Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units
Four new POM-based coordination complexes [Cu(TPP) 2 (CH 3 CN) 2 ] 2 {[Cu(TPP) 2 ] 2 (β-Mo 8 O 26 )}·2CH 3 CN ( 1 ) (TPP = triphenylphosphine), {[Ag(TPP)] 2 ·[Ag(TPP) 2 ] 2 ·(β-Mo 8 O 26 )}·6DMF ( 2 ), {[Cu 2 (DPPM) 2 (CH 3 CN)] 2 (β-Mo 8 O 26 )}·2CH 3 CN·2DCM ( 3 ) (DPPM = bis(diphenylphosphino)met...
Gespeichert in:
| Veröffentlicht in: | CrystEngComm 2024-08, Vol.26 (32), p.4329-4338 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4338 |
|---|---|
| container_issue | 32 |
| container_start_page | 4329 |
| container_title | CrystEngComm |
| container_volume | 26 |
| creator | Yu, Yi-Qi Sun, Shang-Bin Deng, Wen-Hao Li, Jian Lu, Zhi-Yi He, Jia-Hui Wang, Long-Sheng Meng, Xiang-Gao |
| description | Four new POM-based coordination complexes [Cu(TPP)
2
(CH
3
CN)
2
]
2
{[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}·2CH
3
CN (
1
) (TPP = triphenylphosphine), {[Ag(TPP)]
2
·[Ag(TPP)
2
]
2
·(β-Mo
8
O
26
)}·6DMF (
2
), {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
3
) (DPPM = bis(diphenylphosphino)methane), and {[Ag
2
(DPPM)
2
·(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
4
) were prepared through the self-assembly of α-octamolybdates and the corresponding Cu/Ag phosphine building blocks. Single crystal X-ray diffraction reveals that compound
1
consists of two cations of [Cu(TPP)
2
(CH
3
CN)
2
]
+
and one anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
; the anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
can be viewed in such a way that the central cluster of β-Mo
8
O
26
are coordinated with two Cu(TPP)
2
units
via
terminal oxygen atoms to form a linear trimer; compound
2
is a neutral cross-like pentamer which is made up of the central β-Mo
8
O
26
coordinated with two equatorial Ag(TPP)
2
units and two Ag(TPP) units above and below the β-Mo
8
O
26
cluster
via
the terminal oxygen atoms; compounds
3
and
4
can be viewed as a trimer consisting of two binuclear metal clusters of {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
or {[Ag
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
bridged by one β-Mo
8
O
26
cluster
via
terminal oxygen atoms. Their structures are further evidenced by FT-IR and PXRD. TGA study indicates that the skeleton of compounds
1-4
is stable up to 250-290 °C and then a rapid weight loss followed. Their band gaps can be calculated (
E
g
value: 2.27 eV for
1
, 3.14 eV for
2
, 2.66 eV for
3
, and 3.16 eV for
4
) using the Tauc's method according to their solid state UV diffuse reflection spectra. Upon irradiation at 211 nm, compounds
1-4
exhibit a series of successive emissions around 360 nm, 380 nm and 400 nm, which demonstrate a similar solid state emission compared to their corresponding Cu/Ag phosphine building blocks.
