Hydrogen Evolution Reaction Activity of Electrochemically Exfoliated Borophene
Borophene has been theoretically shown as an active catalyst for hydrogen evolution reaction (HER). However, there are a few experimental studies assessing the HER activity of borophene. Herein, we study for the first time HER activity of electrochemically exfoliated borophene in acidic medium. Boro...
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| Veröffentlicht in: | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2024-08, Vol.26 (8), p.183, Article 183 |
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| creator | Can, Suleyman Kuru, Duygu Kuru, Cihan |
| description | Borophene has been theoretically shown as an active catalyst for hydrogen evolution reaction (HER). However, there are a few experimental studies assessing the HER activity of borophene. Herein, we study for the first time HER activity of electrochemically exfoliated borophene in acidic medium. Borophene sheets obtained by anodic exfoliation of crystalline boron particles in Na
2
SO
4
have β-rhombohedral crystal structure with an oxidized surface. Borophene exhibits notably higher catalytic activity compared to bulk boron with an overpotential of 480 mV at 10 mA cm
−2
and a Tafel slope of 163 mV dec
−1
. The superior activity of borophene is attributed to enhanced HER kinetics as well as increased electrochemical surface area. Our study provides encouraging results for the use of borophene in catalysis applications.
Graphical Abstract |
| doi_str_mv | 10.1007/s11051-024-06095-z |
| format | Article |
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2
SO
4
have β-rhombohedral crystal structure with an oxidized surface. Borophene exhibits notably higher catalytic activity compared to bulk boron with an overpotential of 480 mV at 10 mA cm
−2
and a Tafel slope of 163 mV dec
−1
. The superior activity of borophene is attributed to enhanced HER kinetics as well as increased electrochemical surface area. Our study provides encouraging results for the use of borophene in catalysis applications.
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2
SO
4
have β-rhombohedral crystal structure with an oxidized surface. Borophene exhibits notably higher catalytic activity compared to bulk boron with an overpotential of 480 mV at 10 mA cm
−2
and a Tafel slope of 163 mV dec
−1
. The superior activity of borophene is attributed to enhanced HER kinetics as well as increased electrochemical surface area. Our study provides encouraging results for the use of borophene in catalysis applications.
Graphical Abstract</description><subject>Acidic oxides</subject><subject>Alternative energy sources</subject><subject>Boron</subject><subject>Borophene</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical vapor deposition</subject><subject>Chemistry and Materials Science</subject><subject>Crystal structure</subject><subject>Efficiency</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Electron microscopes</subject><subject>Energy consumption</subject><subject>Exfoliation</subject><subject>Fossil fuels</subject><subject>Fourier transforms</subject><subject>Graphite</subject><subject>Green hydrogen</subject><subject>Hydrogen evolution reactions</subject><subject>Inorganic Chemistry</subject><subject>Lasers</subject><subject>Materials Science</subject><subject>Microscopy</subject><subject>Nanotechnology</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Physical Chemistry</subject><subject>Reaction kinetics</subject><subject>Renewable resources</subject><subject>Sodium sulfate</subject><subject>Spectrum analysis</subject><issn>1388-0764</issn><issn>1572-896X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kFFLwzAUhYMoOKd_wKeCz9GbpGmaxzmqE4aCKPgWYnq7dXTNTLth9-vtVsE3n865cM658BFyzeCWAai7hjGQjAKPKSSgJd2fkBGTitNUJx-nvRdpSkEl8Tm5aJoVAEu45iPyPOvy4BdYR9nOV9u29HX0itYdzaSXXdl2kS-irELXBu-WuC6draouyr4LX5W2xTy698FvlljjJTkrbNXg1a-OyftD9jad0fnL49N0MqeOA7RUOmEllwlnqbWonEUNKk9Rccc5Cg0omJYxZxLVp4uLnOeiv_MkAZaDEGJMbobdTfBfW2xas_LbUPcvjYBUKya1PqT4kHLBN03AwmxCubahMwzMgZsZuJmemzlyM_u-JIZS04frBYa_6X9aP-fRcRE</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Can, Suleyman</creator><creator>Kuru, Duygu</creator><creator>Kuru, Cihan</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>7U7</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>K9.</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>20240801</creationdate><title>Hydrogen Evolution Reaction Activity of Electrochemically Exfoliated Borophene</title><author>Can, Suleyman ; Kuru, Duygu ; Kuru, Cihan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-5c3a5256218aae7cae907d8e72c22e390e31954215e7bc4fd2d3954d6601d0333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Acidic oxides</topic><topic>Alternative energy sources</topic><topic>Boron</topic><topic>Borophene</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical vapor deposition</topic><topic>Chemistry and Materials Science</topic><topic>Crystal structure</topic><topic>Efficiency</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Electron microscopes</topic><topic>Energy consumption</topic><topic>Exfoliation</topic><topic>Fossil fuels</topic><topic>Fourier transforms</topic><topic>Graphite</topic><topic>Green hydrogen</topic><topic>Hydrogen evolution reactions</topic><topic>Inorganic Chemistry</topic><topic>Lasers</topic><topic>Materials Science</topic><topic>Microscopy</topic><topic>Nanotechnology</topic><topic>Optical Devices</topic><topic>Optics</topic><topic>Photonics</topic><topic>Physical Chemistry</topic><topic>Reaction kinetics</topic><topic>Renewable resources</topic><topic>Sodium sulfate</topic><topic>Spectrum analysis</topic><toplevel>online_resources</toplevel><creatorcontrib>Can, Suleyman</creatorcontrib><creatorcontrib>Kuru, Duygu</creatorcontrib><creatorcontrib>Kuru, Cihan</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Can, Suleyman</au><au>Kuru, Duygu</au><au>Kuru, Cihan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen Evolution Reaction Activity of Electrochemically Exfoliated Borophene</atitle><jtitle>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</jtitle><stitle>J Nanopart Res</stitle><date>2024-08-01</date><risdate>2024</risdate><volume>26</volume><issue>8</issue><spage>183</spage><pages>183-</pages><artnum>183</artnum><issn>1388-0764</issn><eissn>1572-896X</eissn><abstract>Borophene has been theoretically shown as an active catalyst for hydrogen evolution reaction (HER). However, there are a few experimental studies assessing the HER activity of borophene. Herein, we study for the first time HER activity of electrochemically exfoliated borophene in acidic medium. Borophene sheets obtained by anodic exfoliation of crystalline boron particles in Na
2
SO
4
have β-rhombohedral crystal structure with an oxidized surface. Borophene exhibits notably higher catalytic activity compared to bulk boron with an overpotential of 480 mV at 10 mA cm
−2
and a Tafel slope of 163 mV dec
−1
. The superior activity of borophene is attributed to enhanced HER kinetics as well as increased electrochemical surface area. Our study provides encouraging results for the use of borophene in catalysis applications.
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| ispartof | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology, 2024-08, Vol.26 (8), p.183, Article 183 |
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| subjects | Acidic oxides Alternative energy sources Boron Borophene Carbon Catalysis Catalysts Catalytic activity Characterization and Evaluation of Materials Chemical vapor deposition Chemistry and Materials Science Crystal structure Efficiency Electrochemistry Electrodes Electron microscopes Energy consumption Exfoliation Fossil fuels Fourier transforms Graphite Green hydrogen Hydrogen evolution reactions Inorganic Chemistry Lasers Materials Science Microscopy Nanotechnology Optical Devices Optics Photonics Physical Chemistry Reaction kinetics Renewable resources Sodium sulfate Spectrum analysis |
| title | Hydrogen Evolution Reaction Activity of Electrochemically Exfoliated Borophene |
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