Effect of blue light irradiation on the formation of silver nanostructures in polyvinyl alcohol nanocomposite films
PVA/AgNO 3 composite films were prepared on fused silica substrates using a casting technique and irradiated with blue light to synthesize silver nanoparticles (AgNPs) within the polymer matrix. The physical and chemical properties of the films were analyzed, revealing increased crystallinity and th...
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| Veröffentlicht in: | Journal of materials science. Materials in electronics 2024-08, Vol.35 (24), p.1609, Article 1609 |
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| creator | Alzoubi, F. Y. Migdadi, A. B. Bani-Hani, Wajde T. Ahmad, Ahmad A. Al-Bataineh, Qais M. Al-Khateeb, H. M. Alqadi, M. K. |
| description | PVA/AgNO
3
composite films were prepared on fused silica substrates using a casting technique and irradiated with blue light to synthesize silver nanoparticles (AgNPs) within the polymer matrix. The physical and chemical properties of the films were analyzed, revealing increased crystallinity and the formation of Ag nanoparticles and nanorods after irradiation. FTIR spectra showed a vibrational band of Ag–O at 760 cm⁻
1
after 30 min of irradiation. The absorption coefficient exhibited a transition band between 400 and 500 nm, with peak amplitude increasing with irradiation time, indicating more Ag nanostructure formation. Differential scanning calorimetry (DSC) analysis showed a rise in melting temperature from 62 to 84 °C and a decrease in crystallization temperature from 188 to 185 °C. Thermogravimetric analysis (TGA) indicated thermal stability with minor mass loss up to 270 °C. Electrical conductivity increased from 2.29 to 3.35 µS.cm⁻
1
with increased blue light irradiation time. Our study documents the efficient synthesis of well-distributed AgNPs within the PVA matrix using blue light irradiation, which significantly enhances the optical, thermal, and electrical properties of the composite films. These improved properties make the films suitable for applications in sensors, flexible electronics, and antimicrobial coatings. |
| doi_str_mv | 10.1007/s10854-024-13364-z |
| format | Article |
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3
composite films were prepared on fused silica substrates using a casting technique and irradiated with blue light to synthesize silver nanoparticles (AgNPs) within the polymer matrix. The physical and chemical properties of the films were analyzed, revealing increased crystallinity and the formation of Ag nanoparticles and nanorods after irradiation. FTIR spectra showed a vibrational band of Ag–O at 760 cm⁻
1
after 30 min of irradiation. The absorption coefficient exhibited a transition band between 400 and 500 nm, with peak amplitude increasing with irradiation time, indicating more Ag nanostructure formation. Differential scanning calorimetry (DSC) analysis showed a rise in melting temperature from 62 to 84 °C and a decrease in crystallization temperature from 188 to 185 °C. Thermogravimetric analysis (TGA) indicated thermal stability with minor mass loss up to 270 °C. Electrical conductivity increased from 2.29 to 3.35 µS.cm⁻
1
with increased blue light irradiation time. Our study documents the efficient synthesis of well-distributed AgNPs within the PVA matrix using blue light irradiation, which significantly enhances the optical, thermal, and electrical properties of the composite films. These improved properties make the films suitable for applications in sensors, flexible electronics, and antimicrobial coatings.