Confinement-enhanced stabilization and enrichment of hydroxyl radicals within Ni-based metal–organic frameworks for radiation-self-Fenton degradation of dye pollutants
A radiation-self-Fenton system without the addition of H 2 O 2 was developed for the efficient degradation of organic pollutants. We synthesized nickel-based metal–organic framework (Ni-BTC) as a catalyst for the in-situ generation of abundant hydroxyl radicals (·OH) and H 2 O 2 under X-ray excitati...
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| Veröffentlicht in: | Journal of radioanalytical and nuclear chemistry 2024, Vol.333 (8), p.4059-4072 |
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| container_title | Journal of radioanalytical and nuclear chemistry |
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| creator | Wang, Xuan Zhang, Yukun Wang, Yunlong Hu, Changjiang Li, Qiuhao Chen, Chong |
| description | A radiation-self-Fenton system without the addition of H
2
O
2
was developed for the efficient degradation of organic pollutants. We synthesized nickel-based metal–organic framework (Ni-BTC) as a catalyst for the in-situ generation of abundant hydroxyl radicals (·OH) and H
2
O
2
under X-ray excitation, and the latter was further converted to ·OH in the Fenton reaction to synergistically accelerate the Methylene blue (MB) degradation. The embedded nickel sites and confined layered structure contributed to the stabilization and enrichment of ·OH within the framework. Consequently, the system could completely decolorize 150 mL of MB (20 mg/L) by absorbing 90 Gy dose. This study provided a novel technology for wastewater treatment. |
| doi_str_mv | 10.1007/s10967-024-09541-3 |
| format | Article |
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2
O
2
was developed for the efficient degradation of organic pollutants. We synthesized nickel-based metal–organic framework (Ni-BTC) as a catalyst for the in-situ generation of abundant hydroxyl radicals (·OH) and H
2
O
2
under X-ray excitation, and the latter was further converted to ·OH in the Fenton reaction to synergistically accelerate the Methylene blue (MB) degradation. The embedded nickel sites and confined layered structure contributed to the stabilization and enrichment of ·OH within the framework. Consequently, the system could completely decolorize 150 mL of MB (20 mg/L) by absorbing 90 Gy dose. This study provided a novel technology for wastewater treatment.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-024-09541-3</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Decoloring ; Degradation ; Diagnostic Radiology ; Hadrons ; Heavy Ions ; Hydrogen peroxide ; Hydroxyl radicals ; Inorganic Chemistry ; Metal-organic frameworks ; Methylene blue ; Nickel ; Nuclear Chemistry ; Nuclear Physics ; Physical Chemistry ; Pollutants ; Stabilization ; Wastewater treatment</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2024, Vol.333 (8), p.4059-4072</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c270t-4c4c3419f9bbf1e6026e947fbd45608f92dd25ec596ba1eeb6faef3ed6af4beb3</cites><orcidid>0000-0002-7735-2691</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-024-09541-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-024-09541-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wang, Xuan</creatorcontrib><creatorcontrib>Zhang, Yukun</creatorcontrib><creatorcontrib>Wang, Yunlong</creatorcontrib><creatorcontrib>Hu, Changjiang</creatorcontrib><creatorcontrib>Li, Qiuhao</creatorcontrib><creatorcontrib>Chen, Chong</creatorcontrib><title>Confinement-enhanced stabilization and enrichment of hydroxyl radicals within Ni-based metal–organic frameworks for radiation-self-Fenton degradation of dye pollutants</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>A radiation-self-Fenton system without the addition of H
2
O
2
was developed for the efficient degradation of organic pollutants. We synthesized nickel-based metal–organic framework (Ni-BTC) as a catalyst for the in-situ generation of abundant hydroxyl radicals (·OH) and H
2
O
2
