MXenes Composites as the Protective Layer for Li Metal Electrodes
The life and safety issues of Li metal electrodes seriously hinder its application. In order to solve this problem, MXene protected Li electrode has been prepared. Due to the formation of MXene-Ti3C2Tx interface layer, not only the uneven deposition of Li could be alleviated, but also the unstable f...
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Veröffentlicht in: | Nano hybrids and composites 2022-02, Vol.34, p.9-14 |
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creator | Wang, Chao Jun Qi, Xin Chen, Xiang Li, Xiu Hui Peng, Si Kan Yan, Shao Jiu |
description | The life and safety issues of Li metal electrodes seriously hinder its application. In order to solve this problem, MXene protected Li electrode has been prepared. Due to the formation of MXene-Ti3C2Tx interface layer, not only the uneven deposition of Li could be alleviated, but also the unstable formation of solid electrolyte interphase can be suppressed. Thus, the MXene-Ti3C2Tx@Li electrodes have exhibited excellent cycling stability. The cycling performance of MXene-Ti3C2Tx@Li electrodes have been proved by symmetric cells, which exhibit relatively stable voltage plateau and a small voltage hysteresis even after 29000 min for stripping/plating cycling (about 230 cycles) under current density of 5 A cm-1 and specific capacity of 5 Ah cm-1. Overall, this study demonstrates MXenes as a critical enabler to realize high-performance Li metal batteries. |
doi_str_mv | 10.4028/p-15m3g4 |
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In order to solve this problem, MXene protected Li electrode has been prepared. Due to the formation of MXene-Ti3C2Tx interface layer, not only the uneven deposition of Li could be alleviated, but also the unstable formation of solid electrolyte interphase can be suppressed. Thus, the MXene-Ti3C2Tx@Li electrodes have exhibited excellent cycling stability. The cycling performance of MXene-Ti3C2Tx@Li electrodes have been proved by symmetric cells, which exhibit relatively stable voltage plateau and a small voltage hysteresis even after 29000 min for stripping/plating cycling (about 230 cycles) under current density of 5 A cm-1 and specific capacity of 5 Ah cm-1. Overall, this study demonstrates MXenes as a critical enabler to realize high-performance Li metal batteries.</description><identifier>ISSN: 2297-3370</identifier><identifier>ISSN: 2297-3400</identifier><identifier>EISSN: 2297-3400</identifier><identifier>DOI: 10.4028/p-15m3g4</identifier><language>eng</language><publisher>Zurich: Trans Tech Publications Ltd</publisher><subject>Cycles ; Electric potential ; Electrodes ; Electrolytic cells ; Lithium batteries ; MXenes ; Solid electrolytes ; Voltage</subject><ispartof>Nano hybrids and composites, 2022-02, Vol.34, p.9-14</ispartof><rights>2022 Trans Tech Publications Ltd</rights><rights>Copyright Trans Tech Publications Ltd. 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c181t-fd981a0a689abf981fd21655f1ec2ad4a33c5e717fac4935f30bdc417c13e2b33</cites><orcidid>0000-0002-8145-0681 ; 0000-0002-2593-2854</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttps://www.scientific.net/Image/TitleCover/6184?width=600</thumbnail><link.rule.ids>315,781,785,27926,27927</link.rule.ids></links><search><creatorcontrib>Wang, Chao Jun</creatorcontrib><creatorcontrib>Qi, Xin</creatorcontrib><creatorcontrib>Chen, Xiang</creatorcontrib><creatorcontrib>Li, Xiu Hui</creatorcontrib><creatorcontrib>Peng, Si Kan</creatorcontrib><creatorcontrib>Yan, Shao Jiu</creatorcontrib><title>MXenes Composites as the Protective Layer for Li Metal Electrodes</title><title>Nano hybrids and composites</title><description>The life and safety issues of Li metal electrodes seriously hinder its application. In order to solve this problem, MXene protected Li electrode has been prepared. Due to the formation of MXene-Ti3C2Tx interface layer, not only the uneven deposition of Li could be alleviated, but also the unstable formation of solid electrolyte interphase can be suppressed. Thus, the MXene-Ti3C2Tx@Li electrodes have exhibited excellent cycling stability. The cycling performance of MXene-Ti3C2Tx@Li electrodes have been proved by symmetric cells, which exhibit relatively stable voltage plateau and a small voltage hysteresis even after 29000 min for stripping/plating cycling (about 230 cycles) under current density of 5 A cm-1 and specific capacity of 5 Ah cm-1. Overall, this study demonstrates MXenes as a critical enabler to realize high-performance Li metal batteries.