</description><identifier>ISSN: 0957-4522</identifier><identifier>EISSN: 1573-482X</identifier><identifier>DOI: 10.1007/s10854-024-13364-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Absorptivity ; Characterization and Evaluation of Materials ; Chemical properties ; Chemical synthesis ; Chemistry and Materials Science ; Crystallization ; Electrical properties ; Electrical resistivity ; Flexible components ; Fused silica ; Light irradiation ; Materials Science ; Melt temperature ; Nanocomposites ; Nanoparticles ; Nanorods ; Nanostructure ; Optical and Electronic Materials ; Optical properties ; Polymer films ; Polymer matrix composites ; Polyvinyl alcohol ; Silver nitrate ; Substrates ; Thermal stability ; Thermogravimetric analysis</subject><ispartof>Journal of materials science. Materials in electronics, 2024-08, Vol.35 (24), p.1609, Article 1609</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-7b38a771df6cbbc4010305c21397483d87da6f6d03f08401bb4c3af2b12209863</cites><orcidid>0000-0002-9101-7056</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10854-024-13364-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10854-024-13364-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Alzoubi, F. Y.</creatorcontrib><creatorcontrib>Migdadi, A. B.</creatorcontrib><creatorcontrib>Bani-Hani, Wajde T.</creatorcontrib><creatorcontrib>Ahmad, Ahmad A.</creatorcontrib><creatorcontrib>Al-Bataineh, Qais M.</creatorcontrib><creatorcontrib>Al-Khateeb, H. M.</creatorcontrib><creatorcontrib>Alqadi, M. K.</creatorcontrib><title>Effect of blue light irradiation on the formation of silver nanostructures in polyvinyl alcohol nanocomposite films</title><title>Journal of materials science. Materials in electronics</title><addtitle>J Mater Sci: Mater Electron</addtitle><description>PVA/AgNO
3
composite films were prepared on fused silica substrates using a casting technique and irradiated with blue light to synthesize silver nanoparticles (AgNPs) within the polymer matrix. The physical and chemical properties of the films were analyzed, revealing increased crystallinity and the formation of Ag nanoparticles and nanorods after irradiation. FTIR spectra showed a vibrational band of Ag–O at 760 cm⁻
1
after 30 min of irradiation. The absorption coefficient exhibited a transition band between 400 and 500 nm, with peak amplitude increasing with irradiation time, indicating more Ag nanostructure formation. Differential scanning calorimetry (DSC) analysis showed a rise in melting temperature from 62 to 84 °C and a decrease in crystallization temperature from 188 to 185 °C. Thermogravimetric analysis (TGA) indicated thermal stability with minor mass loss up to 270 °C. Electrical conductivity increased from 2.29 to 3.35 µS.cm⁻
1
with increased blue light irradiation time. Our study documents the efficient synthesis of well-distributed AgNPs within the PVA matrix using blue light irradiation, which significantly enhances the optical, thermal, and electrical properties of the composite films. These improved properties make the films suitable for applications in sensors, flexible electronics, and antimicrobial coatings.</description><subject>Absorptivity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Crystallization</subject><subject>Electrical properties</subject><subject>Electrical resistivity</subject><subject>Flexible components</subject><subject>Fused silica</subject><subject>Light irradiation</subject><subject>Materials Science</subject><subject>Melt temperature</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Nanorods</subject><subject>Nanostructure</subject><subject>Optical and Electronic Materials</subject><subject>Optical properties</subject><subject>Polymer films</subject><subject>Polymer matrix composites</subject><subject>Polyvinyl alcohol</subject><subject>Silver nitrate</subject><subject>Substrates</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><issn>0957-4522</issn><issn>1573-482X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKt_wFXA9ejLx8ykSxG_QHCj4C5kMkmbkk5qkim0v97YFtwJDwIv594HB6FrArcEoL1LBETNK6C8Iow1vNqdoAmpW1ZxQb9O0QRmdVvxmtJzdJHSEgAazsQEpUdrjc44WNz50WDv5ouMXYyqdyq7MOAyeWGwDXF1XFicnN-YiAc1hJTjqPMYTcJuwOvgtxs3bD1WXodF8HtGh9U6JJdLi_OrdInOrPLJXB3fKfp8evx4eKne3p9fH-7fKk0BctV2TKi2Jb1tdNdpDgQY1JoSNmu5YL1oe9XYpgdmQZTfruOaKUs7QinMRMOm6ObQu47hezQpy2UY41BOSlZ8UCGKtELRA6VjSCkaK9fRrVTcSgLyV648yJVFrtzLlbsSYodQKvAwN_Gv-p_UD-4lf2k</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Alzoubi, F. Y.