Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors
Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a...
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Veröffentlicht in: | New journal of chemistry 2024-07, Vol.48 (3), p.13475-13491 |
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container_title | New journal of chemistry |
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creator | El Naggar, Ahmed M.A El-Fawal, Esraa M Abd el Karim, Mohamed I El-Zahhar, Adel A Taha, Mohamed H Ramadan, Ahmed M Ahmed, Hanan B |
description | Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a zinc nanoparticle (Zn NP) and polystyrene (PS) composite (ZnNPs@PS composite). The synthesized composite was characterized, revealing a surface area (
S
BET
) of 33.62 m
2
g
−1
and an average pore diameter (
D
p
) of 9 nm. The analysis was conducted using several techniques including Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The successful immobilization of Zn NPs, with an average size range of 4-50 nm, within the PS matrix was confirmed. The composite's corrosion inhibition efficiency (CIE) was evaluated using the weight loss method. Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H
2
SO
4
) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments.
Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. |
doi_str_mv | 10.1039/d4nj01777c |
format | Article |
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S
BET
) of 33.62 m
2
g
−1
and an average pore diameter (
D
p
) of 9 nm. The analysis was conducted using several techniques including Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The successful immobilization of Zn NPs, with an average size range of 4-50 nm, within the PS matrix was confirmed. The composite's corrosion inhibition efficiency (CIE) was evaluated using the weight loss method. Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H
2
SO
4
) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments.
Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d4nj01777c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Corrosion ; Corrosion inhibitors ; Corrosion potential ; Corrosion prevention ; Corrosion tests ; Diesel fuels ; Electron microscopy ; Fourier transforms ; Infrared analysis ; Infrared spectroscopy ; Microscopy ; Nanoparticles ; Polystyrene resins ; Spectrum analysis ; Steel structures ; Sulfuric acid ; Weight loss ; Zinc</subject><ispartof>New journal of chemistry, 2024-07, Vol.48 (3), p.13475-13491</ispartof><rights>Copyright Royal Society of Chemistry 2024</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c170t-61582dfec30a08e0fe3b740c96eef1e1922d35933a5d1bef61439f71f6667d223</cites><orcidid>0000-0003-1568-7354 ; 0000-0003-3798-0666 ; 0000-0003-2353-1480</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>El Naggar, Ahmed M.A</creatorcontrib><creatorcontrib>El-Fawal, Esraa M</creatorcontrib><creatorcontrib>Abd el Karim, Mohamed I</creatorcontrib><creatorcontrib>El-Zahhar, Adel A</creatorcontrib><creatorcontrib>Taha, Mohamed H</creatorcontrib><creatorcontrib>Ramadan, Ahmed M</creatorcontrib><creatorcontrib>Ahmed, Hanan B</creatorcontrib><title>Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors</title><title>New journal of chemistry</title><description>Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a zinc nanoparticle (Zn NP) and polystyrene (PS) composite (ZnNPs@PS composite). The synthesized composite was characterized, revealing a surface area (
S
BET
) of 33.62 m
2
g
−1
and an average pore diameter (
D
p
) of 9 nm. The analysis was conducted using several techniques including Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The successful immobilization of Zn NPs, with an average size range of 4-50 nm, within the PS matrix was confirmed. The composite's corrosion inhibition efficiency (CIE) was evaluated using the weight loss method. Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H
2
SO
4
) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments.
Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources.</description><subject>Corrosion</subject><subject>Corrosion inhibitors</subject><subject>Corrosion potential</subject><subject>Corrosion prevention</subject><subject>Corrosion tests</subject><subject>Diesel fuels</subject><subject>Electron microscopy</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Microscopy</subject><subject>Nanoparticles</subject><subject>Polystyrene resins</subject><subject>Spectrum analysis</subject><subject>Steel structures</subject><subject>Sulfuric acid</subject><subject>Weight loss</subject><subject>Zinc</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkU1PwzAMhisEEmNw4Y4UiRtSIW7SdD2i8a1pXOBcZakDmbqkJOmk8S_4x2QMwcmW_Niv_TrLToFeAmX1VcvtkkJVVWovGwETdV4XAvZTDpzntOTiMDsKYUkpQCVglH3N3Ro7Itu1tApXaGMgxpLeu4gqGmeJ0yRETEwYvJYKAxmCsW-kd90mxI1Hi6nU985HbImV1vXSR6O6RKbeFUbZdUaRT2MVkYEEqbzRRhnZEeW8d2GrYuy7WZjofDjODrTsAp78xnH2enf7Mn3IZ8_3j9PrWa6gojEXUE6KVqNiVNIJUo1sUXGqaoGoAaEuipaVNWOybGGBWgBnta5ACyGqtijYODvfzU23fgwYYrN0g7dJsmF0UnKeDKoTdbGjVFo0eNRN781K-k0DtNla3tzw-dOP5dMEn-1gH9Qf9_8S9g2E_YIM</recordid><startdate>20240729</startdate><enddate>20240729</enddate><creator>El Naggar, Ahmed M.A</creator><creator>El-Fawal, Esraa M</creator><creator>Abd el Karim, Mohamed I</creator><creator>El-Zahhar, Adel A</creator><creator>Taha, Mohamed H</creator><creator>Ramadan, Ahmed M</creator><creator>Ahmed, Hanan B</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0003-1568-7354</orcidid><orcidid>https://orcid.org/0000-0003-3798-0666</orcidid><orcidid>https://orcid.org/0000-0003-2353-1480</orcidid></search><sort><creationdate>20240729</creationdate><title>Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors</title><author>El Naggar, Ahmed M.A ; El-Fawal, Esraa M ; Abd el Karim, Mohamed I ; El-Zahhar, Adel A ; Taha, Mohamed H ; Ramadan, Ahmed M ; Ahmed, Hanan B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c170t-61582dfec30a08e0fe3b740c96eef1e1922d35933a5d1bef61439f71f6667d223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Corrosion</topic><topic>Corrosion inhibitors</topic><topic>Corrosion potential</topic><topic>Corrosion prevention</topic><topic>Corrosion tests</topic><topic>Diesel fuels</topic><topic>Electron microscopy</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Microscopy</topic><topic>Nanoparticles</topic><topic>Polystyrene resins</topic><topic>Spectrum analysis</topic><topic>Steel structures</topic><topic>Sulfuric acid</topic><topic>Weight loss</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>El Naggar, Ahmed M.A</creatorcontrib><creatorcontrib>El-Fawal, Esraa M</creatorcontrib><creatorcontrib>Abd el Karim, Mohamed I</creatorcontrib><creatorcontrib>El-Zahhar, Adel A</creatorcontrib><creatorcontrib>Taha, Mohamed H</creatorcontrib><creatorcontrib>Ramadan, Ahmed M</creatorcontrib><creatorcontrib>Ahmed, Hanan B</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>El Naggar, Ahmed M.A</au><au>El-Fawal, Esraa M</au><au>Abd el Karim, Mohamed I</au><au>El-Zahhar, Adel A</au><au>Taha, Mohamed H</au><au>Ramadan, Ahmed M</au><au>Ahmed, Hanan B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors</atitle><jtitle>New journal of chemistry</jtitle><date>2024-07-29</date><risdate>2024</risdate><volume>48</volume><issue>3</issue><spage>13475</spage><epage>13491</epage><pages>13475-13491</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a zinc nanoparticle (Zn NP) and polystyrene (PS) composite (ZnNPs@PS composite). The synthesized composite was characterized, revealing a surface area (
S
BET
) of 33.62 m
2
g
−1
and an average pore diameter (
D
p
) of 9 nm. The analysis was conducted using several techniques including Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The successful immobilization of Zn NPs, with an average size range of 4-50 nm, within the PS matrix was confirmed. The composite's corrosion inhibition efficiency (CIE) was evaluated using the weight loss method. Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H
2
SO
4
) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments.
Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d4nj01777c</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0003-1568-7354</orcidid><orcidid>https://orcid.org/0000-0003-3798-0666</orcidid><orcidid>https://orcid.org/0000-0003-2353-1480</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Corrosion Corrosion inhibitors Corrosion potential Corrosion prevention Corrosion tests Diesel fuels Electron microscopy Fourier transforms Infrared analysis Infrared spectroscopy Microscopy Nanoparticles Polystyrene resins Spectrum analysis Steel structures Sulfuric acid Weight loss Zinc |
title | Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors |
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