Fabrication and characterization of PZT/PVDF composite films for force sensor applications

This study explored the impact of hot press parameters on lead zirconate titanate (PZT)/poly(vinylidene fluoride) (PVDF) composite films designed for force‐sensing applications. The systematic fraction (PZT/PVDF), pressure, temperature, and time during hot pressing processes are subject to variation. The focus is on the resulting composite film thickness and its subsequent influence on the piezoelectric properties, which are essential for the performance of force sensors. The present study investigated the characteristics and performance of PZT/PVDF composite films with fraction ratios 2/5, 5/5, and 7/3 and hot pressure of 10, 40, and 60 MPa and temperature at 150 °C for 2 h. The characterization of these films was conducted using X‐ray diffraction, Fourier transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy. The piezoelectric properties (d33 and d31) were measured using impact and extraction tests to evaluate the performance of films with applied forces. The results show that the highest piezoelectric coefficients (d33 and d31) were determined to be 35.8 and 12.60 pC N−1, with fraction ratios of 7/3 and 2/5. The study revealed a positive correlation between the PZT/PVDF ratio and sensitivity, indicating that an increase in the ratio leads to an increase in sensitivity. Conversely, a negative relationship was observed between the impact load and the sensor sensitivity, suggesting that an increase in the impact load results in a sensitivity decrease. The results of this work demonstrate the great potential of piezoelectric PZT/PVDF composite films in force sensors for small load applications. © 2024 Society of Chemical Industry. Innovative hot‐pressed PZT/PVDF composite film for force sensor applications is reported, exhibiting enhanced sensitivity for small load through different hot‐pressing pressure configurations and composite ratios.