpages><orcidid>https://orcid.org/0009-0004-3101-1105</orcidid><orcidid>https://orcid.org/0000-0002-0721-7304</orcidid><orcidid>https://orcid.org/0000-0002-5151-4074</orcidid></addata></record> |
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| issn | 1466-8033 1466-8033 |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Charge transfer Color Electromagnetic absorption Electron paramagnetic resonance Fourier transforms High temperature Infrared analysis Infrared spectroscopy Ion implantation Iron Lattice vacancies Oxygen Photoelectrons Quartz Valence X ray photoelectron spectroscopy |
| title | Study on the visible-light absorption of quartz with different valence states of iron |
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