The Perfluoro‐o‐phenylene‐mercury Trimer [Hg(o‐C6F4)]3 – a Textbook Example of Phase‐Dependent Structural Differences

The geometric and electronic structure of [Hg(o‐C6F4)]3 (1) in the gas phase, i. e. free of intermolecular interactions, was determined by a synchronous gas‐phase electron diffraction/mass spectrometry experiment (GED/MS), complemented by quantum chemical calculations. 1 is stable up to 498 K and th...

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Veröffentlicht in:	Chemistry : a European journal 2024-08, Vol.30 (46), p.e202401575-n/a
Hauptverfasser:	Giricheva, Nina I., Tverdova, Natalya V., Otlyotov, Arseniy A., Lamm, Jan‐Hendrik, Girichev, Georgiy V., Mitzel, Norbert W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical bonds Electron diffraction Electronic structure Electrons Gas-phase electron diffraction Mass spectrometry Mass spectroscopy Mercury Mercury (planet) Molecular structure Nature of bonding Phase dependence Planar structures Quantum chemical calculations Quantum chemistry Quantum theory Relativistic effects Structure Structure-function relationships Trimers Vapor phases
Online-Zugang:	Volltext
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