Four POM-based coordination compounds were obtained by the self-assembly of α-octamolybdates and luminescent Cu/Ag phosphine units, which maintain the luminescence feature of their precursors of Cu/Ag phosphine units. |
| doi_str_mv | 10.1039/d4ce00496e |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3091989406</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3091989406</sourcerecordid><originalsourceid>FETCH-LOGICAL-c170t-427ad412ffc0c2853f35411dbc59c04753d2a1efe00ea966d9823451dc779b373</originalsourceid><addsrcrecordid>eNpNkMtKxDAUhosoOI5u3AsBd2KdpEkvWQ51vIDgQl2XNDl1OrRJTVJxwKfyQXwm44yoq3PhO_8554-iY4IvCKZ8ppgEjBnPYCeaEJZlcYEp3f2X70cHzq0wJowQPIneH9baL8G17hw5b0fpRwsOCa1QN_atBidBS0CmQQ5ewYoOSWOsarXwrdGh6IcO3sJILRwoFFqfH7GRXvSmW9dKeNiIzZ9n5YiGpXHDMqiiUbfeHUZ7jegcHP3EafR0tXgsb-K7--vbcn4XS5JjH7MkF4qRpGkklkmR0oam4XpVy5RLzPKUqkQQaMLnIHiWKV4klKVEyTznNc3pNDrd6g7WvIzgfLUyo9VhZUUxJ7zgDGeBOttS0hrnLDTVYNte2HVFcPXtbnXJysXG3UWAT7awdfKX-3OffgGuenkO</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3091989406</pqid></control><display><type>article</type><title>Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yu, Yi-Qi ; Sun, Shang-Bin ; Deng, Wen-Hao ; Li, Jian ; Lu, Zhi-Yi ; He, Jia-Hui ; Wang, Long-Sheng ; Meng, Xiang-Gao</creator><creatorcontrib>Yu, Yi-Qi ; Sun, Shang-Bin ; Deng, Wen-Hao ; Li, Jian ; Lu, Zhi-Yi ; He, Jia-Hui ; Wang, Long-Sheng ; Meng, Xiang-Gao</creatorcontrib><description>Four new POM-based coordination complexes [Cu(TPP)
2
(CH
3
CN)
2
]
2
{[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}·2CH
3
CN (
1
) (TPP = triphenylphosphine), {[Ag(TPP)]
2
·[Ag(TPP)
2
]
2
·(β-Mo
8
O
26
)}·6DMF (
2
), {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
3
) (DPPM = bis(diphenylphosphino)methane), and {[Ag
2
(DPPM)
2
·(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
4
) were prepared through the self-assembly of α-octamolybdates and the corresponding Cu/Ag phosphine building blocks. Single crystal X-ray diffraction reveals that compound
1
consists of two cations of [Cu(TPP)
2
(CH
3
CN)
2
]
+
and one anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
; the anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
can be viewed in such a way that the central cluster of β-Mo
8
O
26
are coordinated with two Cu(TPP)
2
units
via
terminal oxygen atoms to form a linear trimer; compound
2
is a neutral cross-like pentamer which is made up of the central β-Mo
8
O
26
coordinated with two equatorial Ag(TPP)
2
units and two Ag(TPP) units above and below the β-Mo
8
O
26
cluster
via
the terminal oxygen atoms; compounds
3
and
4
can be viewed as a trimer consisting of two binuclear metal clusters of {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
or {[Ag
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
bridged by one β-Mo
8
O
26
cluster
via
terminal oxygen atoms. Their structures are further evidenced by FT-IR and PXRD. TGA study indicates that the skeleton of compounds
1-4
is stable up to 250-290 °C and then a rapid weight loss followed. Their band gaps can be calculated (
E
g
value: 2.27 eV for
1
, 3.14 eV for
2
, 2.66 eV for
3
, and 3.16 eV for
4
) using the Tauc's method according to their solid state UV diffuse reflection spectra. Upon irradiation at 211 nm, compounds
1-4
exhibit a series of successive emissions around 360 nm, 380 nm and 400 nm, which demonstrate a similar solid state emission compared to their corresponding Cu/Ag phosphine building blocks.
Four POM-based coordination compounds were obtained by the self-assembly of α-octamolybdates and luminescent Cu/Ag phosphine units, which maintain the luminescence feature of their precursors of Cu/Ag phosphine units.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d4ce00496e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anions ; Atomic properties ; Atomic structure ; Coordination compounds ; Copper ; Electrons ; Metal clusters ; Oxygen atoms ; Phosphines ; Self-assembly ; Silver ; Single crystals ; Solid state ; Trimers ; Weight loss</subject><ispartof>CrystEngComm, 2024-08, Vol.26 (32), p.4329-4338</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-427ad412ffc0c2853f35411dbc59c04753d2a1efe00ea966d9823451dc779b373</cites><orcidid>0000-0002-3340-0081</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Yu, Yi-Qi</creatorcontrib><creatorcontrib>Sun, Shang-Bin</creatorcontrib><creatorcontrib>Deng, Wen-Hao</creatorcontrib><creatorcontrib>Li, Jian</creatorcontrib><creatorcontrib>Lu, Zhi-Yi</creatorcontrib><creatorcontrib>He, Jia-Hui</creatorcontrib><creatorcontrib>Wang, Long-Sheng</creatorcontrib><creatorcontrib>Meng, Xiang-Gao</creatorcontrib><title>Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units</title><title>CrystEngComm</title><description>Four new POM-based coordination complexes [Cu(TPP)