</description><subject>Cycles</subject><subject>Electric potential</subject><subject>Electrodes</subject><subject>Electrolytic cells</subject><subject>Lithium batteries</subject><subject>MXenes</subject><subject>Solid electrolytes</subject><subject>Voltage</subject><issn>2297-3370</issn><issn>2297-3400</issn><issn>2297-3400</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNplkE1LAzEQhoMoWLTgTwh4EWE1k-w2m2Mp9QO26EHBW0izE7ulbdYkFfrvjaziwdM8MA_vMC8hF8BuSsbr276AaiveyyMy4lzJQpSMHf-ykOyUjGNcM8Y4gIIJH5Hp4g13GOnMb3sfu5TRRJpWSJ-DT2hT94m0MQcM1PlAm44uMJkNnW_yLvgW4zk5cWYTcfwzz8jr3fxl9lA0T_ePs2lTWKghFa5VNRhmJrUyS5fZtRwmVeUALTdtaYSwFUqQzthSicoJtmxtCdKCQL4U4oxcDrl98B97jEmv_T7s8kktmAIpaiVltq4GywYfY0Cn-9BtTThoYPq7I93roaOsXg9qCmYX86-rv8R_8hfzg2a7</recordid><startdate>20220223</startdate><enddate>20220223</enddate><creator>Wang, Chao Jun</creator><creator>Qi, Xin</creator><creator>Chen, Xiang</creator><creator>Li, Xiu Hui</creator><creator>Peng, Si Kan</creator><creator>Yan, Shao Jiu</creator><general>Trans Tech Publications Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-8145-0681</orcidid><orcidid>https://orcid.org/0000-0002-2593-2854</orcidid></search><sort><creationdate>20220223</creationdate><title>MXenes Composites as the Protective Layer for Li Metal Electrodes</title><author>Wang, Chao Jun ; Qi, Xin ; Chen, Xiang ; Li, Xiu Hui ; Peng, Si Kan ; Yan, Shao Jiu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c181t-fd981a0a689abf981fd21655f1ec2ad4a33c5e717fac4935f30bdc417c13e2b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cycles</topic><topic>Electric potential</topic><topic>Electrodes</topic><topic>Electrolytic cells</topic><topic>Lithium batteries</topic><topic>MXenes</topic><topic>Solid electrolytes</topic><topic>Voltage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Chao Jun</creatorcontrib><creatorcontrib>Qi, Xin</creatorcontrib><creatorcontrib>Chen, Xiang</creatorcontrib><creatorcontrib>Li, Xiu Hui</creatorcontrib><creatorcontrib>Peng, Si Kan</creatorcontrib><creatorcontrib>Yan, Shao Jiu</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Nano hybrids and composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Chao Jun</au><au>Qi, Xin</au><au>Chen, Xiang</au><au>Li, Xiu Hui</au><au>Peng, Si Kan</au><au>Yan, Shao Jiu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MXenes Composites as the Protective Layer for Li Metal Electrodes</atitle><jtitle>Nano hybrids and composites</jtitle><date>2022-02-23</date><risdate>2022</risdate><volume>34</volume><spage>9</spage><epage>14</epage><pages>9-14</pages><issn>2297-3370</issn><issn>2297-3400</issn><eissn>2297-3400</eissn><abstract>The life and safety issues of Li metal electrodes seriously hinder its application. In order to solve this problem, MXene protected Li electrode has been prepared. Due to the formation of MXene-Ti3C2Tx interface layer, not only the uneven deposition of Li could be alleviated, but also the unstable formation of solid electrolyte interphase can be suppressed. Thus, the MXene-Ti3C2Tx@Li electrodes have exhibited excellent cycling stability. The cycling performance of MXene-Ti3C2Tx@Li electrodes have been proved by symmetric cells, which exhibit relatively stable voltage plateau and a small voltage hysteresis even after 29000 min for stripping/plating cycling (about 230 cycles) under current density of 5 A cm-1 and specific capacity of 5 Ah cm-1. 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subjects | Cycles Electric potential Electrodes Electrolytic cells Lithium batteries MXenes Solid electrolytes Voltage |
title | MXenes Composites as the Protective Layer for Li Metal Electrodes |
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