under X-ray excitation, and the latter was further converted to ·OH in the Fenton reaction to synergistically accelerate the Methylene blue (MB) degradation. The embedded nickel sites and confined layered structure contributed to the stabilization and enrichment of ·OH within the framework. Consequently, the system could completely decolorize 150 mL of MB (20 mg/L) by absorbing 90 Gy dose. This study provided a novel technology for wastewater treatment.</description><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Decoloring</subject><subject>Degradation</subject><subject>Diagnostic Radiology</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Hydrogen peroxide</subject><subject>Hydroxyl radicals</subject><subject>Inorganic Chemistry</subject><subject>Metal-organic frameworks</subject><subject>Methylene blue</subject><subject>Nickel</subject><subject>Nuclear Chemistry</subject><subject>Nuclear Physics</subject><subject>Physical Chemistry</subject><subject>Pollutants</subject><subject>Stabilization</subject><subject>Wastewater treatment</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kb2OEzEUhS0EEmHhBagsURuuxx7PTIkiFpBW0EBt-ec68TKxgz3REiregafgtXgSvBkkOioX95zvk3wIec7hJQcYXlUOkxoYdJLB1EvOxAOy4f04sm4Y4SHZQCcU6wfBH5Mntd4CwDSOYkN-bXMKMeEB08Iw7U1y6GldjI1z_G6WmBM1yVNMJbr9fYrmQPdnX_K380yL8dGZudK7uOxjoh8is6Y2wgEXM__-8TOXnUnR0VDMAe9y-VJpyOXSu8BZxTmw68ZtIo-7dlilzeLPSI95nk-LSUt9Sh6FZsJnf98r8vn6zaftO3bz8e377esb5roBFiaddELyKUzWBo4KOoWTHIL1slcwhqnzvuvR9ZOyhiNaFQwGgV6ZIC1acUVerNxjyV9PWBd9m08lNaUW7ZOVApDQUt2aciXXWjDoY4kHU86ag76fRK-T6DaJvkyiRSuJtVRbOO2w_EP_p_UHRMOWOQ</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Wang, Xuan</creator><creator>Zhang, Yukun</creator><creator>Wang, Yunlong</creator><creator>Hu, Changjiang</creator><creator>Li, Qiuhao</creator><creator>Chen, Chong</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7735-2691</orcidid></search><sort><creationdate>2024</creationdate><title>Confinement-enhanced stabilization and enrichment of hydroxyl radicals within Ni-based metal–organic frameworks for radiation-self-Fenton degradation of dye pollutants</title><author>Wang, Xuan ; Zhang, Yukun ; Wang, Yunlong ; Hu, Changjiang ; Li, Qiuhao ; Chen, Chong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-4c4c3419f9bbf1e6026e947fbd45608f92dd25ec596ba1eeb6faef3ed6af4beb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Decoloring</topic><topic>Degradation</topic><topic>Diagnostic Radiology</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Hydrogen peroxide</topic><topic>Hydroxyl radicals</topic><topic>Inorganic Chemistry</topic><topic>Metal-organic frameworks</topic><topic>Methylene blue</topic><topic>Nickel</topic><topic>Nuclear Chemistry</topic><topic>Nuclear Physics</topic><topic>Physical Chemistry</topic><topic>Pollutants</topic><topic>Stabilization</topic><topic>Wastewater treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Xuan</creatorcontrib><creatorcontrib>Zhang, Yukun</creatorcontrib><creatorcontrib>Wang, Yunlong</creatorcontrib><creatorcontrib>Hu, Changjiang</creatorcontrib><creatorcontrib>Li, Qiuhao</creatorcontrib><creatorcontrib>Chen, Chong</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Xuan</au><au>Zhang, Yukun</au><au>Wang, Yunlong</au><au>Hu, Changjiang</au><au>Li, Qiuhao</au><au>Chen, Chong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Confinement-enhanced stabilization and enrichment of hydroxyl radicals within Ni-based metal–organic frameworks for radiation-self-Fenton degradation of dye pollutants</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2024</date><risdate>2024</risdate><volume>333</volume><issue>8</issue><spage>4059</spage><epage>4072</epage><pages>4059-4072</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>A radiation-self-Fenton system without the addition of H
2
O
2
was developed for the efficient degradation of organic pollutants. We synthesized nickel-based metal–organic framework (Ni-BTC) as a catalyst for the in-situ generation of abundant hydroxyl radicals (·OH) and H
2
O
2
under X-ray excitation, and the latter was further converted to ·OH in the Fenton reaction to synergistically accelerate the Methylene blue (MB) degradation. The embedded nickel sites and confined layered structure contributed to the stabilization and enrichment of ·OH within the framework. Consequently, the system could completely decolorize 150 mL of MB (20 mg/L) by absorbing 90 Gy dose. This study provided a novel technology for wastewater treatment.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-024-09541-3</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-7735-2691</orcidid></addata></record> |
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| ispartof | Journal of radioanalytical and nuclear chemistry, 2024, Vol.333 (8), p.4059-4072 |
| issn | 0236-5731 1588-2780 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemical synthesis Chemistry Chemistry and Materials Science Decoloring Degradation Diagnostic Radiology Hadrons Heavy Ions Hydrogen peroxide Hydroxyl radicals Inorganic Chemistry Metal-organic frameworks Methylene blue Nickel Nuclear Chemistry Nuclear Physics Physical Chemistry Pollutants Stabilization Wastewater treatment |
| title | Confinement-enhanced stabilization and enrichment of hydroxyl radicals within Ni-based metal–organic frameworks for radiation-self-Fenton degradation of dye pollutants |
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