2
(CH
3
CN)
2
]
2
{[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}·2CH
3
CN (
1
) (TPP = triphenylphosphine), {[Ag(TPP)]
2
·[Ag(TPP)
2
]
2
·(β-Mo
8
O
26
)}·6DMF (
2
), {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
3
) (DPPM = bis(diphenylphosphino)methane), and {[Ag
2
(DPPM)
2
·(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
4
) were prepared through the self-assembly of α-octamolybdates and the corresponding Cu/Ag phosphine building blocks. Single crystal X-ray diffraction reveals that compound
1
consists of two cations of [Cu(TPP)
2
(CH
3
CN)
2
]
+
and one anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
; the anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
can be viewed in such a way that the central cluster of β-Mo
8
O
26
are coordinated with two Cu(TPP)
2
units
via
terminal oxygen atoms to form a linear trimer; compound
2
is a neutral cross-like pentamer which is made up of the central β-Mo
8
O
26
coordinated with two equatorial Ag(TPP)
2
units and two Ag(TPP) units above and below the β-Mo
8
O
26
cluster
via
the terminal oxygen atoms; compounds
3
and
4
can be viewed as a trimer consisting of two binuclear metal clusters of {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
or {[Ag
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
bridged by one β-Mo
8
O
26
cluster
via
terminal oxygen atoms. Their structures are further evidenced by FT-IR and PXRD. TGA study indicates that the skeleton of compounds
1-4
is stable up to 250-290 °C and then a rapid weight loss followed. Their band gaps can be calculated (
E
g
value: 2.27 eV for
1
, 3.14 eV for
2
, 2.66 eV for
3
, and 3.16 eV for
4
) using the Tauc's method according to their solid state UV diffuse reflection spectra. Upon irradiation at 211 nm, compounds
1-4
exhibit a series of successive emissions around 360 nm, 380 nm and 400 nm, which demonstrate a similar solid state emission compared to their corresponding Cu/Ag phosphine building blocks.
Four POM-based coordination compounds were obtained by the self-assembly of α-octamolybdates and luminescent Cu/Ag phosphine units, which maintain the luminescence feature of their precursors of Cu/Ag phosphine units.</description><subject>Anions</subject><subject>Atomic properties</subject><subject>Atomic structure</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Electrons</subject><subject>Metal clusters</subject><subject>Oxygen atoms</subject><subject>Phosphines</subject><subject>Self-assembly</subject><subject>Silver</subject><subject>Single crystals</subject><subject>Solid state</subject><subject>Trimers</subject><subject>Weight loss</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpNkMtKxDAUhosoOI5u3AsBd2KdpEkvWQ51vIDgQl2XNDl1OrRJTVJxwKfyQXwm44yoq3PhO_8554-iY4IvCKZ8ppgEjBnPYCeaEJZlcYEp3f2X70cHzq0wJowQPIneH9baL8G17hw5b0fpRwsOCa1QN_atBidBS0CmQQ5ewYoOSWOsarXwrdGh6IcO3sJILRwoFFqfH7GRXvSmW9dKeNiIzZ9n5YiGpXHDMqiiUbfeHUZ7jegcHP3EafR0tXgsb-K7--vbcn4XS5JjH7MkF4qRpGkklkmR0oam4XpVy5RLzPKUqkQQaMLnIHiWKV4klKVEyTznNc3pNDrd6g7WvIzgfLUyo9VhZUUxJ7zgDGeBOttS0hrnLDTVYNte2HVFcPXtbnXJysXG3UWAT7awdfKX-3OffgGuenkO</recordid><startdate>20240812</startdate><enddate>20240812</enddate><creator>Yu, Yi-Qi</creator><creator>Sun, Shang-Bin</creator><creator>Deng, Wen-Hao</creator><creator>Li, Jian</creator><creator>Lu, Zhi-Yi</creator><creator>He, Jia-Hui</creator><creator>Wang, Long-Sheng</creator><creator>Meng, Xiang-Gao</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3340-0081</orcidid></search><sort><creationdate>20240812</creationdate><title>Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units</title><author>Yu, Yi-Qi ; Sun, Shang-Bin ; Deng, Wen-Hao ; Li, Jian ; Lu, Zhi-Yi ; He, Jia-Hui ; Wang, Long-Sheng ; Meng, Xiang-Gao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-427ad412ffc0c2853f35411dbc59c04753d2a1efe00ea966d9823451dc779b373</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anions</topic><topic>Atomic properties</topic><topic>Atomic structure</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Electrons</topic><topic>Metal clusters</topic><topic>Oxygen atoms</topic><topic>Phosphines</topic><topic>Self-assembly</topic><topic>Silver</topic><topic>Single