Eco-friendly calcium alginate microspheres enable enhanced profile control and oil displacement
Polymer microspheres (PMs), such as polyacrylamide, have been widely applied for enhanced oil recovery (EOR), yet with environmental concerns. Here, we report a microfluid displacement technology containing a bio-based eco-friendly material, i.e., calcium alginate (CaAlg) microspheres for EOR. Two d...
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| Veröffentlicht in: | Petroleum science 2024-06, Vol.21 (3), p.1928-1943 |
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| creator | Zhang, Xiao-Han Zhou, Chang-Jing Xiao, Yuan-Xiang Hui, Bo Xie, Yong-Gang Su, Yu-Bin Li, Xin-Ru Huang, Jie Liu, Mao-Chang |
| description | Polymer microspheres (PMs), such as polyacrylamide, have been widely applied for enhanced oil recovery (EOR), yet with environmental concerns. Here, we report a microfluid displacement technology containing a bio-based eco-friendly material, i.e., calcium alginate (CaAlg) microspheres for EOR. Two dominant mechanisms responsible for EOR over CaAlg fluid have been verified, including the microscopic oil displacement efficacy augmented by regulating capillary force (determined by the joint action of interfacial tension and wettability between different phases) and macroscopic sweep volume increment through profile control and mobility ratio reduction. This comprehensive effectiveness can be further impacted when the CaAlg microsphere is embellished ulteriorly by using appropriate amount of sodium dodecyl sulfonate (SDS). The core flooding and nuclear magnetic resonance (NMR) tests demonstrate that CaAlg-SDS microsphere can balance the interphase property regulation (wettability alteration and IFT reduction) and rheology properties, enabling simultaneous profile control and oil displacement. Excessive introduction of SDS will have a negative impact on rheological properties, which is not favored for EOR. Our results show that the involvement of 4-mM SDS will provide the best behavior, with an EOR rate of 34.38%. This cost-effective and environmentally-friendly bio-microsphere-based microfluidic displacement technology is expected to achieve “green” oil recovery in future oilfield exploitation. |
| doi_str_mv | 10.1016/j.petsci.2023.12.013 |
| format | Article |
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Here, we report a microfluid displacement technology containing a bio-based eco-friendly material, i.e., calcium alginate (CaAlg) microspheres for EOR. Two dominant mechanisms responsible for EOR over CaAlg fluid have been verified, including the microscopic oil displacement efficacy augmented by regulating capillary force (determined by the joint action of interfacial tension and wettability between different phases) and macroscopic sweep volume increment through profile control and mobility ratio reduction. This comprehensive effectiveness can be further impacted when the CaAlg microsphere is embellished ulteriorly by using appropriate amount of sodium dodecyl sulfonate (SDS). The core flooding and nuclear magnetic resonance (NMR) tests demonstrate that CaAlg-SDS microsphere can balance the interphase property regulation (wettability alteration and IFT reduction) and rheology properties, enabling simultaneous profile control and oil displacement. Excessive introduction of SDS will have a negative impact on rheological properties, which is not favored for EOR. Our results show that the involvement of 4-mM SDS will provide the best behavior, with an EOR rate of 34.38%. This cost-effective and environmentally-friendly bio-microsphere-based microfluidic displacement technology is expected to achieve “green” oil recovery in future oilfield exploitation.</description><identifier>ISSN: 1995-8226</identifier><identifier>ISSN: 1672-5107</identifier><identifier>EISSN: 1995-8226</identifier><identifier>DOI: 10.1016/j.petsci.2023.12.013</identifier><language>eng</language><publisher>Beijing: Elsevier B.V</publisher><subject>Biomass ; Calcium ; Calcium alginate ; Calcium alginate microspheres ; Composite materials ; Effectiveness ; Efficiency ; Enhanced oil recovery ; Enhanced oil recovery (EOR) ; Interfacial tension ; Magnetic properties ; Microspheres ; Mineral oils ; NMR ; Nuclear magnetic resonance ; Oil and gas fields ; Oil fields ; Oil recovery ; Permeability ; Polyacrylamide ; Polymers ; Rheological properties ; Rheology ; Seaweed meal ; Sodium ; Surface tension ; Surfactants ; Viscoelasticity ; Viscosity ; Wettability</subject><ispartof>Petroleum science, 2024-06, Vol.21 (3), p.1928-1943</ispartof><rights>2023 The Authors</rights><rights>2024. 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Excessive introduction of SDS will have a negative impact on rheological properties, which is not favored for EOR. Our results show that the involvement of 4-mM SDS will provide the best behavior, with an EOR rate of 34.38%. 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Here, we report a microfluid displacement technology containing a bio-based eco-friendly material, i.e., calcium alginate (CaAlg) microspheres for EOR. Two dominant mechanisms responsible for EOR over CaAlg fluid have been verified, including the microscopic oil displacement efficacy augmented by regulating capillary force (determined by the joint action of interfacial tension and wettability between different phases) and macroscopic sweep volume increment through profile control and mobility ratio reduction. This comprehensive effectiveness can be further impacted when the CaAlg microsphere is embellished ulteriorly by using appropriate amount of sodium dodecyl sulfonate (SDS). The core flooding and nuclear magnetic resonance (NMR) tests demonstrate that CaAlg-SDS microsphere can balance the interphase property regulation (wettability alteration and IFT reduction) and rheology properties, enabling simultaneous profile control and oil displacement. Excessive introduction of SDS will have a negative impact on rheological properties, which is not favored for EOR. Our results show that the involvement of 4-mM SDS will provide the best behavior, with an EOR rate of 34.38%. This cost-effective and environmentally-friendly bio-microsphere-based microfluidic displacement technology is expected to achieve “green” oil recovery in future oilfield exploitation.</abstract><cop>Beijing</cop><pub>Elsevier B.V</pub><doi>10.1016/j.petsci.2023.12.013</doi><tpages>16</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1995-8226 |
| ispartof | Petroleum science, 2024-06, Vol.21 (3), p.1928-1943 |
| issn | 1995-8226 1672-5107 1995-8226 |
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| source | EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection |
| subjects | Biomass Calcium Calcium alginate Calcium alginate microspheres Composite materials Effectiveness Efficiency Enhanced oil recovery Enhanced oil recovery (EOR) Interfacial tension Magnetic properties Microspheres Mineral oils NMR Nuclear magnetic resonance Oil and gas fields Oil fields Oil recovery Permeability Polyacrylamide Polymers Rheological properties Rheology Seaweed meal Sodium Surface tension Surfactants Viscoelasticity Viscosity Wettability |
| title | Eco-friendly calcium alginate microspheres enable enhanced profile control and oil displacement |
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