Palladium‐Catalyzed Carbonylative Transformation for the Synthesis of Tetracyclic Indoline Thioesters

Palladium‐catalyzed thioesterification of (aza)indole‐tethered aryl iodides, Mo(CO)6, and sulfonyl chlorides is reported. A series of C2 thioester‐group substituted indoline‐fused ring compounds are constructed by an intramolecular Heck cyclization and carbonylation chemistry involving N‐(2‐iodobenz...

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Veröffentlicht in:	Advanced synthesis & catalysis 2024-08, Vol.366 (15), p.3367-3371
Hauptverfasser:	Li, Ming, Zhao, Guo‐Xiao, Xu, Shanmei, Miao, Dong‐Yu, Li, Shun‐Xi, Qiu, Yi‐Feng, Chen, Dong‐Ping, Quan, Zheng‐Jun, Wang, Xi‐Cun, Liang, Yong‐Min
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon monoxide Carbonylation Carbonyls Chemical synthesis Condensed ring dearomatization Cyclic compounds Functional groups Heck reaction Palladium Thioester compounds Thioesterification Thioesters
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