Direct benzylation of carboxylic acids using Pd@Cu2(BDC)2DABCO via C‐H (sp3) bond activation
In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu2(BDC)2DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp3) bond activation. The catalyst structure was charac...
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| Veröffentlicht in: | Applied organometallic chemistry 2024-09, Vol.38 (9), p.n/a |
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| creator | Changizian, Zeynab Jafari Mokhtari, Javad Taheri, Salman |
| description | In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu2(BDC)2DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp3) bond activation. The catalyst structure was characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and inductively coupled plasma (ICP). This catalyst showed high catalytic activity, selectivity, and good functional group tolerance for the direct benzylation of carboxylic acids.
Pd‐NPs@Cu2(BDC)2DABCO is used as a recyclable heterogeneous catalyst in this study to establish a method for the synthesis of benzyl benzoate via C‐H bond activation. Pd nanoparticles encapsulated in the mesoporous metal–organic framework showed extraordinarily high catalytic activity and selectivity for the direct benzylation of carboxylic acids with toluene. |
| doi_str_mv | 10.1002/aoc.7627 |
| format | Article |
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Pd‐NPs@Cu2(BDC)2DABCO is used as a recyclable heterogeneous catalyst in this study to establish a method for the synthesis of benzyl benzoate via C‐H bond activation. Pd nanoparticles encapsulated in the mesoporous metal–organic framework showed extraordinarily high catalytic activity and selectivity for the direct benzylation of carboxylic acids with toluene.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.7627</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>benzyl ester ; Carboxylic acids ; Catalysts ; Catalytic activity ; cu‐MOF ; C‐H activation ; Electron microscopy ; Functional groups ; Inductively coupled plasma ; Metal-organic frameworks ; metal–organic framework ; Palladium ; Pd@MOFs</subject><ispartof>Applied organometallic chemistry, 2024-09, Vol.38 (9), p.n/a</ispartof><rights>2024 John Wiley & Sons Ltd.</rights><rights>2024 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0009-0006-4940-4606 ; 0000-0001-8512-9513</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.7627$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.7627$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Changizian, Zeynab Jafari</creatorcontrib><creatorcontrib>Mokhtari, Javad</creatorcontrib><creatorcontrib>Taheri, Salman</creatorcontrib><title>Direct benzylation of carboxylic acids using Pd@Cu2(BDC)2DABCO via C‐H (sp3) bond activation</title><title>Applied organometallic chemistry</title><description>In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu2(BDC)2DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp3) bond activation. The catalyst structure was characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and inductively coupled plasma (ICP). This catalyst showed high catalytic activity, selectivity, and good functional group tolerance for the direct benzylation of carboxylic acids.
Pd‐NPs@Cu2(BDC)2DABCO is used as a recyclable heterogeneous catalyst in this study to establish a method for the synthesis of benzyl benzoate via C‐H bond activation. Pd nanoparticles encapsulated in the mesoporous metal–organic framework showed extraordinarily high catalytic activity and selectivity for the direct benzylation of carboxylic acids with toluene.</description><subject>benzyl ester</subject><subject>Carboxylic acids</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>cu‐MOF</subject><subject>C‐H activation</subject><subject>Electron microscopy</subject><subject>Functional groups</subject><subject>Inductively coupled plasma</subject><subject>Metal-organic frameworks</subject><subject>metal–organic framework</subject><subject>Palladium</subject><subject>Pd@MOFs</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNotkLtOwzAYhS0EEqUg8QiWWMqQ8tuOY3ujTYEiVSpDZyzHcZGrkIRcCmHiEXhGnoSEspyznIv0IXRJYEoA6I0p7FREVByhEQGlAhBMHaMR0EgGNAJ-is7qegcAKiLhCD0vfOVsgxOXf3aZaXyR42KLramS4qPLvMXG-rTGbe3zF_yU3sYtncwX8TVdzObxGu-9wfHP1_cST-qSXeOkyNO-0vj939Y5OtmarHYX_z5Gm_u7TbwMVuuHx3i2CkoiuQgUoWLLQjBMMu5IyE3IE5uahDvHuaFOhcQ4G5EkAiNl2gsRxClgzBEh2RhdHWbLqnhrXd3oXdFWef-oGSjOmOR8SAWH1LvPXKfLyr-aqtME9EBO9-T0QE7P1vHg7BeU5GCU</recordid><startdate>202409</startdate><enddate>202409</enddate><creator>Changizian, Zeynab Jafari</creator><creator>Mokhtari, Javad</creator><creator>Taheri, Salman</creator><general>Wiley Subscription Services, Inc</general><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0009-0006-4940-4606</orcidid><orcidid>https://orcid.org/0000-0001-8512-9513</orcidid></search><sort><creationdate>202409</creationdate><title>Direct benzylation of carboxylic acids using Pd@Cu2(BDC)2DABCO via C‐H (sp3) bond activation</title><author>Changizian, Zeynab Jafari ; Mokhtari, Javad ; Taheri, Salman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1857-9127f340a3835e145a45bcdab5ee55a2e941aec61b60a88d0a8171e9033e1783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>benzyl ester</topic><topic>Carboxylic acids</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>cu‐MOF</topic><topic>C‐H activation</topic><topic>Electron microscopy</topic><topic>Functional groups</topic><topic>Inductively coupled plasma</topic><topic>Metal-organic frameworks</topic><topic>metal–organic framework</topic><topic>Palladium</topic><topic>Pd@MOFs</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Changizian, Zeynab Jafari</creatorcontrib><creatorcontrib>Mokhtari, Javad</creatorcontrib><creatorcontrib>Taheri, Salman</creatorcontrib><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Changizian, Zeynab Jafari</au><au>Mokhtari, Javad</au><au>Taheri, Salman</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct benzylation of carboxylic acids using Pd@Cu2(BDC)2DABCO via C‐H (sp3) bond activation</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2024-09</date><risdate>2024</risdate><volume>38</volume><issue>9</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>In this study, Pd nanoparticles encapsulated in the copper‐based mesoporous metal–organic framework (Cu2(BDC)2DABCO) and used as a reusable heterogeneous catalyst to establish a method for the direct benzylation of carboxylic acids through C‐H (sp3) bond activation. The catalyst structure was characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X‐ray diffraction (XRD), Brunauer–Emmett–Teller (BET), and inductively coupled plasma (ICP). This catalyst showed high catalytic activity, selectivity, and good functional group tolerance for the direct benzylation of carboxylic acids.
Pd‐NPs@Cu2(BDC)2DABCO is used as a recyclable heterogeneous catalyst in this study to establish a method for the synthesis of benzyl benzoate via C‐H bond activation. Pd nanoparticles encapsulated in the mesoporous metal–organic framework showed extraordinarily high catalytic activity and selectivity for the direct benzylation of carboxylic acids with toluene.</abstract><cop>Chichester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aoc.7627</doi><tpages>8</tpages><orcidid>https://orcid.org/0009-0006-4940-4606</orcidid><orcidid>https://orcid.org/0000-0001-8512-9513</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | benzyl ester Carboxylic acids Catalysts Catalytic activity cu‐MOF C‐H activation Electron microscopy Functional groups Inductively coupled plasma Metal-organic frameworks metal–organic framework Palladium Pd@MOFs |
| title | Direct benzylation of carboxylic acids using Pd@Cu2(BDC)2DABCO via C‐H (sp3) bond activation |
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