Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals
The reaction of triphenylcyclopentadienyl potassium and bipyridine with lanthanum, praseodymium, erbium, lutetium, and scandium chloride tetrahydrofuranates results in the formation of binuclear [Cp Ph3 Ln(Bipy)Cl(μ 2 -Cl)] 2 (Ln = La ( I ), Pr ( II )) and mononuclear [Cp Ph3 Ln(Bipy)Cl 2 (THF)] (Ln...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2024-05, Vol.50 (5), p.334-342 |
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| container_title | Russian journal of coordination chemistry |
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| creator | Bardonov, D. A. Lyssenko, K. A. Degtyareva, S. S. Nifant’ev, I. E. Roitershtein, D. M. |
| description | The reaction of triphenylcyclopentadienyl potassium and bipyridine with lanthanum, praseodymium, erbium, lutetium, and scandium chloride tetrahydrofuranates results in the formation of binuclear [Cp
Ph3
Ln(Bipy)Cl(μ
2
-Cl)]
2
(Ln = La (
I
), Pr (
II
)) and mononuclear [Cp
Ph3
Ln(Bipy)Cl
2
(THF)] (Ln = Er (
III
), Lu (
IV
), [Cp
Ph3
Sc(Bipy)Cl
2
] (
V
) complexes (Cp
Ph3
= 1,2,4-triphenylcyclopentadienyl, Bipy = bipyridine). The decrease in the REE radius in the series La…Sc results in the formation of mononuclear instead of binuclear complexes and in a decrease in the coordination number of the central ion. The coplanar arrangement of two different π-systems gives rise to stacking interactions between the triphenylcyclopentadienyl ligand and bipyridine. The molecular structure of complexes
I
–
V
was established by X-ray diffraction analysis (CCDC nos. 2308609 (
I
), 2308608 (
II
), 2308610 (
III
), 2308611 (
IV
), 2308607 (
V
)). |
| doi_str_mv | 10.1134/S1070328423601565 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3093575130</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3093575130</sourcerecordid><originalsourceid>FETCH-LOGICAL-c268t-e47dc44d766be4212498052a7e767ad87c973113d9a0840dbace0980c52aba573</originalsourceid><addsrcrecordid>eNp1kE9Lw0AQxRdRsFY_gLeA10Zn_ySbHLVWK1QEW89hu5naLWkSdzdivr0bKngQTzPD-703zBBySeGaUi5ulhQkcJYJxlOgSZockRFNIYs5p9lx6IMcD_opOXNuB0ABknxE6qW3nfadVVV0bz7ROuP7qNlEc_Romwpbb3REJ2wi4pU17RbrvtK9rpoWa69KM8zxnWl7a0pTYzRt9m2FX-iGkFdlMZop67fRM3pVuXNysgkFL37qmLw9zFbTebx4eXya3i5izdLMxyhkqYUoZZquUTDKRJ5BwpREmUpVZlLnkoe7y1xBJqBcK40QEB2YtUokH5OrQ25rm48OnS92TWfrsLLgkPNEJpRDoOiB0rZxzuKmaK3ZK9sXFIrhrcWftwYPO3hcYOt3tL_J_5u-AcWlecY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3093575130</pqid></control><display><type>article</type><title>Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals</title><source>Springer Nature - Complete Springer Journals</source><creator>Bardonov, D. A. ; Lyssenko, K. A. ; Degtyareva, S. S. ; Nifant’ev, I. E. ; Roitershtein, D. M.</creator><creatorcontrib>Bardonov, D. A. ; Lyssenko, K. A. ; Degtyareva, S. S. ; Nifant’ev, I. E. ; Roitershtein, D. M.</creatorcontrib><description>The reaction of triphenylcyclopentadienyl potassium and bipyridine with lanthanum, praseodymium, erbium, lutetium, and scandium chloride tetrahydrofuranates results in the formation of binuclear [Cp
Ph3
Ln(Bipy)Cl(μ
2
-Cl)]
2
(Ln = La (
I
), Pr (
II
)) and mononuclear [Cp
Ph3
Ln(Bipy)Cl
2
(THF)] (Ln = Er (
III
), Lu (
IV
), [Cp
Ph3
Sc(Bipy)Cl
2
] (
V
) complexes (Cp
Ph3
= 1,2,4-triphenylcyclopentadienyl, Bipy = bipyridine). The decrease in the REE radius in the series La…Sc results in the formation of mononuclear instead of binuclear complexes and in a decrease in the coordination number of the central ion. The coplanar arrangement of two different π-systems gives rise to stacking interactions between the triphenylcyclopentadienyl ligand and bipyridine. The molecular structure of complexes
I
–
V
was established by X-ray diffraction analysis (CCDC nos. 2308609 (
I
), 2308608 (
II
), 2308610 (
III
), 2308611 (
IV
), 2308607 (
V
)).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328423601565</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Coordination numbers ; Erbium ; Inorganic Chemistry ; Lanthanum ; Lutetium ; Molecular structure ; Physical Chemistry ; Praseodymium ; Rare earth elements ; Scandium</subject><ispartof>Russian journal of coordination chemistry, 2024-05, Vol.50 (5), p.334-342</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 5, pp. 334–342. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-e47dc44d766be4212498052a7e767ad87c973113d9a0840dbace0980c52aba573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328423601565$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328423601565$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Bardonov, D. A.</creatorcontrib><creatorcontrib>Lyssenko, K. A.</creatorcontrib><creatorcontrib>Degtyareva, S. S.</creatorcontrib><creatorcontrib>Nifant’ev, I. E.</creatorcontrib><creatorcontrib>Roitershtein, D. M.</creatorcontrib><title>Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The reaction of triphenylcyclopentadienyl potassium and bipyridine with lanthanum, praseodymium, erbium, lutetium, and scandium chloride tetrahydrofuranates results in the formation of binuclear [Cp
