Regulating microstructure and composition by carbonizing in-situ grown metal-organic frameworks on cotton fabrics for boosting electromagnetic wave absorption
High-temperature carbonized metal-organic frameworks (MOFs) derivatives have demonstrated their superiority for promising electromagnetic wave (EMW) absorbers, but they still suffer from limited EMW absorption capacity and narrow bandwidth. Considering the advantage of microstructure and chemical co...
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| Veröffentlicht in: | Nano research 2024-08, Vol.17 (8), p.7290-7300 |
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| creator | Jin, Jie Long, Hongsen Liu, Hu Guo, Yan Bai, Tiantian Xu, Ben Bin Amin, Mohammed A. Qiu, Hua Helal, Mohamed H. Liu, Chuntai Shen, Changyu El-Bahy, Zeinhom M. Guo, Zhanhu |
| description | High-temperature carbonized metal-organic frameworks (MOFs) derivatives have demonstrated their superiority for promising electromagnetic wave (EMW) absorbers, but they still suffer from limited EMW absorption capacity and narrow bandwidth. Considering the advantage of microstructure and chemical composition regulation for the design of EMW absorber, hierarchical heterostructured MoS
2
/CoS
2
-Co
3
O
4
@cabonized cotton fabric (CF) (MCC@CCF) is prepared by growing ZIF-67 MOFs onto CF surface, chemical etching, and carbonization. Aside from the dual loss mechanism of magnetic-dielectric multicomponent carbonized MOFs, chemical etching and carbonization process can effectively introduce abundant micro-gap structure that can result in better impedance matching and stronger absorption capacity via internal reflection, doped heteroatoms (Mo, N, S) to supply additional dipolar polarization loss, and numerous heterointerfaces among MoS
2
, CoS
2
, Co
3
O
4
, and CCF that produce promoted conduction loss and interfacial polarization loss. Thus, a minimal reflection loss of −52.87 dB and a broadest effective absorption bandwidth of 6.88 GHz were achieved via tunning the sample thickness and filler loading, showing excellent EMW absorption performances. This research is of great value for guiding the research on MOFs derivatives based EMW absorbing materials. |
| doi_str_mv | 10.1007/s12274-024-6745-8 |
| format | Article |
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2
/CoS
2
-Co
3
O
4
@cabonized cotton fabric (CF) (MCC@CCF) is prepared by growing ZIF-67 MOFs onto CF surface, chemical etching, and carbonization. Aside from the dual loss mechanism of magnetic-dielectric multicomponent carbonized MOFs, chemical etching and carbonization process can effectively introduce abundant micro-gap structure that can result in better impedance matching and stronger absorption capacity via internal reflection, doped heteroatoms (Mo, N, S) to supply additional dipolar polarization loss, and numerous heterointerfaces among MoS
2
, CoS
2
, Co
3
O
4
, and CCF that produce promoted conduction loss and interfacial polarization loss. Thus, a minimal reflection loss of −52.87 dB and a broadest effective absorption bandwidth of 6.88 GHz were achieved via tunning the sample thickness and filler loading, showing excellent EMW absorption performances. This research is of great value for guiding the research on MOFs derivatives based EMW absorbing materials.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-024-6745-8</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Absorbers ; Absorption ; Atomic/Molecular Structure and Spectra ; Bandwidths ; Biomedicine ; Biotechnology ; Carbon ; Carbonization ; Chemical composition ; Chemical etching ; Chemistry ; Chemistry and Materials Science ; Civil engineering ; Cobalt oxides ; Cobalt sulfide ; Condensed Matter Physics ; Conduction losses ; Cotton ; Cotton fabrics ; Dielectric properties ; Dielectric strength ; Electromagnetic radiation ; EM Wave Functional Materials ; Etching ; High temperature ; Impedance matching ; Materials Science ; Metal-organic frameworks ; Microscopy ; Microstructure ; Molybdenum disulfide ; Nanotechnology ; Polarization ; Powder metallurgy ; Research Article</subject><ispartof>Nano research, 2024-08, Vol.17 (8), p.7290-7300</ispartof><rights>The Author(s) 2024</rights><rights>The Author(s) 2024. