Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors

Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a...

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Veröffentlicht in:New journal of chemistry 2024-07, Vol.48 (3), p.13475-13491
Hauptverfasser: El Naggar, Ahmed M.A, El-Fawal, Esraa M, Abd el Karim, Mohamed I, El-Zahhar, Adel A, Taha, Mohamed H, Ramadan, Ahmed M, Ahmed, Hanan B
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container_end_page 13491
container_issue 3
container_start_page 13475
container_title New journal of chemistry
container_volume 48
creator El Naggar, Ahmed M.A
El-Fawal, Esraa M
Abd el Karim, Mohamed I
El-Zahhar, Adel A
Taha, Mohamed H
Ramadan, Ahmed M
Ahmed, Hanan B
description Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources. The present study introduces an innovative approach to the development of corrosion inhibitors through the synthesis of a zinc nanoparticle (Zn NP) and polystyrene (PS) composite (ZnNPs@PS composite). The synthesized composite was characterized, revealing a surface area ( S BET ) of 33.62 m 2 g −1 and an average pore diameter ( D p ) of 9 nm. The analysis was conducted using several techniques including Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The successful immobilization of Zn NPs, with an average size range of 4-50 nm, within the PS matrix was confirmed. The composite's corrosion inhibition efficiency (CIE) was evaluated using the weight loss method. Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H 2 SO 4 ) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments. Corrosion poses a significant challenge, causing severe damage to steel infrastructures across various industries, particularly those involved in delivering fossil fuel sources.
doi_str_mv 10.1039/d4nj01777c
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Treated steel samples, after immersion in formation water, diesel fuel, and sulfuric acid (H 2 SO 4 ) for 10 days at 25 °C, demonstrated CIE percentages of 94.27%, 88.18%, and 85.05%, respectively. This novel composite thus shows promising potential as an effective corrosion inhibitor for steel in various corrosive environments. 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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Corrosion
Corrosion inhibitors
Corrosion potential
Corrosion prevention
Corrosion tests
Diesel fuels
Electron microscopy
Fourier transforms
Infrared analysis
Infrared spectroscopy
Microscopy
Nanoparticles
Polystyrene resins
Spectrum analysis
Steel structures
Sulfuric acid
Weight loss
Zinc
title Novel advancements in protection of steel surfaces using polystyrene supported nanoparticles of metallic zinc as sacrificial corrosion inhibitors
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