Ph3
Ln(Bipy)Cl(μ
2
-Cl)]
2
(Ln = La (
I
), Pr (
II
)) and mononuclear [Cp
Ph3
Ln(Bipy)Cl
2
(THF)] (Ln = Er (
III
), Lu (
IV
), [Cp
Ph3
Sc(Bipy)Cl
2
] (
V
) complexes (Cp
Ph3
= 1,2,4-triphenylcyclopentadienyl, Bipy = bipyridine). The decrease in the REE radius in the series La…Sc results in the formation of mononuclear instead of binuclear complexes and in a decrease in the coordination number of the central ion. The coplanar arrangement of two different π-systems gives rise to stacking interactions between the triphenylcyclopentadienyl ligand and bipyridine. The molecular structure of complexes
I
–
V
was established by X-ray diffraction analysis (CCDC nos. 2308609 (
I
), 2308608 (
II
), 2308610 (
III
), 2308611 (
IV
), 2308607 (
V
)).</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination numbers</subject><subject>Erbium</subject><subject>Inorganic Chemistry</subject><subject>Lanthanum</subject><subject>Lutetium</subject><subject>Molecular structure</subject><subject>Physical Chemistry</subject><subject>Praseodymium</subject><subject>Rare earth elements</subject><subject>Scandium</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE9Lw0AQxRdRsFY_gLeA10Zn_ySbHLVWK1QEW89hu5naLWkSdzdivr0bKngQTzPD-703zBBySeGaUi5ulhQkcJYJxlOgSZockRFNIYs5p9lx6IMcD_opOXNuB0ABknxE6qW3nfadVVV0bz7ROuP7qNlEc_Romwpbb3REJ2wi4pU17RbrvtK9rpoWa69KM8zxnWl7a0pTYzRt9m2FX-iGkFdlMZop67fRM3pVuXNysgkFL37qmLw9zFbTebx4eXya3i5izdLMxyhkqYUoZZquUTDKRJ5BwpREmUpVZlLnkoe7y1xBJqBcK40QEB2YtUokH5OrQ25rm48OnS92TWfrsLLgkPNEJpRDoOiB0rZxzuKmaK3ZK9sXFIrhrcWftwYPO3hcYOt3tL_J_5u-AcWlecY</recordid><startdate>20240501</startdate><enddate>20240501</enddate><creator>Bardonov, D. A.</creator><creator>Lyssenko, K. A.</creator><creator>Degtyareva, S. S.</creator><creator>Nifant’ev, I. E.</creator><creator>Roitershtein, D. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240501</creationdate><title>Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals</title><author>Bardonov, D. A. ; Lyssenko, K. A. ; Degtyareva, S. S. ; Nifant’ev, I. E. ; Roitershtein, D. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-e47dc44d766be4212498052a7e767ad87c973113d9a0840dbace0980c52aba573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination numbers</topic><topic>Erbium</topic><topic>Inorganic Chemistry</topic><topic>Lanthanum</topic><topic>Lutetium</topic><topic>Molecular structure</topic><topic>Physical Chemistry</topic><topic>Praseodymium</topic><topic>Rare earth elements</topic><topic>Scandium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bardonov, D. A.</creatorcontrib><creatorcontrib>Lyssenko, K. A.</creatorcontrib><creatorcontrib>Degtyareva, S. S.</creatorcontrib><creatorcontrib>Nifant’ev, I. E.</creatorcontrib><creatorcontrib>Roitershtein, D. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bardonov, D. A.</au><au>Lyssenko, K. A.</au><au>Degtyareva, S. S.</au><au>Nifant’ev, I. E.</au><au>Roitershtein, D. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2024-05-01</date><risdate>2024</risdate><volume>50</volume><issue>5</issue><spage>334</spage><epage>342</epage><pages>334-342</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The reaction of triphenylcyclopentadienyl potassium and bipyridine with lanthanum, praseodymium, erbium, lutetium, and scandium chloride tetrahydrofuranates results in the formation of binuclear [Cp
Ph3
Ln(Bipy)Cl(μ
2
-Cl)]
2
(Ln = La (
I
), Pr (
II
)) and mononuclear [Cp
Ph3
Ln(Bipy)Cl
2
(THF)] (Ln = Er (
III
), Lu (
IV
), [Cp
Ph3
Sc(Bipy)Cl
2
] (
V
) complexes (Cp
Ph3
= 1,2,4-triphenylcyclopentadienyl, Bipy = bipyridine). The decrease in the REE radius in the series La…Sc results in the formation of mononuclear instead of binuclear complexes and in a decrease in the coordination number of the central ion. The coplanar arrangement of two different π-systems gives rise to stacking interactions between the triphenylcyclopentadienyl ligand and bipyridine. The molecular structure of complexes
I
–
V
was established by X-ray diffraction analysis (CCDC nos. 2308609 (
I
), 2308608 (
II
), 2308610 (
III
), 2308611 (
IV
), 2308607 (
V
)).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328423601565</doi><tpages>9</tpages></addata></record> |
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| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_3093575130 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Coordination numbers Erbium Inorganic Chemistry Lanthanum Lutetium Molecular structure Physical Chemistry Praseodymium Rare earth elements Scandium |
| title | Structural Diversity of Heteroleptic 1,2,4-Triphenylcyclopentadienyl-Bipyridine Complexes of Rare Earth Metals |
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