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c289t-4f3bd35d1429abdca6ac98c864b534ae2286bded1d9dae88bad95aaf19df8c873</citedby><cites>FETCH-LOGICAL-c289t-4f3bd35d1429abdca6ac98c864b534ae2286bded1d9dae88bad95aaf19df8c873</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-024-6745-8$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-024-6745-8$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Jin, Jie</creatorcontrib><creatorcontrib>Long, Hongsen</creatorcontrib><creatorcontrib>Liu, Hu</creatorcontrib><creatorcontrib>Guo, Yan</creatorcontrib><creatorcontrib>Bai, Tiantian</creatorcontrib><creatorcontrib>Xu, Ben Bin</creatorcontrib><creatorcontrib>Amin, Mohammed A.</creatorcontrib><creatorcontrib>Qiu, Hua</creatorcontrib><creatorcontrib>Helal, Mohamed H.</creatorcontrib><creatorcontrib>Liu, Chuntai</creatorcontrib><creatorcontrib>Shen, Changyu</creatorcontrib><creatorcontrib>El-Bahy, Zeinhom M.</creatorcontrib><creatorcontrib>Guo, Zhanhu</creatorcontrib><title>Regulating microstructure and composition by carbonizing in-situ grown metal-organic frameworks on cotton fabrics for boosting electromagnetic wave absorption</title><title>Nano research</title><addtitle>Nano Res</addtitle><description>High-temperature carbonized metal-organic frameworks (MOFs) derivatives have demonstrated their superiority for promising electromagnetic wave (EMW) absorbers, but they still suffer from limited EMW absorption capacity and narrow bandwidth. Considering the advantage of microstructure and chemical composition regulation for the design of EMW absorber, hierarchical heterostructured MoS
2
/CoS
2
-Co
3
O
4
@cabonized cotton fabric (CF) (MCC@CCF) is prepared by growing ZIF-67 MOFs onto CF surface, chemical etching, and carbonization. Aside from the dual loss mechanism of magnetic-dielectric multicomponent carbonized MOFs, chemical etching and carbonization process can effectively introduce abundant micro-gap structure that can result in better impedance matching and stronger absorption capacity via internal reflection, doped heteroatoms (Mo, N, S) to supply additional dipolar polarization loss, and numerous heterointerfaces among MoS
2
, CoS
2
, Co
3
O
4
, and CCF that produce promoted conduction loss and interfacial polarization loss. Thus, a minimal reflection loss of −52.87 dB and a broadest effective absorption bandwidth of 6.88 GHz were achieved via tunning the sample thickness and filler loading, showing excellent EMW absorption performances. This research is of great value for guiding the research on MOFs derivatives based EMW absorbing materials.</description><subject>Absorbers</subject><subject>Absorption</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Bandwidths</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Carbon</subject><subject>Carbonization</subject><subject>Chemical composition</subject><subject>Chemical etching</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Civil engineering</subject><subject>Cobalt oxides</subject><subject>Cobalt sulfide</subject><subject>Condensed Matter Physics</subject><subject>Conduction losses</subject><subject>Cotton</subject><subject>Cotton fabrics</subject><subject>Dielectric properties</subject><subject>Dielectric strength</subject><subject>Electromagnetic radiation</subject><subject>EM Wave Functional Materials</subject><subject>Etching</subject><subject>High temperature</subject><subject>Impedance matching</subject><subject>Materials Science</subject><subject>Metal-organic frameworks</subject><subject>Microscopy</subject><subject>Microstructure</subject><subject>Molybdenum