crystals</topic><topic>Solid state</topic><topic>Trimers</topic><topic>Weight loss</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Yi-Qi</creatorcontrib><creatorcontrib>Sun, Shang-Bin</creatorcontrib><creatorcontrib>Deng, Wen-Hao</creatorcontrib><creatorcontrib>Li, Jian</creatorcontrib><creatorcontrib>Lu, Zhi-Yi</creatorcontrib><creatorcontrib>He, Jia-Hui</creatorcontrib><creatorcontrib>Wang, Long-Sheng</creatorcontrib><creatorcontrib>Meng, Xiang-Gao</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Yi-Qi</au><au>Sun, Shang-Bin</au><au>Deng, Wen-Hao</au><au>Li, Jian</au><au>Lu, Zhi-Yi</au><au>He, Jia-Hui</au><au>Wang, Long-Sheng</au><au>Meng, Xiang-Gao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units</atitle><jtitle>CrystEngComm</jtitle><date>2024-08-12</date><risdate>2024</risdate><volume>26</volume><issue>32</issue><spage>4329</spage><epage>4338</epage><pages>4329-4338</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Four new POM-based coordination complexes [Cu(TPP)
2
(CH
3
CN)
2
]
2
{[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}·2CH
3
CN (
1
) (TPP = triphenylphosphine), {[Ag(TPP)]
2
·[Ag(TPP)
2
]
2
·(β-Mo
8
O
26
)}·6DMF (
2
), {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
3
) (DPPM = bis(diphenylphosphino)methane), and {[Ag
2
(DPPM)
2
·(CH
3
CN)]
2
(β-Mo
8
O
26
)}·2CH
3
CN·2DCM (
4
) were prepared through the self-assembly of α-octamolybdates and the corresponding Cu/Ag phosphine building blocks. Single crystal X-ray diffraction reveals that compound
1
consists of two cations of [Cu(TPP)
2
(CH
3
CN)
2
]
+
and one anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
; the anion of {[Cu(TPP)
2
]
2
(β-Mo
8
O
26
)}
2−
can be viewed in such a way that the central cluster of β-Mo
8
O
26
are coordinated with two Cu(TPP)
2
units
via
terminal oxygen atoms to form a linear trimer; compound
2
is a neutral cross-like pentamer which is made up of the central β-Mo
8
O
26
coordinated with two equatorial Ag(TPP)
2
units and two Ag(TPP) units above and below the β-Mo
8
O
26
cluster
via
the terminal oxygen atoms; compounds
3
and
4
can be viewed as a trimer consisting of two binuclear metal clusters of {[Cu
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
or {[Ag
2
(DPPM)
2
(CH
3
CN)]
2
}
2+
bridged by one β-Mo
8
O
26
cluster
via
terminal oxygen atoms. Their structures are further evidenced by FT-IR and PXRD. TGA study indicates that the skeleton of compounds
1-4
is stable up to 250-290 °C and then a rapid weight loss followed. Their band gaps can be calculated (
E
g
value: 2.27 eV for
1
, 3.14 eV for
2
, 2.66 eV for
3
, and 3.16 eV for
4
) using the Tauc's method according to their solid state UV diffuse reflection spectra. Upon irradiation at 211 nm, compounds
1-4
exhibit a series of successive emissions around 360 nm, 380 nm and 400 nm, which demonstrate a similar solid state emission compared to their corresponding Cu/Ag phosphine building blocks.
Four POM-based coordination compounds were obtained by the self-assembly of α-octamolybdates and luminescent Cu/Ag phosphine units, which maintain the luminescence feature of their precursors of Cu/Ag phosphine units.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4ce00496e</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-3340-0081</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2024-08, Vol.26 (32), p.4329-4338 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_proquest_journals_3091989406 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anions Atomic properties Atomic structure Coordination compounds Copper Electrons Metal clusters Oxygen atoms Phosphines Self-assembly Silver Single crystals Solid state Trimers Weight loss |
| title | Synthesis, structures and luminescence of several coordination complexes based on β-octamolybdate and Ag/Cu phosphine units |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T20%3A09%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20structures%20and%20luminescence%20of%20several%20coordination%20complexes%20based%20on%20%CE%B2-octamolybdate%20and%20Ag/Cu%20phosphine%20units&rft.jtitle=CrystEngComm&rft.au=Yu,%20Yi-Qi&rft.date=2024-08-12&rft.volume=26&rft.issue=32&rft.spage=4329&rft.epage=4338&rft.pages=4329-4338&rft.issn=1466-8033&rft.eissn=1466-8033&rft_id=info:doi/10.1039/d4ce00496e&rft_dat=%3Cproquest_cross%3E3091989406%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=3091989406&rft_id=info:pmid/&rfr_iscdi=true |