Time evolution of the inner structure of antimony phosphate nanosheet suspension developing structural colouration
Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structures has not been a topic in colloidal nanosheet systems. In this study, we investigate the time evolution of structures in suspension using UV-visible s...
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| Veröffentlicht in: | Soft matter 2024-08, Vol.2 (32), p.6353-636 |
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| creator | Mouri, Emiko Fukumoto, Takashi Kato, Riki Miyamoto, Nobuyoshi Nakato, Teruyuki |
| description | Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structures has not been a topic in colloidal nanosheet systems. In this study, we investigate the time evolution of structures in suspension using UV-visible spectrometry and small-angle X-ray scattering. Here, we report that antimony phosphate nanosheet systems re-organise their inner structures, especially at lower concentrations (isotropic or biphasic region), and that the basal spacing decreases with time after sample preparation, although the evolution speed depends on the sample concentration. The stability of the inner structure of the suspension is essential for their application as structural colour materials in sensors and colourants.
Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structure has not been a topic in colloidal nanosheet systems. |
| doi_str_mv | 10.1039/d4sm00647j |
| format | Article |
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Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structure has not been a topic in colloidal nanosheet systems.</description><subject>Antimony</subject><subject>Coloration</subject><subject>Evolution</subject><subject>Nanosheets</subject><subject>Sample preparation</subject><subject>Spectrometry</subject><subject>Structural stability</subject><subject>X-ray scattering</subject><issn>1744-683X</issn><issn>1744-6848</issn><issn>1744-6848</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpdkU1P3DAQhq0KxFe5cAdZ6gUhLbVjxx_HaqGlCMQBKvUWeZ0Jm1ViB9tZiX-Pw9KtxGlGM8-8M5oXoRNKLilh-nvNY0-I4HL1BR1QyflMKK52tjn7u48OY1wRwhSnYg_tM01kqYU-QOGp7QHD2ndjar3DvsFpCbh1DgKOKYw2jQGmsnGp7b17xcPSx2FpEmBnnI9LgITjGAdwcVKoYQ2dH1r3vJ03Hba-8zmZdnxFu43pIhx_xCP05-f10_xmdvfw6_f8x93MFoVIM1UYwixXJSlqzSWtJW-EZCBFWdDSKlFrvSgUI1QsSsK1tLSpaSmMaBpCa8uO0PlGdwj-ZYSYqr6NFrrOOPBjrBhRgohCEprRb5_QVb7W5esypQtFZd6aqYsNZYOPMUBTDaHtTXitKKkmJ6or_nj_7sRths8-JMdFD_UW_ff6DJxugBDttvvfSvYG-nqPOQ</recordid><startdate>20240814</startdate><enddate>20240814</enddate><creator>Mouri, Emiko</creator><creator>Fukumoto, Takashi</creator><creator>Kato, Riki</creator><creator>Miyamoto, Nobuyoshi</creator><creator>Nakato, Teruyuki</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5200-2540</orcidid><orcidid>https://orcid.org/0000-0002-0148-0371</orcidid><orcidid>https://orcid.org/0000-0001-7251-982X</orcidid></search><sort><creationdate>20240814</creationdate><title>Time evolution of the inner structure of antimony phosphate nanosheet suspension developing structural colouration</title><author>Mouri, Emiko ; 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In this study, we investigate the time evolution of structures in suspension using UV-visible spectrometry and small-angle X-ray scattering. Here, we report that antimony phosphate nanosheet systems re-organise their inner structures, especially at lower concentrations (isotropic or biphasic region), and that the basal spacing decreases with time after sample preparation, although the evolution speed depends on the sample concentration. The stability of the inner structure of the suspension is essential for their application as structural colour materials in sensors and colourants.
Structural colouration observed in antimony phosphate nanosheet suspensions has been known for two decades, but the stability of their inner structure has not been a topic in colloidal nanosheet systems.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39075969</pmid><doi>10.1039/d4sm00647j</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-5200-2540</orcidid><orcidid>https://orcid.org/0000-0002-0148-0371</orcidid><orcidid>https://orcid.org/0000-0001-7251-982X</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Soft matter, 2024-08, Vol.2 (32), p.6353-636 |
| issn | 1744-683X 1744-6848 1744-6848 |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Antimony Coloration Evolution Nanosheets Sample preparation Spectrometry Structural stability X-ray scattering |
| title | Time evolution of the inner structure of antimony phosphate nanosheet suspension developing structural colouration |
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