disulfide</subject><subject>Nanotechnology</subject><subject>Polarization</subject><subject>Powder metallurgy</subject><subject>Research Article</subject><issn>1998-0124</issn><issn>1998-0000</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp1kU9LHTEUxYfSglb7AboLuE5NMnkzmWURrYIgiK7DzZ8ZYt8krzcZH_bD9LOa4Smuejf3Qs7vHMhpmu-c_eCM9eeZC9FLyoSkXS83VH1qjvkwKMrqfH6_uZBHzdecnxjrBJfquPl376dlCyXEiczBYsoFF1sW9ASiIzbNu5RDCSkS80IsoEkx_F3VIdL6sJAJ0z6S2RfY0oQTxGDJiDD7fcLfmVTQplLqGsFgsJmMCYlJNWh18VtvC6YZpuhLJffwXJNNTrhbQ0-bLyNss__2tk-ax6vLh4trenv36-bi5y21Qg2FyrE1rt04LsUAxlnowA7Kqk6aTSvBC6E647zjbnDglTLghg3AyAc3VlnfnjRnB98dpj-Lz0U_pQVjjdQtUz0TfdutKn5Qrf-U0Y96h2EGfNGc6bUGfahB1xr0WoNWlREHJldtnDx-OP8fegVoYZFm</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Jin, Jie</creator><creator>Long, Hongsen</creator><creator>Liu, Hu</creator><creator>Guo, Yan</creator><creator>Bai, Tiantian</creator><creator>Xu, Ben Bin</creator><creator>Amin, Mohammed A.</creator><creator>Qiu, Hua</creator><creator>Helal, Mohamed H.</creator><creator>Liu, Chuntai</creator><creator>Shen, Changyu</creator><creator>El-Bahy, Zeinhom M.</creator><creator>Guo, Zhanhu</creator><general>Tsinghua University Press</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>K9.</scope><scope>L7M</scope><scope>P64</scope></search><sort><creationdate>20240801</creationdate><title>Regulating microstructure and composition by carbonizing in-situ grown metal-organic frameworks on cotton fabrics for boosting electromagnetic wave absorption</title><author>Jin, Jie ; 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Considering the advantage of microstructure and chemical composition regulation for the design of EMW absorber, hierarchical heterostructured MoS
2
/CoS
2
-Co
3
O
4
@cabonized cotton fabric (CF) (MCC@CCF) is prepared by growing ZIF-67 MOFs onto CF surface, chemical etching, and carbonization. Aside from the dual loss mechanism of magnetic-dielectric multicomponent carbonized MOFs, chemical etching and carbonization process can effectively introduce abundant micro-gap structure that can result in better impedance matching and stronger absorption capacity via internal reflection, doped heteroatoms (Mo, N, S) to supply additional dipolar polarization loss, and numerous heterointerfaces among MoS
2
, CoS
2
, Co
3
O
4
, and CCF that produce promoted conduction loss and interfacial polarization loss. Thus, a minimal reflection loss of −52.87 dB and a broadest effective absorption bandwidth of 6.88 GHz were achieved via tunning the sample thickness and filler loading, showing excellent EMW absorption performances. This research is of great value for guiding the research on MOFs derivatives based EMW absorbing materials.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-024-6745-8</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1998-0124 |
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| issn | 1998-0124 1998-0000 |
| language | eng |
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| source | Springer Journals |
| subjects | Absorbers Absorption Atomic/Molecular Structure and Spectra Bandwidths Biomedicine Biotechnology Carbon Carbonization Chemical composition Chemical etching Chemistry Chemistry and Materials Science Civil engineering Cobalt oxides Cobalt sulfide Condensed Matter Physics Conduction losses Cotton Cotton fabrics Dielectric properties Dielectric strength Electromagnetic radiation EM Wave Functional Materials Etching High temperature Impedance matching Materials Science Metal-organic frameworks Microscopy Microstructure Molybdenum disulfide Nanotechnology Polarization Powder metallurgy Research Article |
| title | Regulating microstructure and composition by carbonizing in-situ grown metal-organic frameworks on cotton fabrics for boosting electromagnetic wave absorption |
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