Stability and reliability of BaTiO3-based MLCCs with high dielectric by rare-earth doping: an insight from domain-engineering

Rare earth (RE)-doped BaTiO 3 materials are promising dielectric materials for base-metal electrode multilayer ceramic capacitors (BME-MLCCs). Thus, the fundamental understanding of their effect on dielectric properties and reliability is crucial for further improvement of its performance. Herein, a...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2024-08, Vol.130 (8), Article 601
Hauptverfasser: Tan, Junhui, Wang, Pengfei, Huang, Rongxia, Lin, Hua-Tay, Hu, Zhiping, Yang, Jun, Cheng, Lixia, Fu, Zhenxiao, Cao, Xiuhua, Zhang, Lei, Yu, Shuhui, Sun, Rong
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container_title Applied physics. A, Materials science & processing
container_volume 130
creator Tan, Junhui
Wang, Pengfei
Huang, Rongxia
Lin, Hua-Tay
Hu, Zhiping
Yang, Jun
Cheng, Lixia
Fu, Zhenxiao
Cao, Xiuhua
Zhang, Lei
Yu, Shuhui
Sun, Rong
description Rare earth (RE)-doped BaTiO 3 materials are promising dielectric materials for base-metal electrode multilayer ceramic capacitors (BME-MLCCs). Thus, the fundamental understanding of their effect on dielectric properties and reliability is crucial for further improvement of its performance. Herein, according to Preisach model, the dielectric stability of Dy and Y-doped BaTiO 3 MLCCs with different particle sizes was investigated in this study. First order reversal curve (FORC) analysis showed that the reversible and irreversible domain wall motion of Dy-doped samples was weaker than that of Y-doped samples. Results also showed that the higher “shell” proportion of “core-shell” structure in Dy-doping was beneficial for improving the dielectric stability and insulation resistance degradation. The findings provide a comprehensive understanding and illustrate the significant role of the “core-shell” volume ratio in the tetragonality and domain wall motion in RE-doped BaTiO 3 materials, and consequently laying an important ground work to obtain high dielectric stability and reliability in BME-MLCCs.
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subjects Barium titanates
Characterization and Evaluation of Materials
Condensed Matter Physics
Dielectric properties
Dielectric strength
Domain walls
Doping
Dysprosium
Machines
Manufacturing
Multilayers
Nanotechnology
Optical and Electronic Materials
Physics
Physics and Astronomy
Processes
Rare earth elements
Reliability
Shell stability
Stability
Surfaces and Interfaces
Thin Films
Yttrium
title Stability and reliability of BaTiO3-based MLCCs with high dielectric by rare-earth doping: an insight from domain-engineering
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