</creator><creator>Migdadi, A. B.</creator><creator>Bani-Hani, Wajde T.</creator><creator>Ahmad, Ahmad A.</creator><creator>Al-Bataineh, Qais M.</creator><creator>Al-Khateeb, H. M.</creator><creator>Alqadi, M. K.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9101-7056</orcidid></search><sort><creationdate>20240801</creationdate><title>Effect of blue light irradiation on the formation of silver nanostructures in polyvinyl alcohol nanocomposite films</title><author>Alzoubi, F. Y. ; Migdadi, A. B. ; Bani-Hani, Wajde T. ; Ahmad, Ahmad A. ; Al-Bataineh, Qais M. ; Al-Khateeb, H. M. ; Alqadi, M. 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Y.</creatorcontrib><creatorcontrib>Migdadi, A. B.</creatorcontrib><creatorcontrib>Bani-Hani, Wajde T.</creatorcontrib><creatorcontrib>Ahmad, Ahmad A.</creatorcontrib><creatorcontrib>Al-Bataineh, Qais M.</creatorcontrib><creatorcontrib>Al-Khateeb, H. M.</creatorcontrib><creatorcontrib>Alqadi, M. K.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials science. Materials in electronics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alzoubi, F. Y.</au><au>Migdadi, A. B.</au><au>Bani-Hani, Wajde T.</au><au>Ahmad, Ahmad A.</au><au>Al-Bataineh, Qais M.</au><au>Al-Khateeb, H. M.</au><au>Alqadi, M. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of blue light irradiation on the formation of silver nanostructures in polyvinyl alcohol nanocomposite films</atitle><jtitle>Journal of materials science. Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2024-08-01</date><risdate>2024</risdate><volume>35</volume><issue>24</issue><spage>1609</spage><pages>1609-</pages><artnum>1609</artnum><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>PVA/AgNO
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composite films were prepared on fused silica substrates using a casting technique and irradiated with blue light to synthesize silver nanoparticles (AgNPs) within the polymer matrix. The physical and chemical properties of the films were analyzed, revealing increased crystallinity and the formation of Ag nanoparticles and nanorods after irradiation. FTIR spectra showed a vibrational band of Ag–O at 760 cm⁻
1
after 30 min of irradiation. The absorption coefficient exhibited a transition band between 400 and 500 nm, with peak amplitude increasing with irradiation time, indicating more Ag nanostructure formation. Differential scanning calorimetry (DSC) analysis showed a rise in melting temperature from 62 to 84 °C and a decrease in crystallization temperature from 188 to 185 °C. Thermogravimetric analysis (TGA) indicated thermal stability with minor mass loss up to 270 °C. Electrical conductivity increased from 2.29 to 3.35 µS.cm⁻
1
with increased blue light irradiation time. Our study documents the efficient synthesis of well-distributed AgNPs within the PVA matrix using blue light irradiation, which significantly enhances the optical, thermal, and electrical properties of the composite films. These improved properties make the films suitable for applications in sensors, flexible electronics, and antimicrobial coatings.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-024-13364-z</doi><orcidid>https://orcid.org/0000-0002-9101-7056</orcidid></addata></record> |
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| subjects | Absorptivity Characterization and Evaluation of Materials Chemical properties Chemical synthesis Chemistry and Materials Science Crystallization Electrical properties Electrical resistivity Flexible components Fused silica Light irradiation Materials Science Melt temperature Nanocomposites Nanoparticles Nanorods Nanostructure Optical and Electronic Materials Optical properties Polymer films Polymer matrix composites Polyvinyl alcohol Silver nitrate Substrates Thermal stability Thermogravimetric analysis |
| title | Effect of blue light irradiation on the formation of silver nanostructures in polyvinyl alcohol nanocomposite films |
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